注册 English

用于可扩展和高分辨率隐形印刷的磷光碳纳米点油墨

龙燕 ,  赵文博 ,  曹庆 ,  李翔宇 ,  李付奎 ,  胡宴伟 ,  宋世玉 ,  刘凯凯

downloadPDF
引用本文: 龙燕, 赵文博, 曹庆, 李翔宇, 李付奎, 胡宴伟, 宋世玉, 刘凯凯. 用于可扩展和高分辨率隐形印刷的磷光碳纳米点油墨[J]. 物理化学学报, 2026, 42(3): 100198. doi: 10.1016/j.actphy.2025.100198 shu
Citation:  Yan Long,  Wenbo Zhao,  Qing Cao,  Xiangyu Li,  Fukui Li,  Yanwei Hu,  Shiyu Song,  Kaikai Liu. Phosphorescent carbon nanodot inks for scalable and high-resolution invisible printing[J]. Acta Physico-Chimica Sinica, 2026, 42(3): 100198. doi: 10.1016/j.actphy.2025.100198 shu

用于可扩展和高分辨率隐形印刷的磷光碳纳米点油墨

  • 郑州大学, 物理学院, 教育部材料物理重点实验室, 河南省金刚石光电材料与器件重点实验室, 河南 郑州 450052

    • 通讯作者: 赵文博,Email:zwb2626@163.com; 宋世玉,Email:sysong@zzu.edu.cn; 刘凯凯,Email:liukaikai@zzu.edu.cn
  • 基金项目:

    国家自然科学基金(12474413, 12274378, 12504485)；中国博士后科学基金(BX20240337, 2025M773431, 2025M773392)及河南省重点研发与推广专项(252102231055)资助

摘要: 基于碳纳米点(CNDs)的磷光油墨为持久可视化和延时信息读取提供了一种环保且低成本的解决方案。然而，当前依赖基质的磷光碳纳米点存在加工性能差和基底兼容性有限的问题，阻碍了其在可扩展、高分辨率隐形印刷中的应用。本文报道了一种可实现高分辨率、环境稳定且隐形印刷的水溶性磷光CNDs油墨。通过印刷过程中的空间限域效应，稳定CNDs中的三重态激子，从而产生明亮且长寿命的磷光。该磷光CNDs油墨能以微米级分辨率(2480×3508 dpi，约100 μm特征尺寸)实现复杂文本图案的隐形高保真印刷，在五类纸质基底上支持最小5 pt字号与0.05 pt的细线宽度。印刷图案在约870万像素中显示出超过98.7%的准确度，展现出卓越的保真性。基于优异的隐形印刷特性，研究团队成功制作了采用磷光CNDs油墨的200页无字书。这项工作为磷光油墨印刷提供了可扩展、低成本且高分辨率的平台，标志着隐形印刷技术的重大突破。

English

    1. [1]

      L.E. MacKenzie, R. Pal, Nat. Rev. Chem. 5(2021) 109, https://doi.org/10.1038/s41570-020-00235-4.L.E. MacKenzie, R. Pal, Nat. Rev. Chem. 5(2021) 109, https://doi.org/10.1038/s41570-020-00235-4.

    2. [2]

      J.J. Wang, C. Chen, W.G. Chen, J.S. Yao, J.N. Yang, K.H. Wang, Y.C. Yin, M.M. Yao, L.Z. Feng, C. Ma, et al., J. Am. Chem. Soc. 142(1) (2020) 3686, https://doi.org/10.1021/jacs.9b12908.J.J. Wang, C. Chen, W.G. Chen, J.S. Yao, J.N. Yang, K.H. Wang, Y.C. Yin, M.M. Yao, L.Z. Feng, C. Ma, et al., J. Am. Chem. Soc. 142(1) (2020) 3686, https://doi.org/10.1021/jacs.9b12908.

    3. [3]

      R. Khalilzadeh, M. Babazadeh-Mamaqani, M. Mohammadi-Jorjafki, H. Roghani-Mamaqani, R. Hoogenboom, Prog. Mater. Sci. 153(2025) 101487, https://doi.org/10.1016/j.pmatsci.2025.101487.R. Khalilzadeh, M. Babazadeh-Mamaqani, M. Mohammadi-Jorjafki, H. Roghani-Mamaqani, R. Hoogenboom, Prog. Mater. Sci. 153(2025) 101487, https://doi.org/10.1016/j.pmatsci.2025.101487.

