范德华S型异质结赋予快速电荷转移助力光催化活性提升

引用本文: 许凯强, 于佳, 夏伟, 张建军, 韩生. 范德华S型异质结赋予快速电荷转移助力光催化活性提升[J]. 物理化学学报, 2026, 42(7): 100211. doi: 10.1016/j.actphy.2025.100211 shu

Citation: Kaiqiang Xu, Jia Yu, Wei Xia, Jianjun Zhang, Sheng Han. Rapid charge transfer endowed by van der Waals S-scheme heterojunction for boosting photocatalytic activity[J]. Acta Physico-Chimica Sinica, 2026, 42(7): 100211. doi: 10.1016/j.actphy.2025.100211 shu

范德华S型异质结赋予快速电荷转移助力光催化活性提升

许凯强 ^1, ,
于佳 ^1, ,
夏伟 ^2, ,
张建军 ^{2,
,} ,
韩生 ^{1,
,}

1.
上海应用技术大学化学与环境工程学院, 上海 201418;
2.
中国地质大学(武汉)材料与化学学院太阳燃料实验室, 湖北武汉 430078

通讯作者: 张建军,E-mail:zhangjianjun@cug.edu.cn; 韩生,E-mail:hansheng654321@sina.com

基金项目:
本研究得到环境光催化应用技术湖南省重点实验室开放项目(2214505)；上海应用技术大学引进人才科研启动项目(YJ2023-7)；国家自然科学基金(22278269)；教育部联合基金(8091B02052304)；新疆生产建设兵团引导计划项目(2024ZD013)；上海市教育委员会科研项目(2023ZKZD54)；上海市产业协同创新项目(XTCX-KJ-2022-70)的资助

摘要: 合理设计高效梯型(S型)异质结已成为当前光催化领域的一项重要突破，在推动环境友好型生态修复与能源转化技术的发展方面具有巨大潜力。然而，传统S型异质结普遍存在晶格失配问题，导致界面内建电场削弱，从而限制了光生载流子的有效分离。为克服这一瓶颈，本研究提出了一种创新的原位沉积策略，在Bi₂O₂S-BiOBr复合体系中成功构建了范德华S型异质结。该策略有效缓解了晶格失配，实现了紧密的界面结合，从而形成强效内建电场，显著促进了载流子的高效迁移与分离。Bi₂O₂S-BiOBr复合材料光吸收范围超过700 nm，并在氙灯照射下对环丙沙星(CIP)展现出优异的光催化降解性能。其中，20%Bi₂O₂S-BiOBr在15 min内即可实现93%的CIP去除率，显著优于所有对比样品。这种显著的性能提升源于范德华S型异质结中光生载流子高效分离与传输效率。本研究为范德华S型异质结的理性设计提供了新的思路与理论支撑。

关键词:

English

Rapid charge transfer endowed by van der Waals S-scheme heterojunction for boosting photocatalytic activity

Kaiqiang Xu ^1, ,
Jia Yu ^1, ,
Wei Xia ^2, ,
Jianjun Zhang ^{2,
,} ,
Sheng Han ^{1,
,}

1.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China;
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430078, Hubei Province, China

Corresponding author: Jianjun Zhang, ; Sheng Han,

Received Date: 30 September 2025
Accepted Date: 22 October 2025
Revised Date: 21 October 2025

Abstract: The rational design of efficient step-scheme (S-scheme) heterojunctions is a significant breakthrough in photocatalysis, holding great potential to enhance eco-friendly environmental restoration and energy conversion technologies. However, conventional S-scheme heterojunctions frequently suffer from lattice mismatch issues, which severely compromise the efficacy of built-in electric fields in charge separation. To address this limitation, we developed an innovative in situ deposition strategy to construct van der Waals S-scheme heterojunctions within Bi₂O₂S-BiOBr composites. This approach effectively mitigates lattice mismatch and ensures intimate interfacial contact, enabling the formation of a strong internal electric field that facilitates efficient carrier migration. The Bi₂O₂S-BiOBr composites exhibit an extended light absorption range exceeding 700 nm, allowing for broad-spectrum photocatalytic activity. Under Xenon lamp irradiation, the Bi₂O₂S-BiOBr composites demonstrated outstanding photocatalytic efficiency in the degradation of ciprofloxacin (CIP). Notably, the 20%Bi₂O₂S-BiOBr composite achieved 93% CIP removal within 15 min, outperforming all other tested composites. The notable enhancement in performance stems from the van der Waals S-scheme heterojunction, which facilitates highly efficient separation of photogenerated carriers. This work provides valuable insights for the strategic design of advanced van der Waals heterostructures with S-scheme charge transfer mechanisms.

