双层锰酸盐正极LaSr2Mn2O6.96在全固态氟离子电池中的结构与电化学行为

引用本文: Vanita Vanita, Roland Schoch, Pascal Puphal, Hasan Yilmaz, Matthias Bauer, Oliver Clemens. 双层锰酸盐正极LaSr²Mn²O^6.96在全固态氟离子电池中的结构与电化学行为[J]. 物理化学学报, 2026, 42(3): 100181. doi: 10.1016/j.actphy.2025.100181 shu

Citation: Vanita Vanita, Roland Schoch, Pascal Puphal, Hasan Yilmaz, Matthias Bauer, Oliver Clemens. Structural and electrochemical behaviour of bilayer manganite LaSr₂Mn₂O_6.96 cathode for all-solid-state fluoride ion batteries[J]. Acta Physico-Chimica Sinica, 2026, 42(3): 100181. doi: 10.1016/j.actphy.2025.100181 shu

双层锰酸盐正极LaSr²Mn²O^6.96在全固态氟离子电池中的结构与电化学行为

1.
University of Stuttgart, Institute for Materials Science, Materials Synthesis Group, Heisenbergstraße 3, 70569 Germany;
2.
Institute of Inorganic Chemistry and Center for Sustainable Systems Design (CSSD), Paderborn University, Warburger Straße 100, 33098 Paderborn, Germany;
3.
Max-Planck-Institute, Heisenbergstr. 1, 70569 Stuttgart, Germany

通讯作者: Oliver Clemens,Email:oliver.clemens@imw.uni-stuttgart.de

基金项目:
Eberhard Goering (Max-Planck-Institute, Stuttgart) is acknowledged for modifying the sample holders to enable magnetic measurements on the cell pellets. The authors would also like to thank Manish Revar, a student assistant in our lab, for his assistance in preparing the battery cell pellets for electrochemical testing.

摘要: 本研究探讨了Ruddlesden-Popper型双层锰酸盐LaSr₂Mn₂O_6.96作为全固态氟离子电池(FIBs)插层型正极材料的潜力。通过非原位X射线衍射分析了LaSr₂Mn₂O_6.96在氟离子嵌入/脱嵌过程中的结构变化，发现F^-的嵌入会形成三种不同的四方相。为理解这些物相的复杂行为，采用X射线吸收光谱和磁学测量手段研究了Mn氧化态及配位环境的变化。在20 kN的堆叠压力和1 V至-1 V电位区间的电化学循环中，LaSr₂Mn₂O_6.96的比容量从初始的~30 mAh g^-1持续增加至200次循环后的~68 mAh g^-1，库仑效率达~99%，且未出现容量衰减迹象。这表明双层锰酸盐LaSr₂Mn₂O_6.96有望成为循环稳定的全固态FIBs正极材料，尤其是在施加堆叠压力的条件下。

关键词:

English

Structural and electrochemical behaviour of bilayer manganite LaSr₂Mn₂O_6.96 cathode for all-solid-state fluoride ion batteries

1.
University of Stuttgart, Institute for Materials Science, Materials Synthesis Group, Heisenbergstraße 3, 70569 Germany;
2.
Institute of Inorganic Chemistry and Center for Sustainable Systems Design (CSSD), Paderborn University, Warburger Straße 100, 33098 Paderborn, Germany;
3.
Max-Planck-Institute, Heisenbergstr. 1, 70569 Stuttgart, Germany

Corresponding author: Oliver Clemens, oliver.clemens@imw.uni-stuttgart.de

Received Date: 30 June 2025
Accepted Date: 04 September 2025
Revised Date: 27 August 2025

Abstract: In this study, we explore the potential of the Ruddlesden-Popper (RP)-type bilayer manganite LaSr₂Mn₂O_6.96 as an intercalation-based cathode material for all-solid-state fluoride ion batteries (FIBs). Structural changes of LaSr₂Mn₂O_6.96 during fluoride intercalation and de-intercalation were analyzed via ex situ X-ray diffraction, revealing that F^- insertion induces the formation of three distinct tetragonal phases. To understand the complex behavior of these phases, we examined the changes in the Mn oxidation state and coordination environment using X-ray absorption spectroscopy and magnetic measurements. Under stack pressure (20 kN), electrochemical cycling of LaSr₂Mn₂O_6.96 in the potential range of 1 V to -1 V exhibited a continuous increase in specific capacity from capacity of ~30 mAh g^-1 to ~68 mAh g^-1 over 200 cycles, with ~99% coulombic efficiency and no signs of capacity fading. This makes the bilayer manganite LaSr₂Mn₂O_6.96 a promising candidate for a cycling stable cathode for all-solid-state FIBs, especially under the application of stack pressure.