    4. [4]

      L. Ding, X.D. Wang, J. Am. Chem. Soc. 142(31) (2020) 13558, https://doi.org/10.1021/jacs.0c05506.L. Ding, X.D. Wang, J. Am. Chem. Soc. 142(31) (2020) 13558, https://doi.org/10.1021/jacs.0c05506.

    5. [5]

      H. Alidaei-Sharif, M. Babazadeh-Mamaqani, H. Roghani-Mamaqani, M. Salami Kalajahi, Eur. Polym. J. 197(2023) 112339, https://doi.org/10.1016/j.eurpolymj.2023.112339.H. Alidaei-Sharif, M. Babazadeh-Mamaqani, H. Roghani-Mamaqani, M. Salami Kalajahi, Eur. Polym. J. 197(2023) 112339, https://doi.org/10.1016/j.eurpolymj.2023.112339.

    6. [6]

      Q. Mei, Z. Zhang, Angew. Chem. Int. Ed. 51(23) (2012) 5602, https://doi.org/10.1002/anie.201201389.Q. Mei, Z. Zhang, Angew. Chem. Int. Ed. 51(23) (2012) 5602, https://doi.org/10.1002/anie.201201389.

    7. [7]

      J. Song, J. Li, L. Xu, J. Li, F. Zhang, B. Han, Q. Shan, H. Zeng, Adv. Mater. 30(30) (2018) 1800764, https://doi.org/10.1002/adma.201800764.J. Song, J. Li, L. Xu, J. Li, F. Zhang, B. Han, Q. Shan, H. Zeng, Adv. Mater. 30(30) (2018) 1800764, https://doi.org/10.1002/adma.201800764.

    8. [8]

      S. Ronneberger, J. Zhang, Y. Liu, F.F. Loeffler, Adv. Funct. Mater. 33(17) (2023) 2210116, https://doi.org/10.1002/adfm.202210116.S. Ronneberger, J. Zhang, Y. Liu, F.F. Loeffler, Adv. Funct. Mater. 33(17) (2023) 2210116, https://doi.org/10.1002/adfm.202210116.

    9. [9]

      H. Peng, G. Xie, Y. Cao, L. Zhang, X. Yan, X. Zhang, S. Miao, Y. Tao, H. Li, C. Zheng, et al., Sci. Adv. 8(15) (2022) eabk2925, https://doi.org/10.1126/sciadv.abk2925.H. Peng, G. Xie, Y. Cao, L. Zhang, X. Yan, X. Zhang, S. Miao, Y. Tao, H. Li, C. Zheng, et al., Sci. Adv. 8(15) (2022) eabk2925, https://doi.org/10.1126/sciadv.abk2925.

    10. [10]

      L. Shi, L. Ding, Y. Zhang, S. Lu, Nano Today 55(2024) 102200, https://doi.org/10.1016/j.nantod.2024.102200.L. Shi, L. Ding, Y. Zhang, S. Lu, Nano Today 55(2024) 102200, https://doi.org/10.1016/j.nantod.2024.102200.

    11. [11]

      X. Wang, H. Qi, Y. Shao, M. Zhao, H. Chen, Y. Chen, Y. Ying, Y. Wang, Adv. Sci. 11(25) (2024) 2400207, https://doi.org/10.1002/advs.202400207.X. Wang, H. Qi, Y. Shao, M. Zhao, H. Chen, Y. Chen, Y. Ying, Y. Wang, Adv. Sci. 11(25) (2024) 2400207, https://doi.org/10.1002/advs.202400207.

    12. [12]

      G. Tongyu, Z. Yongxi, Q. Zhao, W. Chenger, D. Mobin, Z. Xia, C. Xiaoxia, L. Yuanhong, L. Ronghui, J. Alloys Compd. 1037(2025) 182399, https://doi.org/10.1016/j.jallcom.2025.182399.G. Tongyu, Z. Yongxi, Q. Zhao, W. Chenger, D. Mobin, Z. Xia, C. Xiaoxia, L. Yuanhong, L. Ronghui, J. Alloys Compd. 1037(2025) 182399, https://doi.org/10.1016/j.jallcom.2025.182399.