Key words:

1. [1]
  Z. Su, K. Wang, F. Yang, T. Zhuang, Water Res. 235 (2023) 119867, https://doi.org/10.1016/j.watres.2023.119867.Z. Su, K. Wang, F. Yang, T. Zhuang, Water Res. 235 (2023) 119867, https://doi.org/10.1016/j.watres.2023.119867.
2. [2]
  K. Guo, C. Yu, B. Gao, B. Liu, Z. Wang, Y. Wang, Q. Yue, Y. Gao, Water Res. 244 (2023) 120483, https://doi.org/10.1016/j.watres.2023.120483.K. Guo, C. Yu, B. Gao, B. Liu, Z. Wang, Y. Wang, Q. Yue, Y. Gao, Water Res. 244 (2023) 120483, https://doi.org/10.1016/j.watres.2023.120483.
3. [3]
  Q. Chen, C. Liu, R. Liu, Y. Hou, J. Bi, J. C. Yu, L. Wu, Sep. Purif. Technol. 355 (2025) 129768, https://doi.org/10.1016/j.seppur.2024.129768.Q. Chen, C. Liu, R. Liu, Y. Hou, J. Bi, J. C. Yu, L. Wu, Sep. Purif. Technol. 355 (2025) 129768, https://doi.org/10.1016/j.seppur.2024.129768.
4. [4]
  D. Liu, L. Jiang, D. Chen, Z. Hao, B. Deng, Y. Sun, X. Liu, B. Jia, L. Chen, H. Liu, Chem. Eng. J. 482 (2024) 149165, https://doi.org/10.1016/j.cej.2024.149165.D. Liu, L. Jiang, D. Chen, Z. Hao, B. Deng, Y. Sun, X. Liu, B. Jia, L. Chen, H. Liu, Chem. Eng. J. 482 (2024) 149165, https://doi.org/10.1016/j.cej.2024.149165.
5. [5]
  Q. F. Han, C. Song, X. Sun, S. Zhao, S. G. Wang, Chemosphere 279 (2021) 130381, https://doi.org/10.1016/j.chemosphere.2021.130381.Q. F. Han, C. Song, X. Sun, S. Zhao, S. G. Wang, Chemosphere 279 (2021) 130381, https://doi.org/10.1016/j.chemosphere.2021.130381.
6. [6]
  J. Sun, H. Liu, S. Wang, Y. Zhang, C. Bie, L. Zhang, J. Materiomics 11 (2025) 100975, https://doi.org/10.1016/j.jmat.2024.100975.J. Sun, H. Liu, S. Wang, Y. Zhang, C. Bie, L. Zhang, J. Materiomics 11 (2025) 100975, https://doi.org/10.1016/j.jmat.2024.100975.
7. [7]
  Y. Zhao, Y. Zhang, H. Tan, C. Ai, J. Zhang, J. Materiomic 11 (2025) 100970, https://doi.org/10.1016/j.jmat.2024.100970.Y. Zhao, Y. Zhang, H. Tan, C. Ai, J. Zhang, J. Materiomic 11 (2025) 100970, https://doi.org/10.1016/j.jmat.2024.100970.
8. [8]
  B. Zhang, B. Sun, F. Liu, T. Gao, G. Zhou, Sci. China Mater. 67 (2024) 424, https://doi.org/10.1007/s40843-023-2754-8.B. Zhang, B. Sun, F. Liu, T. Gao, G. Zhou, Sci. China Mater. 67 (2024) 424, https://doi.org/10.1007/s40843-023-2754-8.
9. [9]
  M. Sayed, K. Qi, X. Wu, L. Zhang, H. García, J. Yu, Chem. Soc. Rev. 54 (2025) 4874, https://doi.org/10.1039/D4CS01091D.M. Sayed, K. Qi, X. Wu, L. Zhang, H. García, J. Yu, Chem. Soc. Rev. 54 (2025) 4874, https://doi.org/10.1039/D4CS01091D.
10. [10]
  S. Mao, R. He, S. Song, Chinese J. Catal. 64 (2024) 1, https://doi.org/10.1016/S1872-2067(24)60102-6.S. Mao, R. He, S. Song, Chinese J. Catal. 64 (2024) 1, https://doi.org/10.1016/S1872-2067(24)60102-6.
11. [11]
  Y. Wu, Y. Yang, M. Gu, C. Bie, H. Tan, B. Cheng, J. Xu, Chin. J. Catal. 53 (2023) 123, https://doi.org/10.1016/S1872-2067(23)64514-0.Y. Wu, Y. Yang, M. Gu, C. Bie, H. Tan, B. Cheng, J. Xu, Chin. J. Catal. 53 (2023) 123, https://doi.org/10.1016/S1872-2067(23)64514-0.
12. [12]
  B. Liu, J. Cai, J. Zhang, H. Tan, B. Cheng, J. Xu, Chin. J. Catal. 51 (2023) 204, https://doi.org/10.1016/S1872-2067(23)64466-3.B. Liu, J. Cai, J. Zhang, H. Tan, B. Cheng, J. Xu, Chin. J. Catal. 51 (2023) 204, https://doi.org/10.1016/S1872-2067(23)64466-3.
13. [13]
  M. Li, X. Li, J. B. Ghasemi, Chin. J. Catal. 73 (2025) 12, https://doi.org/10.1016/S1872-2067(25)64709-7.M. Li, X. Li, J. B. Ghasemi, Chin. J. Catal. 73 (2025) 12, https://doi.org/10.1016/S1872-2067(25)64709-7.
