掺铬富锂锰基材料作为高性能全固态锂电池正极

引用本文: 高珂珂, 许浩哲, 刘兴坤, 孙春文. 掺铬富锂锰基材料作为高性能全固态锂电池正极[J]. 物理化学学报, 2026, 42(3): 100200. doi: 10.1016/j.actphy.2025.100200 shu

Citation: Keke Gao, Haozhe Xu, Xingkun Liu, Chunwen Sun. Cr-doped lithium-rich manganese-based materials as a cathode for high-performance all-solid-state lithium batteries[J]. Acta Physico-Chimica Sinica, 2026, 42(3): 100200. doi: 10.1016/j.actphy.2025.100200 shu

掺铬富锂锰基材料作为高性能全固态锂电池正极

中国矿业大学(北京), 化学与环境工程学院, 北京 100083

通讯作者: 孙春文,Email:csun@cumtb.edu.cn

基金项目:
The authors acknowledge the financial support of the National Natural Science Foundation of China (No. 52472271) and the National Key R&D Program of China (No. 2023YFE0115800).

摘要: 具有富锂锰基材料(LRMs)的全固态锂离子电池(ASSLBs)因其高能量密度和安全性被视为下一代储能体系。然而，不可逆的氧释放导致的卤化物固态电解质(SEs)严重的界面降解问题亟待解决。本研究合成了兼具高容量与稳定性的铬掺杂LRMs材料。Cr³⁺/Cr⁶⁺的可逆氧化还原反应提升了额外的容量，同时Cr⁶⁺离子在八面体与四面体位点间的可逆迁移有效维持了材料结构稳定性。此外，强Cr-O键能稳定晶格氧，构建稳定的正极/电解质界面并缓解电压衰减。因此，采用LRMs-Cr0.1正极与卤化物电解质的ASSLBs在0.5C倍率下循环500圈，每圈容量衰减率仅为0.065%。值得注意的是，LRMs-Cr0.1//Li₂₁Si₅@Si/C全电池在0.3C倍率下循环1000圈，容量保持率接近100%，对应的能量密度为413.11 Wh kg^-1。该研究为开发高能量密度的固态电池提供了指导。

关键词:

English

Cr-doped lithium-rich manganese-based materials as a cathode for high-performance all-solid-state lithium batteries

School of Chemical and Environmental Engineering, China University of Mining & Technology (Beijing), Beijing 100083, China

Corresponding author: Chunwen Sun, csun@cumtb.edu.cn

Received Date: 08 July 2025
Accepted Date: 14 October 2025
Revised Date: 16 September 2025

Abstract: With prospects for high energy density and safety, all-solid-state lithium-ion batteries (ASSLBs) with lithium-rich manganese-based materials (LRMs) are exploited as next-generation energy storage systems. However, the severe interfacial degradations with halide solid electrolytes (SEs) caused by the irreversible oxygen release remain to be urgently solved. In this work, we synthesized Cr-substituted LRMs with high capacity and stability. The reversible redox of Cr³⁺/Cr⁶⁺ contributes to an enhanced capacity, accompanied by the reversible migration of Cr⁶⁺ ions between octahedral and tetrahedral sites, effectively maintaining the structural stability of LRMs. Meanwhile, the strong Cr–O bond can stabilize the lattice oxygen, establish a stable cathode/electrolyte interface, and alleviate the voltage decay. Therefore, the ASSBs with LRMs-Cr0.1 cathode and halide electrolyte show an excellent cycling stability with 0.065% capacity decay per cycle for 500 cycles at 0.5C. Notably, the LRMs-Cr0.1//Li₂₁Si₅@Si/C full cell exhibits outstanding long-term cyclability over 1000 cycles with nearly 100% capacity retention at 0.3C, corresponding to an energy density of 413.11 Wh kg^-1. This work provides guidance for developing high energy-density solid-state batteries.

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沈阳化工大学材料科学与工程学院沈阳 110142

掺铬富锂锰基材料作为高性能全固态锂电池正极

通讯作者: 孙春文,Email:csun@cumtb.edu.cn

English

Cr-doped lithium-rich manganese-based materials as a cathode for high-performance all-solid-state lithium batteries

Corresponding author: Chunwen Sun, csun@cumtb.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

掺铬富锂锰基材料作为高性能全固态锂电池正极

通讯作者: 孙春文,Email:csun@cumtb.edu.cn

English

Cr-doped lithium-rich manganese-based materials as a cathode for high-performance all-solid-state lithium batteries

Corresponding author: Chunwen Sun, csun@cumtb.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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