    13. [13]

      T. Shen, H. Zheng, R. Liao, B. Li, J. Wu, Z. Jiang, X. Meng, C. Cao, Nano Res. 18(5) (2025) 94907380, https://doi.org/10.26599/NR.2025.94907380.T. Shen, H. Zheng, R. Liao, B. Li, J. Wu, Z. Jiang, X. Meng, C. Cao, Nano Res. 18(5) (2025) 94907380, https://doi.org/10.26599/NR.2025.94907380.

    14. [14]

      L. Ethordevic, F. Arcudi, M. Cacioppo, M. Prato, Nat. Nanotechnol. 17(2022) 112, https://doi.org/10.1038/s41565-021-01051-7.L. Ethordevic, F. Arcudi, M. Cacioppo, M. Prato, Nat. Nanotechnol. 17(2022) 112, https://doi.org/10.1038/s41565-021-01051-7.

    15. [15]

      P. Miao, K. Han, Y. Tang, B. Wang, T. Lin, W. Cheng, Nanoscale 7(5) (2015) 1586, https://doi.org/10.1039/C4NR05712K.P. Miao, K. Han, Y. Tang, B. Wang, T. Lin, W. Cheng, Nanoscale 7(5) (2015) 1586, https://doi.org/10.1039/C4NR05712K.

    16. [16]

      S. Qu, X. Wang, Q. Lu, X. Liu, L. Wang, Angew. Chem. Int. Ed. 51(49) (2012) 12215, https://doi.org/10.1002/anie.201206791.S. Qu, X. Wang, Q. Lu, X. Liu, L. Wang, Angew. Chem. Int. Ed. 51(49) (2012) 12215, https://doi.org/10.1002/anie.201206791.

    17. [17]

      J. Li, X. Zhao, X. Gong, Small 20(31) (2024) 2400107, https://doi.org/10.1002/smll.202400107.J. Li, X. Zhao, X. Gong, Small 20(31) (2024) 2400107, https://doi.org/10.1002/smll.202400107.

    18. [18]

      P. Dhumal, S. Chakraborty, B. Ibrahim, M. Kaur, E. Valsami-Jones, J. Cleaner Prod. 480(2024) 144115, https://doi.org/10.1016/j.jclepro.2024.144115.P. Dhumal, S. Chakraborty, B. Ibrahim, M. Kaur, E. Valsami-Jones, J. Cleaner Prod. 480(2024) 144115, https://doi.org/10.1016/j.jclepro.2024.144115.

    19. [19]

      R. Li, F. Liang, X. Hu, H. Bian, C. Deng, F. Seidi, B. Zhang, H. Xiao, Y. Liu, Carbohydr. Polym. 298(2022) 120073, https://doi.org/10.1016/j.carbpol.2022.120073.R. Li, F. Liang, X. Hu, H. Bian, C. Deng, F. Seidi, B. Zhang, H. Xiao, Y. Liu, Carbohydr. Polym. 298(2022) 120073, https://doi.org/10.1016/j.carbpol.2022.120073.

    20. [20]

      W.T. Huang, Y. Meesala, H.P. Hsueh, M. H. Fang, Z. Bao, J.W. Chiou, R.S. Liu, Chem. Eng. J. 430(2022) 132789, https://doi.org/10.1016/j.cej.2021.132789.W.T. Huang, Y. Meesala, H.P. Hsueh, M. H. Fang, Z. Bao, J.W. Chiou, R.S. Liu, Chem. Eng. J. 430(2022) 132789, https://doi.org/10.1016/j.cej.2021.132789.

    21. [21]

      J.M. Kim, K. Cheong, J. Jiang, S.O. Jeon, W.P. Hong, J.Y. Lee, Trends Chem. 5(4) (2023) 267, https://doi.org/10.1016/j.trechm.2023.01.004.J.M. Kim, K. Cheong, J. Jiang, S.O. Jeon, W.P. Hong, J.Y. Lee, Trends Chem. 5(4) (2023) 267, https://doi.org/10.1016/j.trechm.2023.01.004.

    22. [22]

      P. Li, J. Zeng, B. Wang, Z. Cheng, J. Xu, W. Gao, K. Chen, Carbohydr. Polym. 247(2020) 116721, https://doi.org/10.1016/j.carbpol.2020.116721.P. Li, J. Zeng, B. Wang, Z. Cheng, J. Xu, W. Gao, K. Chen, Carbohydr. Polym. 247(2020) 116721, https://doi.org/10.1016/j.carbpol.2020.116721.

    23. [23]

      J. Du, L. Sheng, Y. Xu, Q. Chen, C. Gu, M. Li, S.X.A. Zhang, Adv. Mater. 33(20) (2021) 2008055, https://doi.org/10.1002/adma.202008055.J. Du, L. Sheng, Y. Xu, Q. Chen, C. Gu, M. Li, S.X.A. Zhang, Adv. Mater. 33(20) (2021) 2008055, https://doi.org/10.1002/adma.202008055.

    24. [24]

      D. Wang, Z. Wang, Q. Zhan, Y. Pu, J.X. Wang, N.R. Foster, L. Dai, Engineering 3(3) (2017) 402, https://doi.org/10.1016/J.ENG.2017.03.014.D. Wang, Z. Wang, Q. Zhan, Y. Pu, J.X. Wang, N.R. Foster, L. Dai, Engineering 3(3) (2017) 402, https://doi.org/10.1016/J.ENG.2017.03.014.

    25. [25]

      S. Zhang, C. Shen, J. Li, J. Liao, P. Miao, X. Zhao, X. Gong, Chem. Sci. 16(2025) 14098, https://doi.org/10.1039/D5SC02963E.S. Zhang, C. Shen, J. Li, J. Liao, P. Miao, X. Zhao, X. Gong, Chem. Sci. 16(2025) 14098, https://doi.org/10.1039/D5SC02963E.

    26. [26]

      S.Y. Song, K.K. Liu, Q. Cao, X. Mao, W.B. Zhao, Y. Wang, Y.C. Liang, J.H. Zang, Q. Lou, L. Dong, et al., Light: Sci. Appl. 11(2022) 146, https://doi.org/10.1038/s41377-022-00837-1.S.Y. Song, K.K. Liu, Q. Cao, X. Mao, W.B. Zhao, Y. Wang, Y.C. Liang, J.H. Zang, Q. Lou, L. Dong, et al., Light: Sci. Appl. 11(2022) 146, https://doi.org/10.1038/s41377-022-00837-1.

    27. [27]

      X. He, W. Huang, Y. Zheng, X. Xu, H. Wei, P. Liang, X. Yang, C. Hu, X. Zhang, B. Lei, et al., Angew. Chem. Int. Ed. 64(16) (2025) e202423388, https://doi.org/10.1002/anie.202423388.X. He, W. Huang, Y. Zheng, X. Xu, H. Wei, P. Liang, X. Yang, C. Hu, X. Zhang, B. Lei, et al., Angew. Chem. Int. Ed. 64(16) (2025) e202423388, https://doi.org/10.1002/anie.202423388.

    28. [28]

      S.Y. Song, K.K. Liu, X. Mao, Q. Cao, N. Li, W.B. Zhao, Y. Wang, Y.C. Liang, J.H. Zang, X. Li, et al., Adv. Mater. 35(21) (2023) 2212286, https://doi.org/10.1002/adma.202212286.S.Y. Song, K.K. Liu, X. Mao, Q. Cao, N. Li, W.B. Zhao, Y. Wang, Y.C. Liang, J.H. Zang, X. Li, et al., Adv. Mater. 35(21) (2023) 2212286, https://doi.org/10.1002/adma.202212286.

    29. [29]

      J. Li, H. Zhou, S. Jin, B. Xu, Q. Teng, C. Li, J. Li, Q. Li, Z. Gao, C. Zhu, et al., Adv. Mater. 36(24) (2024) 2401493, https://doi.org/10.1002/adma.202401493.J. Li, H. Zhou, S. Jin, B. Xu, Q. Teng, C. Li, J. Li, Q. Li, Z. Gao, C. Zhu, et al., Adv. Mater. 36(24) (2024) 2401493, https://doi.org/10.1002/adma.202401493.

    30. [30]

      D. Chen, X. Guo, X. Sun, X. Feng, K. Chen, J. Zhang, Z. Zhu, X. Zhang, X. Liu, M. Liu, et al., Exploration 4(6) (2024) 20230166, https://doi.org/10.1002/EXP.20230166.D. Chen, X. Guo, X. Sun, X. Feng, K. Chen, J. Zhang, Z. Zhu, X. Zhang, X. Liu, M. Liu, et al., Exploration 4(6) (2024) 20230166, https://doi.org/10.1002/EXP.20230166.