14. [14]
  W. Yu, Chin. J. Catal. 73 (2025) 8, https://doi.org/10.1016/S1872-2067(25)60706-1.W. Yu, Chin. J. Catal. 73 (2025) 8, https://doi.org/10.1016/S1872-2067(25)60706-1.
15. [15]
  X. Li, J. Cao, X. Jia, S. Li, X. Jin, Q. Wang, S. Chen, H. Lin, Appl. Catal. B Environ. Energy 362 (2025) 124713, https://doi.org/10.1016/j.apcatb.2024.124713.X. Li, J. Cao, X. Jia, S. Li, X. Jin, Q. Wang, S. Chen, H. Lin, Appl. Catal. B Environ. Energy 362 (2025) 124713, https://doi.org/10.1016/j.apcatb.2024.124713.
16. [16]
  Z. Li, C. Wen, D. Li, Z. Fang, Z. Lin, D. Liu, Y. Wang, X. Zhang, P. Chen, W. Lv, G. Liu, Chem. Eng. J. 492 (2024) 152449, https://doi.org/10.1016/j.cej.2024.152449.Z. Li, C. Wen, D. Li, Z. Fang, Z. Lin, D. Liu, Y. Wang, X. Zhang, P. Chen, W. Lv, G. Liu, Chem. Eng. J. 492 (2024) 152449, https://doi.org/10.1016/j.cej.2024.152449.
17. [17]
  R. Jiang, G. Lu, T. Dang, M. Wang, J. Liu, Z. Yan, Sep. Purif. Technol. 320 (2023) 124134, https://doi.org/10.1016/j.seppur.2023.124134.R. Jiang, G. Lu, T. Dang, M. Wang, J. Liu, Z. Yan, Sep. Purif. Technol. 320 (2023) 124134, https://doi.org/10.1016/j.seppur.2023.124134.
18. [18]
  D. Li, L. Li, Y. Liu, Y. Wang, H. Li, Z. Hou, H. Lin, Z. Asghar, Y. Zhang, J. Hou, Sol. Energy 287 (2025) 113226, https://doi.org/10.1016/j.solener.2024.113226.D. Li, L. Li, Y. Liu, Y. Wang, H. Li, Z. Hou, H. Lin, Z. Asghar, Y. Zhang, J. Hou, Sol. Energy 287 (2025) 113226, https://doi.org/10.1016/j.solener.2024.113226.
19. [19]
  Y. Wang, Z. Fan, Y. Wan, M. Xu, J. Li, Y. Ling, Y. Xie, K. Yang, X. Li, Appl. Catal. B Environ. Energy 366 (2025) 125017, https://doi.org/10.1016/j.apcatb.2024.125017.Y. Wang, Z. Fan, Y. Wan, M. Xu, J. Li, Y. Ling, Y. Xie, K. Yang, X. Li, Appl. Catal. B Environ. Energy 366 (2025) 125017, https://doi.org/10.1016/j.apcatb.2024.125017.
20. [20]
  X. He, X. Zhong, W. Si, Z. Zhao, H. Wang, X. Zhang, Y. Xie, Nano Lett. 24 (2024) 6545, https://doi.org/10.1021/acs.nanolett.4c00951.X. He, X. Zhong, W. Si, Z. Zhao, H. Wang, X. Zhang, Y. Xie, Nano Lett. 24 (2024) 6545, https://doi.org/10.1021/acs.nanolett.4c00951.
21. [21]
  M. Gu, Y. Yang, B. Cheng, L. Zhang, P. Xiao, T. Chen, Chin. J. Catal. 59 (2024) 185, https://doi.org/10.1016/S1872-2067(23)64610-8.M. Gu, Y. Yang, B. Cheng, L. Zhang, P. Xiao, T. Chen, Chin. J. Catal. 59 (2024) 185, https://doi.org/10.1016/S1872-2067(23)64610-8.
22. [22]
  Y. Zhang, S. Wang, Chin. J. Catal. 71 (2025) 1, https://doi.org/10.1016/S1872-2067(24)60253-6.Y. Zhang, S. Wang, Chin. J. Catal. 71 (2025) 1, https://doi.org/10.1016/S1872-2067(24)60253-6.
23. [23]
  F. Xu, F. Zhao, X. Deng, J. Zhang, J. Zhang, C. Ai, J. Yu, H. García, Nat. Commun. 16 (2025) 6882, https://doi.org/10.1038/s41467-025-60961-5.F. Xu, F. Zhao, X. Deng, J. Zhang, J. Zhang, C. Ai, J. Yu, H. García, Nat. Commun. 16 (2025) 6882, https://doi.org/10.1038/s41467-025-60961-5.
24. [24]
  L. Wang, J. Zhao, J. Mater. Sci. Technol. 241 (2026) 18, https://doi.org/10.1016/j.jmst.2025.04.009.L. Wang, J. Zhao, J. Mater. Sci. Technol. 241 (2026) 18, https://doi.org/10.1016/j.jmst.2025.04.009.
25. [25]
  D. Xu, R. He, Z. Jiang, J. Mater. Sci. Technol. 236 (2025) 280, https://doi.org/10.1016/j.jmst.2025.02.040.D. Xu, R. He, Z. Jiang, J. Mater. Sci. Technol. 236 (2025) 280, https://doi.org/10.1016/j.jmst.2025.02.040.
26. [26]
