花瓣状WS2/MnFe2O4/GNs复合材料展现出高效电磁波吸收性能

引用本文: 朱耿素, 马媛媛, 孙承志, 李梦婷, 王春雨, 钟博, 夏龙. 花瓣状WS₂/MnFe₂O₄/GNs复合材料展现出高效电磁波吸收性能[J]. 物理化学学报, 2026, 42(9): 100273. doi: 10.1016/j.actphy.2026.100273 shu

Citation: Gengsu Zhu, Yuanyuan Ma, Chengzhi Sun, Mengting Li, Chunyu Wang, Bo Zhong, Long Xia. Preparation and absorption properties of petal-clustered WS₂/MnFe₂/O₄/GNs composite materials[J]. Acta Physico-Chimica Sinica, 2026, 42(9): 100273. doi: 10.1016/j.actphy.2026.100273 shu

花瓣状WS₂/MnFe₂O₄/GNs复合材料展现出高效电磁波吸收性能

朱耿素 ^{2, 3,} ,
马媛媛 ^2, ,
孙承志 ^2, ,
李梦婷 ^2, ,
王春雨 ^{1, 2,
,} ,
钟博 ^{2,
,} ,
夏龙 ^{2,
,}

1.
哈尔滨工业大学(威海)材料结构精密焊接与连接全国重点实验室, 山东威海 264209
2.
哈尔滨工业大学(威海)材料科学与工程学院, 山东威海 264209
3.
西北工业大学化学与化工学院, 陕西西安 710072

通讯作者: Email: wcyadam@126.com (王春雨); zhongbo@hit.edu.cn (钟博); xialong@hit.edu.cn (夏龙)

摘要: 异质界面的合理构造是改善材料吸波性能一种有效的方法。本研究采用简便的两步水热法合成花瓣状WS₂/MnFe₂O₄/GNs复合材料(其中GNs为石墨烯)。WS₂均匀包覆在多面体MnFe₂O₄颗粒上附着于GNs表面，形成多层三维异质结构。通过调节MnFe₂O₄/GNs的负载量，可有效调控三元复合材料的电磁波吸收特性。当负载量为20%时，RL_min达−44.50 dB，最大有效吸收带宽达4.08 GHz。这归功于花状WS₂、多面体MnFe₂O₄与GNs共同构成的多级微结构，多层结构的存在使得电磁波的反射路径更加丰富，通过多次反射增强能量耗散，另一方面，它改善了材料的阻抗匹配，并强化了磁损耗与介质损耗的协同效应。

关键词:

English

Preparation and absorption properties of petal-clustered WS₂/MnFe₂/O₄/GNs composite materials

Gengsu Zhu ^{2, 3,} ,
Yuanyuan Ma ^2, ,
Chengzhi Sun ^2, ,
Mengting Li ^2, ,
Chunyu Wang ^{1, 2,
,} ,
Bo Zhong ^{2,
,} ,
Long Xia ^{2,
,}

1.
State Key Laboratory of Precision Welding & Joining of Materials and Structures, Harbin Institute of Technology (Weihai), Weihai 264209, Shandong Province, China
2.
School of Materials Science and Engineering, Harbin Institute of Technology (Weihai), Weihai 264209, Shandong Province, China
3.
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, Shaanxi Province, China

Corresponding author: Email: wcyadam@126.com (Chunyu Wang); zhongbo@hit.edu.cn (Bo Zhong); xialong@hit.edu.cn (Long Xia)

Received Date: 25 January 2026
Accepted Date: 01 March 2026
Revised Date: 26 February 2026
Available Online: 15 September 2026

Abstract: Rational construction of heterointerfaces represents an effective strategy for exploring high-performance electromagnetic wave absorption. This study employs a simple two-step hydrothermal method to synthesize petal-clustered WS₂/MnFe₂O₄/GNs (where GNs denotes graphene) hybrid materials. WS₂ uniformly coats the polyhedral MnFe₂O₄ particles attached to the GNs surface, forming a multi-layer three-dimensional hetero-structure. By adjusting the MnFe₂O₄/GNs loading, the electromagnetic wave absorption properties of the ternary hybrid material can be effectively tuned. At a MnFe₂O₄/GNs loading of 20%, the minimum reflection loss reaches −44.50 dB, with a maximum effective absorption bandwidth of 4.08 GHz. This is attributed to the multilevel microstructure formed by flower-like WS₂, polyhedral MnFe₂O₄, and GNs.