    31. [31]

      Y.C. Liang, S.F. Zhang, Q. Cao, L.Y. Jiang, Y.F. Jiao, Y. Wang, H.L. Zhang, H.Y. Wang, C.X. Shan, L.M. Kuang, et al., Nano Lett. 25(21) (2025) 8713, https://doi.org/10.1021/acs.nanolett.5c01655.Y.C. Liang, S.F. Zhang, Q. Cao, L.Y. Jiang, Y.F. Jiao, Y. Wang, H.L. Zhang, H.Y. Wang, C.X. Shan, L.M. Kuang, et al., Nano Lett. 25(21) (2025) 8713, https://doi.org/10.1021/acs.nanolett.5c01655.

    32. [32]

      W. Zhao, Z. He, B.Z. Tang, Nat. Rev. Mater. 5(2020) 869, https://doi.org/10.1038/s41578-020-0223-z.W. Zhao, Z. He, B.Z. Tang, Nat. Rev. Mater. 5(2020) 869, https://doi.org/10.1038/s41578-020-0223-z.

    33. [33]

      M. Yu, P. Li, J. Li, X. Chen, Z. Hu, Y. Wang, J. Zeng, F. Han, X. Gong, B. Li, et al., Adv. Healthcare Mater. 14(2) (2024) 2403201, https://doi.org/10.1002/adhm.202403201.M. Yu, P. Li, J. Li, X. Chen, Z. Hu, Y. Wang, J. Zeng, F. Han, X. Gong, B. Li, et al., Adv. Healthcare Mater. 14(2) (2024) 2403201, https://doi.org/10.1002/adhm.202403201.

    34. [34]

      X. Chen, J. Li, W. Zou, X. Gong, Small 20(50) (2024) 2404407, https://doi.org/10.1002/smll.202404407.X. Chen, J. Li, W. Zou, X. Gong, Small 20(50) (2024) 2404407, https://doi.org/10.1002/smll.202404407.

    35. [35]

      K. Wang, L. Qu, C. Yang, Small 19(31) (2023) 2206429, https://doi.org/10.1002/smll.202206429.K. Wang, L. Qu, C. Yang, Small 19(31) (2023) 2206429, https://doi.org/10.1002/smll.202206429.

    36. [36]

      Q. Cao, K.K. Liu, Y.C. Liang, S.Y. Song, Y. Deng, X. Mao, W.B. Zhao, Q. Lou, C.X. Shan, Nano Lett. 22(10) (2022) 4097, https://doi.org/10.1021/acs.nanolett.2c00788.Q. Cao, K.K. Liu, Y.C. Liang, S.Y. Song, Y. Deng, X. Mao, W.B. Zhao, Q. Lou, C.X. Shan, Nano Lett. 22(10) (2022) 4097, https://doi.org/10.1021/acs.nanolett.2c00788.

    37. [37]

      Q. Lou, N. Chen, J. Zhu, K. Liu, C. Li, Y. Zhu, W. Xu, X. Chen, Z. Song, C. Liang, et al., Adv. Mater. 35(20) (2023) 2211858, https://doi.org/10.1002/adma.202211858.Q. Lou, N. Chen, J. Zhu, K. Liu, C. Li, Y. Zhu, W. Xu, X. Chen, Z. Song, C. Liang, et al., Adv. Mater. 35(20) (2023) 2211858, https://doi.org/10.1002/adma.202211858.

    38. [38]

      Y.C. Liang, H.C. Shao, K.K. Liu, Q. Cao, L.Y. Jiang, C.X. Shan, L.M. Kuang, H. Jing, Small 20(36) (2024) 2312218, https://doi.org/10.1002/smll.202312218.Y.C. Liang, H.C. Shao, K.K. Liu, Q. Cao, L.Y. Jiang, C.X. Shan, L.M. Kuang, H. Jing, Small 20(36) (2024) 2312218, https://doi.org/10.1002/smll.202312218.

    39. [39]

      F. Liu, Z. Li, Y. Li, Y. Feng, W. Feng, Carbon 181(2021) 9, https://doi.org/10.1016/j.carbon.2021.05.023.F. Liu, Z. Li, Y. Li, Y. Feng, W. Feng, Carbon 181(2021) 9, https://doi.org/10.1016/j.carbon.2021.05.023.

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  61
  • HTML全文浏览量:  6
文章相关
  • 收稿日期:  2025-08-03
  • 接受日期:  2025-09-28
  • 修回日期:  2025-09-24
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net