  X. Li, Z. Wang, Acta Phys. Chim. Sin. 41 (2025) 100080, https://doi.org/10.1016/j.actphy.2025.100080.X. Li, Z. Wang, Acta Phys. Chim. Sin. 41 (2025) 100080, https://doi.org/10.1016/j.actphy.2025.100080.
27. [27]
  B. Liu, J. Zhang, H. Li, B. Cheng, C. Bie, Acta Phys. Chim. Sin. 41 (2025) 100121, https://doi.org/10.1016/j.actphy.2025.100121.B. Liu, J. Zhang, H. Li, B. Cheng, C. Bie, Acta Phys. Chim. Sin. 41 (2025) 100121, https://doi.org/10.1016/j.actphy.2025.100121.
28. [28]
  G. Tang, J. Zhang, C. Bie, X. Zheng, C. Jiang, J. Yu, Adv. Mater. 37 (2025) 2514576, https://doi.org/10.1002/adma.202514576.G. Tang, J. Zhang, C. Bie, X. Zheng, C. Jiang, J. Yu, Adv. Mater. 37 (2025) 2514576, https://doi.org/10.1002/adma.202514576.
29. [29]
  X. Wu, M. Sayed, G. Wang, W. Yu, B. Zhu, Adv. Mater. 37 (2025) 2511322, https://doi.org/10.1002/adma.202511322.X. Wu, M. Sayed, G. Wang, W. Yu, B. Zhu, Adv. Mater. 37 (2025) 2511322, https://doi.org/10.1002/adma.202511322.
30. [30]
  M. Gu, J. Zhang, I.V. Kurganskii, A.S. Poryvaev, M.V. Fedin, B. Cheng, J. Yu, L. Zhang, Adv. Mater. 37 (2025) 2414803, https://doi.org/10.1002/adma.202414803.M. Gu, J. Zhang, I.V. Kurganskii, A.S. Poryvaev, M.V. Fedin, B. Cheng, J. Yu, L. Zhang, Adv. Mater. 37 (2025) 2414803, https://doi.org/10.1002/adma.202414803.
31. [31]
  B. Zhu, C. Jiang, J. Xu, Z. Zhang, J. Fu, J. Yu, Mater. Today 82 (2025) 251, https://doi.org/10.1016/j.mattod.2024.11.012.B. Zhu, C. Jiang, J. Xu, Z. Zhang, J. Fu, J. Yu, Mater. Today 82 (2025) 251, https://doi.org/10.1016/j.mattod.2024.11.012.
32. [32]
  X. Deng, J. Zhang, K. Qi, G. Liang, F. Xu, J. Yu, Nat. Commun. 15 (2024) 4807, https://doi.org/10.1038/s41467-024-49004-7.X. Deng, J. Zhang, K. Qi, G. Liang, F. Xu, J. Yu, Nat. Commun. 15 (2024) 4807, https://doi.org/10.1038/s41467-024-49004-7.
33. [33]
  K. Meng, J. Zhang, B. Cheng, X. Ren, Z. Xia, F. Xu, L. Zhang, J. Yu, Adv. Mater. 36 (2024) 2406460, https://doi.org/10.1002/adma.202406460.K. Meng, J. Zhang, B. Cheng, X. Ren, Z. Xia, F. Xu, L. Zhang, J. Yu, Adv. Mater. 36 (2024) 2406460, https://doi.org/10.1002/adma.202406460.
34. [34]
  J. Yan, L. Wei, Acta Phys. Chim. Sin. 40 (2024) 2312024, https://doi.org/10.3866/PKU.WHXB202312024.J. Yan, L. Wei, Acta Phys. Chim. Sin. 40 (2024) 2312024, https://doi.org/10.3866/PKU.WHXB202312024.
35. [35]
  R. He, D. Xu, M. Sayed, J. Materiomics 11 (2025) 100989, https://doi.org/10.1016/j.jmat.2024.100989.R. He, D. Xu, M. Sayed, J. Materiomics 11 (2025) 100989, https://doi.org/10.1016/j.jmat.2024.100989.
36. [36]
  Z. Meng, J. Zhang, H. Long, H. García, L. Zhang, B. Zhu, J. Yu, Angew. Chem. Int. Ed. 64 (2025) e202505456, https://doi.org/10.1002/ange.202505456.Z. Meng, J. Zhang, H. Long, H. García, L. Zhang, B. Zhu, J. Yu, Angew. Chem. Int. Ed. 64 (2025) e202505456, https://doi.org/10.1002/ange.202505456.
37. [37]
  K. Meng, J. Zhang, B. Zhu, C. Jiang, H. García, J. Yu, Adv. Mater. 37 (2025) 2505088, https://doi.org/10.1002/adma.202505088.K. Meng, J. Zhang, B. Zhu, C. Jiang, H. García, J. Yu, Adv. Mater. 37 (2025) 2505088, https://doi.org/10.1002/adma.202505088.
38. [38]
  M. Sayed, H. Li, C. Bie, Acta Phys. Chim. Sin. 41 (2025) 100117, https://doi.org/10.1016/j.actphy.2025.100117.M. Sayed, H. Li, C. Bie, Acta Phys. Chim. Sin. 41 (2025) 100117, https://doi.org/10.1016/j.actphy.2025.100117.
39. [39]
  L. Zhang, J. Zhang, J. Yu, H. García, Nat. Rev. Chem. 9 (2025) 328, https://doi.org/10.1038/s41570-025-00698-3.L. Zhang, J. Zhang, J. Yu, H. García, Nat. Rev. Chem. 9 (2025) 328, https://doi.org/10.1038/s41570-025-00698-3.
40. [40]
  J. Yan, J. Zhang, J. Mater. Sci. Technol. 193 (2024) 18, https://doi.org/10.1016/j.jmst.2023.12.054.J. Yan, J. Zhang, J. Mater. Sci. Technol. 193 (2024) 18, https://doi.org/10.1016/j.jmst.2023.12.054.
41. [41]
  J. Cai, B. Liu, S. Zhang, L. Wang, Z. Wu, J. Zhang, B. Cheng, J. Mater. Sci. Technol. 197 (2024) 183, https://doi.org/10.1016/j.jmst.2024.02.012.J. Cai, B. Liu, S. Zhang, L. Wang, Z. Wu, J. Zhang, B. Cheng, J. Mater. Sci. Technol. 197 (2024) 183, https://doi.org/10.1016/j.jmst.2024.02.012.
42. [42]
  W. Wang, B. Cheng, G. Luo, J. Yu, S. Cao, Mater. Today 81 (2024) 137, https://doi.org/10.1016/j.mattod.2024.10.006.W. Wang, B. Cheng, G. Luo, J. Yu, S. Cao, Mater. Today 81 (2024) 137, https://doi.org/10.1016/j.mattod.2024.10.006.
43. [43]
  R. Kavitha, C. Manjunatha, J. Yu, S.G. Kumar, EnergyChem 7 (2025) 100159, https://doi.org/10.1016/j.enchem.2025.100159.R. Kavitha, C. Manjunatha, J. Yu, S.G. Kumar, EnergyChem 7 (2025) 100159, https://doi.org/10.1016/j.enchem.2025.100159.
44. [44]
  X. Chen, W. Pan, R. Guo, X. Hu, Z. Bi, J. Wang, J. Mater. Chem. A 10 (2022) 7604, https://doi.org/10.1039/D2TA00500J.X. Chen, W. Pan, R. Guo, X. Hu, Z. Bi, J. Wang, J. Mater. Chem. A 10 (2022) 7604, https://doi.org/10.1039/D2TA00500J.
45. [45]
  Z. Wang, B. Cheng, L. Zhang, J. Yu, Y. Li, S. Wageh, A.A. Al-Ghamdi, Chin. J. Catal. 43 (2022) 1657, https://doi.org/10.1016/S1872-2067(21)64010-X.Z. Wang, B. Cheng, L. Zhang, J. Yu, Y. Li, S. Wageh, A.A. Al-Ghamdi, Chin. J. Catal. 43 (2022) 1657, https://doi.org/10.1016/S1872-2067(21)64010-X.
46. [46]
  X. Yang, R. Li, Y. Wang, J. Zhang, Adv. Mater. 35 (2023) 2303580, https://doi.org/10.1002/adma.202303580.X. Yang, R. Li, Y. Wang, J. Zhang, Adv. Mater. 35 (2023) 2303580, https://doi.org/10.1002/adma.202303580.
47. [47]
  J. Dong, J. Zhao, X. Yan, L. Li, G. Liu, M. Ji, B. Wang, Y. She, H. Li, J. Xia, Appl. Catal. B Environ. Energy 351 (2024) 123993, https://doi.org/10.1016/j.apcatb.2024.123993.J. Dong, J. Zhao, X. Yan, L. Li, G. Liu, M. Ji, B. Wang, Y. She, H. Li, J. Xia, Appl. Catal. B Environ. Energy 351 (2024) 123993, https://doi.org/10.1016/j.apcatb.2024.123993.
48. [48]
  J. Wu, J. Du, X. He, X. Guo, ChemCatChem 16 (2024) e202301234, https://doi.org/10.1002/cctc.202301234.J. Wu, J. Du, X. He, X. Guo, ChemCatChem 16 (2024) e202301234, https://doi.org/10.1002/cctc.202301234.
49. [49]
  P.M. Ismail, S. Ali, S. Ali, J. Li, M. Liu, D. Yan, F. Raziq, F. Wahid, G. Li, S. Yuan, et al., Adv. Mater. 35 (2023) 2303047, https://doi.org/10.1002/adma.202303047.P.M. Ismail, S. Ali, S. Ali, J. Li, M. Liu, D. Yan, F. Raziq, F. Wahid, G. Li, S. Yuan, et al., Adv. Mater. 35 (2023) 2303047, https://doi.org/10.1002/adma.202303047.
50. [50]
  Y. Wu, J. Liu, J. Rong, Y. Zhang, Q. Liang, M. Zhou, Z. Li, S. Xu, Appl. Surf. Sci. 620 (2023) 156781, https://doi.org/10.1016/j.apsusc.2023.156781.Y. Wu, J. Liu, J. Rong, Y. Zhang, Q. Liang, M. Zhou, Z. Li, S. Xu, Appl. Surf. Sci. 620 (2023) 156781, https://doi.org/10.1016/j.apsusc.2023.156781.
51. [51]
  L. Zhang, X. Liu, D. Liu, Y. Cheng, Q. Li, Y. Wang, X. Hu, H. Miao, Sep. Purif. Technol. 334 (2024) 125983, https://doi.org/10.1016/j.seppur.2023.125983.L. Zhang, X. Liu, D. Liu, Y. Cheng, Q. Li, Y. Wang, X. Hu, H. Miao, Sep. Purif. Technol. 334 (2024) 125983, https://doi.org/10.1016/j.seppur.2023.125983.
