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高性能电磁吸收与隔热用界面工程化Mo2C Mxenes

刘东芳 ,  兰笛 ,  尹言泽 ,  孔俊儒 ,  孟彦宏 ,  刘艳 ,  仇亚茹 ,  夏国飞 ,  刘冬

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引用本文: 刘东芳, 兰笛, 尹言泽, 孔俊儒, 孟彦宏, 刘艳, 仇亚茹, 夏国飞, 刘冬. 高性能电磁吸收与隔热用界面工程化Mo2C Mxenes[J]. 物理化学学报, 2026, 42(7): 100275. doi: 10.1016/j.actphy.2026.100275 shu
Citation:  Dongfang Liu,  Di Lan,  Yanze Yin,  Junru Kong,  Yanhong Meng,  Yan Liu,  Yaru Qiu,  Guofei Xia,  Dong Liu. Interface engineered Mo2C high-performance electromagnetic absorption and thermal insulation[J]. Acta Physico-Chimica Sinica, 2026, 42(7): 100275. doi: 10.1016/j.actphy.2026.100275 shu

高性能电磁吸收与隔热用界面工程化Mo2C Mxenes

  • 1.

    山东理工大学化学化工学院, 山东 淄博 255049;

  • 2.

    湖北汽车工业学院汽车材料学院, 湖北 十堰 442002;

  • 3.

    菏泽医学专科学校药学和检验医学系, 山东 菏泽 274000;

  • 4.

    龙腾照明集团股份有限公司, 江苏 扬州 225600

    • 通讯作者: 刘艳,E-mail:liuyan@sdut.edu.cn; 仇亚茹,E-mail:qiuyaru1@163.com; 刘冬,E-mail:liu_dong@sdut.edu.cn
  • 基金项目:

    本研究得到国家自然科学基金(22301168)；山东省自然科学基金(ZR2024QB326)及山东省科技型中小企业创新能力提升工程(2025TSGCCZZB0350)的资助

摘要: 电磁污染问题的日益严重，亟需开发兼具高效吸波与热管理功能的多功能材料。本研究报道了一种基于界面工程化Mo2C MXenes的双功能设计。通过熔盐刻蚀策略，金属离子(Cu/Fe)被原位掺杂到Mo2C中，构建的异质结构显著增强了界面极化与缺陷诱导偶极弛豫。优化后的Mo2C/Fe复合材料展现出卓越的吸波性能，在2.0 mm厚度下实现-41.8 dB的反射损耗及5.12 GHz的宽频带吸收。这种增强效应归因于优化的阻抗匹配与多尺度极化损耗机制的协同作用。此外，所制备的Mo2C/Fe气凝胶具有超低密度(0.0235 g cm-3)和优异隔热性能(80 °C时ΔT < 20 °C)，在中性环境中表现出卓越的耐腐蚀性。本工作为先进MXene基复合材料开发了一种可行的设计策略，展示了其在高效电磁吸收与有效热绝缘方面的双重功能。

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