分子偶极工程调控MXene/ZnO异质结构的介电性能

引用本文: 王嘉浩, 蔡博, 孙博文, 侯志灵, 杨树豪, 杨青林, 赵培炎, 李文萍, 张宇, 王广胜. 分子偶极工程调控MXene/ZnO异质结构的介电性能[J]. 物理化学学报, 2026, 42(6): 100271. doi: 10.1016/j.actphy.2026.100271 shu

Citation: Jia-Hao Wang, Bo Cai, Bowen Sun, Zhi-Ling Hou, Shu-Hao Yang, Qinglin Yang, Pei-Yan Zhao, Wen-Ping Li, Yu Zhang, Guang-Sheng Wang. Molecular dipole engineering for tailored dielectric properties in MXene/ZnO heterostructures[J]. Acta Physico-Chimica Sinica, 2026, 42(6): 100271. doi: 10.1016/j.actphy.2026.100271 shu

分子偶极工程调控MXene/ZnO异质结构的介电性能

王嘉浩 ^1,2, ,
蔡博 ^1,2, ,
孙博文 ^{1,
,} ,
侯志灵 ^3, ,
杨树豪 ^1,2, ,
杨青林 ^1, ,
赵培炎 ^2, ,
李文萍 ^{4,
,} ,
张宇 ^2,5, ,
王广胜 ^{1,2,
,}

1.
北京航空航天大学国际创新研究院(北京航空航天大学国际创新学院), 浙江杭州 311115;
2.
北京航空航天大学化学学院, 北京 100191;
3.
北京工业大学物理与光电工程学院, 北京 100124;
4.
北京航空航天大学物理学院, 北京 100191;
5.
西北工业大学化学与化工学院, 陕西西安 710072

通讯作者: 孙博文,E-mail:sunbw@buaa.edu.cn; 李文萍,E-mail:liwp@buaa.edu.cn; 王广胜,E-mail:wanggsh@buaa.edu.cn

基金项目:
本研究获得北京航空航天大学杭州创新研究院科研基金(2024KQ130)和国家自然科学基金(22575012、52373259)资助。

摘要: 由于异质材料的结构较为复杂，通过调控其极化效应来优化介电性能仍具有挑战性。本研究通过分子接枝诱导偶极子重新取向，实现了对界面极化强度的精准调控。实验证明，这些偶极子的取向可以有效调节界面极化：-CF₃基团增强了电荷转移和极化损耗，而-NH₂基团则抑制这些效应。经-CF₃修饰优化的MXene/ZnO复合材料最小反射损耗达到-66.7 dB，有效吸收带宽为5.05 GHz，表现出了卓越的电磁波吸收性能。该工作通过界面偶极子工程展示了一种精确调控电磁参数的新策略，为先进吸波材料的设计提供了新思路。

关键词:

English

Molecular dipole engineering for tailored dielectric properties in MXene/ZnO heterostructures

1.
Hangzhou International Innovation Institute, Beihang University, Hangzhou 311115, Zhejiang Province, China;
2.
School of Chemistry, Beihang University, Beijing 100191, China;
3.
School of Physics and Optoelectronic Engineering, Beijing University of Technology, Beijing 100124, China;
4.
School of Physics, Beihang University, Beijing 100191, China;
5.
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, Shaanxi Province, China

Corresponding author: Bowen Sun, ; Wen-Ping Li, ; Guang-Sheng Wang,

Received Date: 16 January 2026
Accepted Date: 27 February 2026
Revised Date: 26 February 2026

Abstract: The optimization of dielectric properties through controlling polarization effects in heterogeneous materials remains challenging due to structural complexity. This work demonstrates the precise regulation of interface polarization strength through molecular grafting-induced dipole reorientation. Experimental analyses confirm that the orientation of these dipoles effectively modulates the interfacial polarization: the -CF₃ group enhances, while the -NH₂ group suppresses electron transfer and polarization loss effects. The optimized MXene/ZnO modified with -CF₃ composite exhibits exceptional electromagnetic wave absorption performance, achieving a minimum reflection loss of -66.7 dB and an effective absorption bandwidth of 5.05 GHz. This work demonstrates a novel strategy for the precise tuning of electromagnetic parameters through interfacial dipole engineering, offering new insights for the design of advanced electromagnetic wave-absorbing materials.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

分子偶极工程调控MXene/ZnO异质结构的介电性能

通讯作者: 孙博文,E-mail:sunbw@buaa.edu.cn; 李文萍,E-mail:liwp@buaa.edu.cn; 王广胜,E-mail:wanggsh@buaa.edu.cn

English

Molecular dipole engineering for tailored dielectric properties in MXene/ZnO heterostructures

Corresponding author: Bowen Sun, ; Wen-Ping Li, ; Guang-Sheng Wang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

分子偶极工程调控MXene/ZnO异质结构的介电性能

通讯作者: 孙博文,E-mail:sunbw@buaa.edu.cn; 李文萍,E-mail:liwp@buaa.edu.cn; 王广胜,E-mail:wanggsh@buaa.edu.cn

English

Molecular dipole engineering for tailored dielectric properties in MXene/ZnO heterostructures

Corresponding author: Bowen Sun, ; Wen-Ping Li, ; Guang-Sheng Wang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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