52. [52]
  W. Zhang, X. Liu, W. Jin, Q. Li, Q. Sun, E. Liu, H. Xie, H. Miao, X. Hu, J. Colloid Interf. Sci. 654 (2024) 413, https://doi.org/10.1016/j.jcis.2023.10.035.W. Zhang, X. Liu, W. Jin, Q. Li, Q. Sun, E. Liu, H. Xie, H. Miao, X. Hu, J. Colloid Interf. Sci. 654 (2024) 413, https://doi.org/10.1016/j.jcis.2023.10.035.
53. [53]
  X. Yang, L. Qu, F. Gao, Y. Hu, H. Yu, Y. Wang, M. Cui, Y. Zhang, Z. Fu, Y. Huang, et al., ACS Appl. Mater. Interf. 14 (2022) 7175, https://doi.org/10.1021/acsami.1c22448.X. Yang, L. Qu, F. Gao, Y. Hu, H. Yu, Y. Wang, M. Cui, Y. Zhang, Z. Fu, Y. Huang, et al., ACS Appl. Mater. Interf. 14 (2022) 7175, https://doi.org/10.1021/acsami.1c22448.
54. [54]
  X. Wei, Y. Yang, Z. Ma, Q. Li, Q. Sun, D. Zhang, E. Liu, H. Miao, Surf. Interf. 52 (2024) 104931, https://doi.org/10.1016/j.surfin.2024.104931.X. Wei, Y. Yang, Z. Ma, Q. Li, Q. Sun, D. Zhang, E. Liu, H. Miao, Surf. Interf. 52 (2024) 104931, https://doi.org/10.1016/j.surfin.2024.104931.
55. [55]
  Z. Kong, R. Zhang, J. Dong, J. Yu, D. Zhang, J. Liu, P. Cai, X. Pu, J. Alloy. Compd. 990 (2024) 174463, https://doi.org/10.1016/j.jallcom.2024.174463.Z. Kong, R. Zhang, J. Dong, J. Yu, D. Zhang, J. Liu, P. Cai, X. Pu, J. Alloy. Compd. 990 (2024) 174463, https://doi.org/10.1016/j.jallcom.2024.174463.
56. [56]
  S. Cao, B. Zhong, C. Bie, B. Cheng, F. Xu, Acta Phys. Chim. Sin. 40 (2024) 2307016, https://doi.org/10.3866/PKU.WHXB202307016.S. Cao, B. Zhong, C. Bie, B. Cheng, F. Xu, Acta Phys. Chim. Sin. 40 (2024) 2307016, https://doi.org/10.3866/PKU.WHXB202307016.
57. [57]
  Y. Bian, H. He, G. Dawson, J. Zhang, K. Dai, Sci. China Mater. 67 (2024) 514-523, https://doi.org/10.1007/s40843-023-2725-y.Y. Bian, H. He, G. Dawson, J. Zhang, K. Dai, Sci. China Mater. 67 (2024) 514-523, https://doi.org/10.1007/s40843-023-2725-y.
58. [58]
  X. Xu, C. Shao, J. Zhang, Z. Wang, K. Dai, Acta Phys. Chim. Sin. 40 (2024) 2309031, https://doi.org/10.3866/PKU.WHXB202309031.X. Xu, C. Shao, J. Zhang, Z. Wang, K. Dai, Acta Phys. Chim. Sin. 40 (2024) 2309031, https://doi.org/10.3866/PKU.WHXB202309031.
59. [59]
  T.L. Yusuf, O.C. Olatunde, D. Masekela, K.D. Modibane, D.C. Onwudiwe, S. Makgato, ChemElectroChem 11 (2024) e202400309, https://doi.org/10.1002/celc.202400309.T.L. Yusuf, O.C. Olatunde, D. Masekela, K.D. Modibane, D.C. Onwudiwe, S. Makgato, ChemElectroChem 11 (2024) e202400309, https://doi.org/10.1002/celc.202400309.
60. [60]
  X. Chen, C. Zhen, J. Li, J. Qiu, N. Li, N. Jia, G. Liu, Adv. Funct. Mater. 34 (2024) 2409566, https://doi.org/10.1002/adfm.202409566.X. Chen, C. Zhen, J. Li, J. Qiu, N. Li, N. Jia, G. Liu, Adv. Funct. Mater. 34 (2024) 2409566, https://doi.org/10.1002/adfm.202409566.
61. [61]
  H. Huang, H.L. Wang, Q.Y. Gong, W.F. Jiang, Sep. Purif. Technol. 342 (2024) 127049, https://doi.org/10.1016/j.seppur.2024.127049.H. Huang, H.L. Wang, Q.Y. Gong, W.F. Jiang, Sep. Purif. Technol. 342 (2024) 127049, https://doi.org/10.1016/j.seppur.2024.127049.
62. [62]
  J. Sun, Y. Zhang, S. Fan, X. Li, Q. Zhao, Appl. Catal. B Environ. Energy 356 (2024) 124248, https://doi.org/10.1016/j.apcatb.2024.124248.J. Sun, Y. Zhang, S. Fan, X. Li, Q. Zhao, Appl. Catal. B Environ. Energy 356 (2024) 124248, https://doi.org/10.1016/j.apcatb.2024.124248.