Key words:

1. [1]
  D. Ahmed, K. M. Maraz, Mater. Eng. Res. 5(2023) 265, https://doi.org/10.25082/MER.2023.01.003D. Ahmed, K. M. Maraz, Mater. Eng. Res. 5(2023) 265, https://doi.org/10.25082/MER.2023.01.003
2. [2]
  I. Hadjipaschalis, A. Poullikkas, V. Efthimiou, Renew. Sustain. Energy Rev. 13(2009) 1513, https://doi.org/10.1016/j.rser.2008.09.028I. Hadjipaschalis, A. Poullikkas, V. Efthimiou, Renew. Sustain. Energy Rev. 13(2009) 1513, https://doi.org/10.1016/j.rser.2008.09.028
3. [3]
  M. Li, J. Lu, Z. Chen, K. Amine, Adv. Mater. 30(2018) 1800561, https://doi.org/10.1002/adma.201800561M. Li, J. Lu, Z. Chen, K. Amine, Adv. Mater. 30(2018) 1800561, https://doi.org/10.1002/adma.201800561
4. [4]
  M. J. Lain, E. Kendrick, J. Power Sources 493(2021) 229690, https://doi.org/10.1016/j.jpowsour.2021.229690M. J. Lain, E. Kendrick, J. Power Sources 493(2021) 229690, https://doi.org/10.1016/j.jpowsour.2021.229690
5. [5]
  C. Arbizzani, G. Gabrielli, M. Mastragostino, J. Power Sources 196(2011) 4801, https://doi.org/10.1016/j.jpowsour.2011.01.068C. Arbizzani, G. Gabrielli, M. Mastragostino, J. Power Sources 196(2011) 4801, https://doi.org/10.1016/j.jpowsour.2011.01.068
6. [6]
  S. Hess, M. Wohlfahrt-Mehrens, M. Wachtler, J. Electrochem. Soc. 162(2015) A3084, https://doi.org/10.1149/2.0121502jesS. Hess, M. Wohlfahrt-Mehrens, M. Wachtler, J. Electrochem. Soc. 162(2015) A3084, https://doi.org/10.1149/2.0121502jes
7. [7]
  H. Lee, N. Sitapure, S. Hwang, J. S.-I. Kwon, Comput. Chem. Eng. 153(2021) 107415, https://doi.org/10.1016/j.compchemeng.2021.107415H. Lee, N. Sitapure, S. Hwang, J. S.-I. Kwon, Comput. Chem. Eng. 153(2021) 107415, https://doi.org/10.1016/j.compchemeng.2021.107415
8. [8]
  X. Gao, Y.-N. Zhou, D. Han, J. Zhou, D. Zhou, W. Tang, J. B. Goodenough, Joule 4(2020) 1864, https://doi.org/10.1016/j.joule.2020.06.016X. Gao, Y.-N. Zhou, D. Han, J. Zhou, D. Zhou, W. Tang, J. B. Goodenough, Joule 4(2020) 1864, https://doi.org/10.1016/j.joule.2020.06.016
9. [9]
  H. Vikström, S. Davidsson, M. Höök, Appl. Energy 110(2013) 252, https://doi.org/10.1016/j.apenergy.2013.04.005H. Vikström, S. Davidsson, M. Höök, Appl. Energy 110(2013) 252, https://doi.org/10.1016/j.apenergy.2013.04.005
10. [10]
  S. E. Kesler, P. W. Gruber, P. A. Medina, G. A. Keoleian, M. P. Everson, T. J. Wallington, Ore Geol. Rev. 48(2012) 55, https://doi.org/10.1016/j.oregeorev.2012.05.006S. E. Kesler, P. W. Gruber, P. A. Medina, G. A. Keoleian, M. P. Everson, T. J. Wallington, Ore Geol. Rev. 48(2012) 55, https://doi.org/10.1016/j.oregeorev.2012.05.006
11. [11]
  G. M. Mudd, S. M. Jowitt, Econ. Geol. 109(2014) 1813, https://doi.org/10.2113/econgeo.109.7.1813G. M. Mudd, S. M. Jowitt, Econ. Geol. 109(2014) 1813, https://doi.org/10.2113/econgeo.109.7.1813
12. [12]
  X. Fu, D. N. Beatty, G. G. Gaustad, G. Ceder, R. Roth, R. E. Kirchain, M. Bustamante, C. Babbitt, E. A. Olivetti, Environ. Sci. Technol. 54(2020) 2985, https://doi.org/10.1021/acs.est.9b04975X. Fu, D. N. Beatty, G. G. Gaustad, G. Ceder, R. Roth, R. E. Kirchain, M. Bustamante, C. Babbitt, E. A. Olivetti, Environ. Sci. Technol. 54(2020) 2985, https://doi.org/10.1021/acs.est.9b04975