Key words:

1. [1]
  J. Wen, Y. Liu, S. Hui, L. Deng, L. Zhang, X. Fan, Q. Chen, X. Liu, X. Li, N. Yan; et al., Matter 8 (9) (2025) 12, https://doi.org/10.1016/j.matt.2025.102151. doi: 10.1016/j.matt.2025.102151
2. [2]
  Y. Miao, A. Cui, C. Wang, Z. Tian, T. Wang, J. Liu, Q. Jia, Z. Li, M. Zhang, Adv. Funct. Mater. 35 (33) (2025) 11, https://doi.org/10.1002/adfm.202503394. doi: 10.1002/adfm.202503394
3. [3]
  H. Xu, Y. Wang, M. Liu, Y. Zhai, ACS Appl. Mater. Interfaces 17 (33) (2025) 47679, https://doi.org/10.1021/acsami.5c09658. doi: 10.1021/acsami.5c09658
4. [4]
  Q. Zhang, D. Lan, S. Deng, J. Gu, Y. Wang, J. Ren, G. Wu, Z. Jia, Carbon 226 (2024) 10, https://doi.org/10.1016/j.carbon.2024.119233. doi: 10.1016/j.carbon.2024.119233
5. [5]
  M. Shi, Z. Jia, D. Lan, Z. Gao, S. Zhang, G. Wu, Adv. Funct. Mater. (2025) 16, https://doi.org/10.1002/adfm.202528665. doi: 10.1002/adfm.202528665
6. [6]
  H. Liu, W. Xu, H. Ren, D. Li, J. He, L. Xia, Y. Xu, B. Zeng, C. Yuan, L. Dai, Chem. Eng. J. 486 (2024) 11, https://doi.org/10.1016/j.cej.2024.150444. doi: 10.1016/j.cej.2024.150444
7. [7]
  Z. Jia, J. Liu, Z. Gao, C. Zhang, G. Wu, Adv. Funct. Mater. 35 (18) (2025) 13, https://doi.org/10.1002/adfm.202405523. doi: 10.1002/adfm.202405523
8. [8]
  X. Ren, D. Lan, Z. Gao, S. Zhang, Y. Zhang, M. He, Z. Jia, G. Wu, J. Mater. Sci. Technol. 255 (2026) 236, https://doi.org/10.1016/j.jmst.2025.09.001. doi: 10.1016/j.jmst.2025.09.001
9. [9]
  J. Cheng, Y. Jin, J. Zhao, Q. Jing, B. Gu, J. Wei, S. Yi, M. Li, W. Nie, Q. Qin; et al., Nano-Micro Lett. 16 (1) (2024) 40, https://doi.org/10.1007/s40820-023-01247-7. doi: 10.1007/s40820-023-01247-7
10. [10]
  H. Zhang, J. Cheng, H. Wang, Z. Huang, Q. Zheng, G. Zheng, D. Zhang, R. Che, M. Cao, Adv. Funct. Mater. 32 (6) (2022) 10, https://doi.org/10.1002/adfm.202108194. doi: 10.1002/adfm.202108194
11. [11]
  Y. Shen, Z. Ma, F. Yan, C. Zhu, X. Zhang, Y. Chen, Adv. Funct. Mater. 35 (26) (2025) 11, https://doi.org/10.1002/adfm.202423947. doi: 10.1002/adfm.202423947
12. [12]
  Q. Wang, X. Su, Y. Jia, Y. Liu, F. Shahzad, Ceram. Int. 51 (8) (2025) 9833, https://doi.org/10.1016/j.ceramint.2024.12.415. doi: 10.1016/j.ceramint.2024.12.415
13. [13]
  Z. Jia, J. Li, D. Lan, S. Zhang, Z. Gao, X. Shi, G. Wu, J. Mater. Sci. Technol. 256 (2026) 246, https://doi.org/10.1016/j.jmst.2025.08.044. doi: 10.1016/j.jmst.2025.08.044
14. [14]
  X. Liu, S. Zhang, M. Yu, X. Zhao, Y. Jia, Y. Huang, M. Zong, Chem. Eng. J. 465 (2023) 10, https://doi.org/10.1016/j.cej.2023.142932. doi: 10.1016/j.cej.2023.142932
15. [15]
  J. Wang, Y. Wang, J. Cheng, Y. Fu, Y. Li, W. Nie, J. Wang, B. Liu, D. Zhang, G. Zheng; et al., J. Mater. Sci. Technol. 194 (2024) 193, https://doi.org/10.1016/j.jmst.2024.01.085.
16. [16]
  Y. Guo, H. Liu, D. Wang, Z. El-Bahy, J. Althakafy, H. Abo-Dief, Z. Guo, B. Xu, C. Liu, C. Shen, Nano Res. 15 (8) (2022) 6841, https://doi.org/10.1007/s12274-022-4533-x.
17. [17]
  J. Bai, S. Huang, X. Yao, X. Liu, Z. Huang, J. Mater. Chem. C 12 (16) (2024) 5776, https://doi.org/10.1039/d3tc04672a. doi: 10.1039/d3tc04672a
18. [18]
  H. Peng, D. Zhang, Z. Xie, S. Lu, Y. Liu, F. Liang, Small 21 (8) (2025) 24, https://doi.org/10.1002/smll.202408570. doi: 10.1002/smll.202408570
19. [19]
  J. Chen, Z. Liu, L. Zhang, C. Liu, C. Zhu, H. Wang, P. Liu, Carbon 243 (2025) 11, https://doi.org/10.1016/j.carbon.2025.120575. doi: 10.1016/j.carbon.2025.120575
20. [20]
  H. Xu, H. Zhan, Z. Xu, C. Jing, Q. Chen, M. Zhu, L. Kong, X. Fan, Y. Qing, S. Wen; et al., Adv. Funct. Mater. 35 (23) (2025) 11, https://doi.org/10.1002/adfm.202421242.
21. [21]
  Z. Guo, D. Lan, Z. Jia, Z. Gao, X. Shi, M. He, H. Guo, G. Wu, P. Yin, Nano-Micro Lett. 17 (1) (2025) 21, https://doi.org/10.1007/s40820-024-01527-w. doi: 10.1007/s40820-024-01527-w
22. [22]
  D. Zhang, T. Liu, J. Cheng, Q. Cao, G. Zheng, S. Liang, H. Wang, M. Cao, Nano-Micro Lett. 11 (1) (2019) 15, https://doi.org/10.1007/s40820-019-0270-4. doi: 10.1007/s40820-019-0270-4
23. [23]
  J. Zhou, X. Huang, D. Lan, Z. Jia, G. Wu, Carbon 248 (2026) 10, https://doi.org/10.1016/j.carbon.2025.121143. doi: 10.1016/j.carbon.2025.121143
24. [24]
  T. Hu, D. Lan, J. Wang, X. Zhong, G. Bu, P. Yin, Carbon 232 (2025) 13, https://doi.org/10.1016/j.carbon.2024.119798. doi: 10.1016/j.carbon.2024.119798
25. [25]
  W. Zhao, Z. Guo, D. Lan, Z. Jia, S. Zhang, G. Wu, Small 21 (45) (2025) 10, https://doi.org/10.1002/smll.202509339. doi: 10.1002/smll.202509339
26. [26]
  X. Zhao, Y. Huang, H. Jiang, X. Liu, X. Ma, P. Liu, M. Zong, Compos. Pt. A-Appl. Sci. Manuf. 188 (2025) 9, https://doi.org/10.1016/j.compositesa.2024.108565. doi: 10.1016/j.compositesa.2024.108565
27. [27]
  D. Mandal, K. Mandal, J. Appl. Phys. 129 (7) (2021) 10, https://doi.org/10.1063/5.0039560. doi: 10.1063/5.0039560
28. [28]
  Y. Yang, S. Xu, Q. Huang, Q. Ren, S. Chen, Z. Jin, Y. Ge, W. Liao, W. Xu, H. Xu; et al., Mater. Res. Bull. 178 (2024) 12, https://doi.org/10.1016/j.materresbull.2024.112907.
29. [29]
  C. Li, M. Piao, H. Zhang, X. Wang, J. Alloy. Compd. 912 (2022) 10, https://doi.org/10.1016/j.jallcom.2022.165269. doi: 10.1016/j.jallcom.2022.165269
30. [30]
  Y. Yang, K. Logesh, S. Mehrez, I. Huynen, I. Elbadawy, V. Mohanavel, S. Alamri, Ceram. Int. 49 (2) (2023) 2130, https://doi.org/10.1016/j.ceramint.2022.09.179. doi: 10.1016/j.ceramint.2022.09.179
31. [31]
  D. Zhang, H. Wang, J. Cheng, C. Han, X. Yang, J. Xu, G. Shan, G. Zheng, M. Cao, Appl. Surf. Sci. 528 (2020) 11, https://doi.org/10.1016/j.apsusc.2020.147052. doi: 10.1016/j.apsusc.2020.147052
32. [32]
  W. Guo, H. Zhu, Q. Ren, S. Chen, Y. Ding, C. Xiong, J. Chen, X. Jia, Solid State Sci. 138 (2023) 107152, https://doi.org/10.1016/j.solidstatesciences.2023.107152. doi: 10.1016/j.solidstatesciences.2023.107152
33. [33]
  Z. Guo, X. Zhang, C. Lv, S. Zhang, Z. Gao, Z. Jia, D. Lan, G. Wu, Carbon 234 (2025) 9, https://doi.org/10.1016/j.carbon.2025.120010. doi: 10.1016/j.carbon.2025.120010
34. [34]
  Y. Guan, R. Shu, B. Liu, Chem. Eng. J. 505 (2025) 12, https://doi.org/10.1016/j.cej.2025.159819. doi: 10.1016/j.cej.2025.159819
35. [35]
  Z. Guo, J. Ren, X. Xu, D. Lan, S. Zhang, M. He, Z. Gao, Z. Jia, G. Wu, J. Mater. Sci. Technol. 236 (2025) 19, https://doi.org/10.1016/j.jmst.2025.03.020. doi: 10.1016/j.jmst.2025.03.020
36. [36]
  S. Zhang, C. Wang, X. Meng, S. Liu, X. Li, Z. Yao, M. Yu, Carbon 237 (2025) 13, https://doi.org/10.1016/j.carbon.2025.120176. doi: 10.1016/j.carbon.2025.120176
37. [37]
  Y. Liu, W. Geng, L. Wang, H. Wang, R. Zhang, D. Lan, B. Fan, Chem. Eng. J. 505 (2025) 12, https://doi.org/10.1016/j.cej.2025.159489. doi: 10.1016/j.cej.2025.159489
38. [38]
  A. Feng, L. Yu, D. Lan, C. Lv, S. Zhang, Z. Gao, Z. Guo, G. Wu, J. Mater. Sci. Technol. 228 (2025) 225, https://doi.org/10.1016/j.jmst.2025.02.001. doi: 10.1016/j.jmst.2025.02.001
39. [39]
  X. Xie, R. Liu, C. Chen, D. Lan, Z. Chen, W. Du, G. Wu, Int. J. Miner. Metall. Mater. 32 (3) (2025) 566, https://doi.org/10.1007/s12613-024-3024-3. doi: 10.1007/s12613-024-3024-3
40. [40]
  Y. Zhang, L. Zhang, H. Si, Y. Zhang, C. Li, L. Zhang, J. Zhang, C. Gong, J. Mater. Sci. Technol. 233 (2025) 69, https://doi.org/10.1016/j.jmst.2025.01.046. doi: 10.1016/j.jmst.2025.01.046
41. [41]
  Z. Deng, L. Wang, B. Peng, L. Ye, Z. Li, Z. Shi, W. Dong, C. Chen, Y. Hu, S. Rehman, Chem. Eng. J. 505 (2025) 12, https://doi.org/10.1016/j.cej.2025.159457. doi: 10.1016/j.cej.2025.159457
42. [42]