63. [63]
  Y. Deng, M. Xu, X. Jiang, J. Wang, P.L. Tremblay, T. Zhang, Environ. Res. 216 (2023) 114808, https://doi.org/10.1016/j.envres.2022.114808.Y. Deng, M. Xu, X. Jiang, J. Wang, P.L. Tremblay, T. Zhang, Environ. Res. 216 (2023) 114808, https://doi.org/10.1016/j.envres.2022.114808.
64. [64]
  X. Zhang, Z. Qiao, J. Wu, T. Jia, C. Peng, F. Li, Q. Liu, X. Li, Z. Xiang, Y. Gao, J. Environ. Chem. Eng. 12 (2024) 111689, https://doi.org/10.1016/j.jece.2023.111689.X. Zhang, Z. Qiao, J. Wu, T. Jia, C. Peng, F. Li, Q. Liu, X. Li, Z. Xiang, Y. Gao, J. Environ. Chem. Eng. 12 (2024) 111689, https://doi.org/10.1016/j.jece.2023.111689.
65. [65]
  X. Dong, L. Xu, J. Ma, Y. Li, Z. Yin, D. Chen, Q. Wang, J. Han, J. Qiu, Z. Yang, Z. Song, Chem. Eng. J. 459 (2023) 141557, https://doi.org/10.1016/j.cej.2023.141557.X. Dong, L. Xu, J. Ma, Y. Li, Z. Yin, D. Chen, Q. Wang, J. Han, J. Qiu, Z. Yang, Z. Song, Chem. Eng. J. 459 (2023) 141557, https://doi.org/10.1016/j.cej.2023.141557.
66. [66]
  Y. Xia, X. Xia, L. Chen, R. Liang, G. Yan, S. Liang, Appl. Catal. B Environ. Energy 349 (2024) 123859, https://doi.org/10.1016/j.apcatb.2024.123859.Y. Xia, X. Xia, L. Chen, R. Liang, G. Yan, S. Liang, Appl. Catal. B Environ. Energy 349 (2024) 123859, https://doi.org/10.1016/j.apcatb.2024.123859.
67. [67]
  Y. Feng, Y. Tao, J. Qu, Y. Zhang, Chem. Eng. J. 497 (2024) 154285, https://doi.org/10.1016/j.cej.2024.154285.Y. Feng, Y. Tao, J. Qu, Y. Zhang, Chem. Eng. J. 497 (2024) 154285, https://doi.org/10.1016/j.cej.2024.154285.
68. [68]
  S. Li, C. You, Q. Xue, Y. Zhao, F. Yang, Y. Liu, L. Bai, M. Zhang, C. Zhuang, J. Mater. Sci. Technol. 214 (2025) 255, https://doi.org/10.1016/j.jmst.2024.07.015.S. Li, C. You, Q. Xue, Y. Zhao, F. Yang, Y. Liu, L. Bai, M. Zhang, C. Zhuang, J. Mater. Sci. Technol. 214 (2025) 255, https://doi.org/10.1016/j.jmst.2024.07.015.
69. [69]
  J. Dong, L. Zhang, K. Lau, Y. Shu, S. Wang, Z. Fu, Z. Wu, X. Liu, B. Sa, J. Pei, et al., Small 20 (2024) 2309595, https://doi.org/10.1002/smll.202309595.J. Dong, L. Zhang, K. Lau, Y. Shu, S. Wang, Z. Fu, Z. Wu, X. Liu, B. Sa, J. Pei, et al., Small 20 (2024) 2309595, https://doi.org/10.1002/smll.202309595.
70. [70]
  K. Liu, T. Fu, L. Wang, J. Yan, J. Sun, J. Zhang, X. Wei, Z. Tong, H. Zhang, Sep. Purif. Technol. 323 (2023) 124427, https://doi.org/10.1016/j.seppur.2023.124427.K. Liu, T. Fu, L. Wang, J. Yan, J. Sun, J. Zhang, X. Wei, Z. Tong, H. Zhang, Sep. Purif. Technol. 323 (2023) 124427, https://doi.org/10.1016/j.seppur.2023.124427.
71. [71]
  J. Dong, S. Ji, Y. Zhang, M. Ji, B. Wang, Y. Li, Z. Chen, J. Xia, H. Li, Acta Phys. Chim. Sin. 39 (2023) 2212011, https://doi.org/10.3866/PKU.WHXB202212011.J. Dong, S. Ji, Y. Zhang, M. Ji, B. Wang, Y. Li, Z. Chen, J. Xia, H. Li, Acta Phys. Chim. Sin. 39 (2023) 2212011, https://doi.org/10.3866/PKU.WHXB202212011.
72. [72]
  S. Fu, W. Yuan, X. Liu, Y. Yan, H. Liu, L. Li, F. Zhao, J. Zhou, J. Colloid Interface Sci. 569 (2020) 150, https://doi.org/10.1016/j.jcis.2020.02.077.S. Fu, W. Yuan, X. Liu, Y. Yan, H. Liu, L. Li, F. Zhao, J. Zhou, J. Colloid Interface Sci. 569 (2020) 150, https://doi.org/10.1016/j.jcis.2020.02.077.
73. [73]
  Z. Zan, X. Li, X. Gao, J. Huang, Y. Luo, L. Han, Acta Phys. Chim. Sin. 39 (2023) 2209016, https://doi.org/10.3866/PKU.WHXB202209016.Z. Zan, X. Li, X. Gao, J. Huang, Y. Luo, L. Han, Acta Phys. Chim. Sin. 39 (2023) 2209016, https://doi.org/10.3866/PKU.WHXB202209016.
