引用本文:
Xin Wang, Juan Shen, Jin Cui Wu, Min Fang, Hong Yao Xu. Preparation and property of a novel soluble electron transport POSS-based hybrid material[J]. Chinese Chemical Letters,
2008, 19(6): 634-638.
doi:
10.1016/j.cclet.2008.04.016
Citation: Xin Wang, Juan Shen, Jin Cui Wu, Min Fang, Hong Yao Xu. Preparation and property of a novel soluble electron transport POSS-based hybrid material[J]. Chinese Chemical Letters, 2008, 19(6): 634-638. doi: 10.1016/j.cclet.2008.04.016
Citation: Xin Wang, Juan Shen, Jin Cui Wu, Min Fang, Hong Yao Xu. Preparation and property of a novel soluble electron transport POSS-based hybrid material[J]. Chinese Chemical Letters, 2008, 19(6): 634-638. doi: 10.1016/j.cclet.2008.04.016
Preparation and property of a novel soluble electron transport POSS-based hybrid material
摘要:
A novel POSS-based organic/inorganic hybrid covalently attached at molecular level, 2-(4-(allyloxy)phenyl)-5-(4-(octyloxy)phenyl)-1,3,4-oxadiazole-POSS (6) (abbreviated as oxadiazole-POSS) was synthesized by Pt (dcp) catalyst. The hybrid was soluble in common organic solvents such as CHCl3, toluene, C2H4Cl2, and THF. Its structures and properties were characterized and evaluated with FTIR, 1H NMR, 13C NMR, 29Si NMR, EA, TGA, DSC, GPC, and CV, respectively. The results show that the novel hybrid possesses high thermal stability and good electron injection ability.
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关键词:
- CV
- / Electron transport
- / Oxadiazole
- / POSS
- / Thermal stability
English
Preparation and property of a novel soluble electron transport POSS-based hybrid material
Abstract:
A novel POSS-based organic/inorganic hybrid covalently attached at molecular level, 2-(4-(allyloxy)phenyl)-5-(4-(octyloxy)phenyl)-1,3,4-oxadiazole-POSS (6) (abbreviated as oxadiazole-POSS) was synthesized by Pt (dcp) catalyst. The hybrid was soluble in common organic solvents such as CHCl3, toluene, C2H4Cl2, and THF. Its structures and properties were characterized and evaluated with FTIR, 1H NMR, 13C NMR, 29Si NMR, EA, TGA, DSC, GPC, and CV, respectively. The results show that the novel hybrid possesses high thermal stability and good electron injection ability.
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Key words:
- CV
- / Electron transport
- / Oxadiazole
- / POSS
- / Thermal stability
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