  T. Wang, W. Zhao, Y. Miao, A. Cui, C. Gao, C. Wang, L. Yuan, Z. Tian, A. Meng, Z. Li; et al., Nano-Micro Lett. 16 (1) (2024) 21, https://doi.org/10.1007/s40820-024-01478-2. doi: 10.1007/s40820-024-01478-2
43. [43]
  S. Feng, H. Wang, J. Ma, Z. Lin, C. Wang, X. Li, M. Ma, T. Li, Y. Ma, Compos. Pt. B-Eng. 275 (2024) 14, https://doi.org/10.1016/j.compositesb.2024.111344. doi: 10.1016/j.compositesb.2024.111344
44. [44]
  L. Zhu, W. Wu, J. Chen, Z. Hu, J. Yu, Y. Wang, Chem. Eng. J. 488 (2024) 9, https://doi.org/10.1016/j.cej.2024.150649. doi: 10.1016/j.cej.2024.150649
45. [45]
  H. Liang, Y. Guo, S. Hui, Z. Hou, Z. Wang, H. Shen, H. Wu, Carbon 243 (2025) 10, https://doi.org/10.1016/j.carbon.2025.120605. doi: 10.1016/j.carbon.2025.120605
46. [46]
  D. Wu, C. Fan, W. Luo, Y. Jin, Q. He, Y. Wang, Inorg. Chem. Front. 12 (8) (2025) 3083, https://doi.org/10.1039/d5qi00118h. doi: 10.1039/d5qi00118h
47. [47]
  X. Zhong, M. He, C. Zhang, Y. Guo, J. Hu, J. Gu, Adv. Funct. Mater. 34 (19) (2024) 13, https://doi.org/10.1002/adfm.202313544. doi: 10.1002/adfm.202313544
48. [48]
  C. Wang, W. Kong, G. Li, M. Zhang, Y. Zhang, Z. Liu, L. Zu, W. Ding, H. Zhang, S. Tan, J. Alloy. Compd. 1005 (2024) 11, https://doi.org/10.1016/j.jallcom.2024.176203. doi: 10.1016/j.jallcom.2024.176203
49. [49]
  J. Zhao, M. He, H. Guo, Y. Zhang, H. Qiu, H. Lai, J. Mater. Sci. Technol. 218 (2025) 35, https://doi.org/10.1016/j.jmst.2024.08.034. doi: 10.1016/j.jmst.2024.08.034
50. [50]
  S. Yan, S. Shao, Y. Tang, X. Zhang, C. Guo, L. Wang, J. Liu, L. Wu, F. Wang, ACS Appl. Mater. Interfaces 16 (28) (2024) 36962, https://doi.org/10.1021/acsami.4c05903. doi: 10.1021/acsami.4c05903
51. [51]
  M. Li, F. Wei, Q. Chen, Z. Xue, C. Yao, X. Zhou, M. Liu, B. Fan, S. Xu, Ceram. Int. 51 (15) (2025) 21055, https://doi.org/10.1016/j.ceramint.2025.02.274. doi: 10.1016/j.ceramint.2025.02.274
52. [52]
  X. Ren, Z. Jia, Z. Gao, S. Zhang, Y. Zhang, D. Lan, G. Wu, Adv. Funct. Mater. (2025) 11, https://doi.org/10.1002/adfm.202524264. doi: 10.1002/adfm.202524264

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

花瓣状WS₂/MnFe₂O₄/GNs复合材料展现出高效电磁波吸收性能

通讯作者: Email: wcyadam@126.com (王春雨); zhongbo@hit.edu.cn (钟博); xialong@hit.edu.cn (夏龙)

English

Preparation and absorption properties of petal-clustered WS₂/MnFe₂/O₄/GNs composite materials

Corresponding author: Email: wcyadam@126.com (Chunyu Wang); zhongbo@hit.edu.cn (Bo Zhong); xialong@hit.edu.cn (Long Xia)

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