74. [74]
  K. Liu, H. Zhang, Y. Muhammad, T. Fu, R. Tang, Z. Tong, Y. Wang, Sep. Purif. Technol. 274 (2021) 118992, https://doi.org/10.1016/j.seppur.2021.118992.K. Liu, H. Zhang, Y. Muhammad, T. Fu, R. Tang, Z. Tong, Y. Wang, Sep. Purif. Technol. 274 (2021) 118992, https://doi.org/10.1016/j.seppur.2021.118992.
75. [75]
  S. Ma, X. Xia, Q. Song, Y. Zhao, J. Yang, Solid State Sci. 138 (2023) 107135, https://doi.org/10.1016/j.solidstatesciences.2023.107135.S. Ma, X. Xia, Q. Song, Y. Zhao, J. Yang, Solid State Sci. 138 (2023) 107135, https://doi.org/10.1016/j.solidstatesciences.2023.107135.
76. [76]
  X. Yan, Q. Ji, C. Wang, J. Xu, L. Wang, J. Colloid Interface Sci. 587 (2021) 820, https://doi.org/10.1016/j.jcis.2020.11.043.X. Yan, Q. Ji, C. Wang, J. Xu, L. Wang, J. Colloid Interface Sci. 587 (2021) 820, https://doi.org/10.1016/j.jcis.2020.11.043.
77. [77]
  J. Huang, H. Yu, X. Yuan, X. Li, L. Jiang, K. Yi, C. Zhang, Environ. Sci. Pollut. Res. 30 (2023) 19210, https://doi.org/10.1007/s11356-022-23503-w.J. Huang, H. Yu, X. Yuan, X. Li, L. Jiang, K. Yi, C. Zhang, Environ. Sci. Pollut. Res. 30 (2023) 19210, https://doi.org/10.1007/s11356-022-23503-w.
78. [78]
  F. Xu, Y. He, J. Zhang, G. Liang, C. Liu, J. Yu, Angew. Chem. Int. Ed. 64 (2025) e202414672, https://doi.org/10.1002/anie.202414672.F. Xu, Y. He, J. Zhang, G. Liang, C. Liu, J. Yu, Angew. Chem. Int. Ed. 64 (2025) e202414672, https://doi.org/10.1002/anie.202414672.
79. [79]
  X. Zhang, J. Xu, H. Long, J. Yu, H. Yu, ACS Catal. 14 (2024) 18669, https://doi.org/10.1021/acscatal.4c05674.X. Zhang, J. Xu, H. Long, J. Yu, H. Yu, ACS Catal. 14 (2024) 18669, https://doi.org/10.1021/acscatal.4c05674.
80. [80]
  T. Yang, J. Wang, Z. Wang, J. Zhang, K. Dai, Chin. J. Catal. 58 (2024) 157, https://doi.org/10.1016/S1872-2067(23)64607-8.T. Yang, J. Wang, Z. Wang, J. Zhang, K. Dai, Chin. J. Catal. 58 (2024) 157, https://doi.org/10.1016/S1872-2067(23)64607-8.
81. [81]
  Y. Yang, X. Zhou, M. Gu, B. Cheng, Z. Wu, J. Zhang, Acta Phys. Chim. Sin. 41 (2025) 100064, https://doi.org/10.1016/j.actphy.2025.100064.Y. Yang, X. Zhou, M. Gu, B. Cheng, Z. Wu, J. Zhang, Acta Phys. Chim. Sin. 41 (2025) 100064, https://doi.org/10.1016/j.actphy.2025.100064.
82. [82]
  J. Cai, C. Cheng, B. Liu, J. Zhang, C. Jiang, B. Cheng, Acta Phys. Chim. Sin. 41 (2025) 100084, https://doi.org/10.1016/j.actphy.2025.100084.J. Cai, C. Cheng, B. Liu, J. Zhang, C. Jiang, B. Cheng, Acta Phys. Chim. Sin. 41 (2025) 100084, https://doi.org/10.1016/j.actphy.2025.100084.

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沈阳化工大学材料科学与工程学院沈阳 110142

范德华S型异质结赋予快速电荷转移助力光催化活性提升

通讯作者: 张建军,E-mail:zhangjianjun@cug.edu.cn; 韩生,E-mail:hansheng654321@sina.com

English

Rapid charge transfer endowed by van der Waals S-scheme heterojunction for boosting photocatalytic activity

Corresponding author: Jianjun Zhang, ; Sheng Han,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

范德华S型异质结赋予快速电荷转移助力光催化活性提升

通讯作者: 张建军,E-mail:zhangjianjun@cug.edu.cn; 韩生,E-mail:hansheng654321@sina.com

English

Rapid charge transfer endowed by van der Waals S-scheme heterojunction for boosting photocatalytic activity

Corresponding author: Jianjun Zhang, ; Sheng Han,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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