13. [13]
  F. Gschwind, G. Rodriguez-Garcia, D. Sandbeck, A. Gross, M. Weil, M. Fichtner, N. Hörmann, J. Fluorine Chem. 182(2016) 76, https://doi.org/10.1016/j.jfluchem.2015.12.002F. Gschwind, G. Rodriguez-Garcia, D. Sandbeck, A. Gross, M. Weil, M. Fichtner, N. Hörmann, J. Fluorine Chem. 182(2016) 76, https://doi.org/10.1016/j.jfluchem.2015.12.002
14. [14]
  M. Zhang, X. Cao, Y. Hao, H. Wang, J. Pu, B. Chi, Z. Shen, Energy Rev. 3(2024) 100083, https://doi.org/10.1016/j.enrev.2024.100083M. Zhang, X. Cao, Y. Hao, H. Wang, J. Pu, B. Chi, Z. Shen, Energy Rev. 3(2024) 100083, https://doi.org/10.1016/j.enrev.2024.100083
15. [15]
  M. A. Nowroozi, I. Mohammad, P. Molaiyan, K. Wissel, A. R. Munnangi, O. Clemens, J. Mater. Chem. A 9(2021) 5980, https://doi.org/10.1039/d0ta11656dM. A. Nowroozi, I. Mohammad, P. Molaiyan, K. Wissel, A. R. Munnangi, O. Clemens, J. Mater. Chem. A 9(2021) 5980, https://doi.org/10.1039/d0ta11656d
16. [16]
  A. W. Xiao, G. Galatolo, M. Pasta, Joule 5(2021) 2823, https://doi.org/10.1016/j.joule.2021.09.016A. W. Xiao, G. Galatolo, M. Pasta, Joule 5(2021) 2823, https://doi.org/10.1016/j.joule.2021.09.016
17. [17]
  H. Nakano, T. Matsunaga, T. Mori, K. Nakanishi, Y. Morita, K. Ide, K.-i. Okazaki, Y. Orikasa, T. Minato, K. Yamamoto, Chem. Mater. 33(2020) 459, https://doi.org/10.1021/acs.chemmater.0c04570H. Nakano, T. Matsunaga, T. Mori, K. Nakanishi, Y. Morita, K. Ide, K.-i. Okazaki, Y. Orikasa, T. Minato, K. Yamamoto, Chem. Mater. 33(2020) 459, https://doi.org/10.1021/acs.chemmater.0c04570
18. [18]
  I. Mohammad, R. Witter, M. Fichtner, M. Anji Reddy, ACS Appl. Energy Mater. 1(2018) 4766, https://doi.org/10.1021/acsaem.8b00864I. Mohammad, R. Witter, M. Fichtner, M. Anji Reddy, ACS Appl. Energy Mater. 1(2018) 4766, https://doi.org/10.1021/acsaem.8b00864
19. [19]
  Y. Yu, M. Lei, D. Li, C. Li, Adv. Energy Mater. 13(2023) 2203168, https://doi.org/10.1002/aenm.202203168Y. Yu, M. Lei, D. Li, C. Li, Adv. Energy Mater. 13(2023) 2203168, https://doi.org/10.1002/aenm.202203168
20. [20]
  Y. Yu, G. Li, C. Li, Adv. Funct. Mater. 35(2025) 2410891, https://doi.org/10.1002/adfm.202410891Y. Yu, G. Li, C. Li, Adv. Funct. Mater. 35(2025) 2410891, https://doi.org/10.1002/adfm.202410891
21. [21]
  G. Li, D. Li, M. Lei, C. Li, Adv. Energy Mater. 15(2025) 2404282, https://doi.org/10.1002/aenm.202404282G. Li, D. Li, M. Lei, C. Li, Adv. Energy Mater. 15(2025) 2404282, https://doi.org/10.1002/aenm.202404282
22. [22]
  G. Li, Y. Yu, D. Li, C. Li, Adv. Funct. Mater. 34(2024) 2406421, https://doi.org/10.1002/adfm.202406421G. Li, Y. Yu, D. Li, C. Li, Adv. Funct. Mater. 34(2024) 2406421, https://doi.org/10.1002/adfm.202406421
23. [23]
  D. T. Thieu, M. Hammad, H. Bhatia, T. Diemant, V. S. K. Chakravadhanula, R. J. Behm, C. Kubel, M. Fichtner, Adv. Funct. Mater. 27(2017) 1701051, https://doi.org/10.1002/adfm.201701051D. T. Thieu, M. Hammad, H. Bhatia, T. Diemant, V. S. K. Chakravadhanula, R. J. Behm, C. Kubel, M. Fichtner, Adv. Funct. Mater. 27(2017) 1701051, https://doi.org/10.1002/adfm.201701051
24. [24]
  I. Mohammad, R. Witter, Mater. