引用本文:
Yi Ru Peng, Yu Hong Cao, Pei Feng Chen, Xiao Xia Huang. Synthesis of di-μ-oxo-tetra-(α-pentyloxy) tin(IV) phthalocyanine[J]. Chinese Chemical Letters,
2008, 19(3): 273-276.
doi:
10.1016/j.cclet.2007.12.020
Citation: Yi Ru Peng, Yu Hong Cao, Pei Feng Chen, Xiao Xia Huang. Synthesis of di-μ-oxo-tetra-(α-pentyloxy) tin(IV) phthalocyanine[J]. Chinese Chemical Letters, 2008, 19(3): 273-276. doi: 10.1016/j.cclet.2007.12.020
Citation: Yi Ru Peng, Yu Hong Cao, Pei Feng Chen, Xiao Xia Huang. Synthesis of di-μ-oxo-tetra-(α-pentyloxy) tin(IV) phthalocyanine[J]. Chinese Chemical Letters, 2008, 19(3): 273-276. doi: 10.1016/j.cclet.2007.12.020
Synthesis of di-μ-oxo-tetra-(α-pentyloxy) tin(IV) phthalocyanine
摘要:
Axially substituted tin phthalocyanines, namely dichloride-tetra-(α-pentyloxy) tin (IV) phthalocyanine 2, dihydroxy-tetra-(α-pentyloxy) tin (IV) phthalocyanine 3 and its dimmer di-μ-oxo-tetra-(α-pentyloxy) tin (IV) phthalocyanine 4 were synthesized. The catalytic effect of H2O-free CaCl2 in quinoline was used for condensation of dihydroxy tin phthalocyanine 3 to the cofacially arraydimmer 4. Their structures were characterized by UV-vis, IR, elemental analysis, MS, as well as 1HNMR spectroscopy.
English
Synthesis of di-μ-oxo-tetra-(α-pentyloxy) tin(IV) phthalocyanine
Abstract:
Axially substituted tin phthalocyanines, namely dichloride-tetra-(α-pentyloxy) tin (IV) phthalocyanine 2, dihydroxy-tetra-(α-pentyloxy) tin (IV) phthalocyanine 3 and its dimmer di-μ-oxo-tetra-(α-pentyloxy) tin (IV) phthalocyanine 4 were synthesized. The catalytic effect of H2O-free CaCl2 in quinoline was used for condensation of dihydroxy tin phthalocyanine 3 to the cofacially arraydimmer 4. Their structures were characterized by UV-vis, IR, elemental analysis, MS, as well as 1HNMR spectroscopy.
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Key words:
- Axially substituted tin (IV) phthalocyanine
- / Dimmer
- / Synthesis
- / Characterization
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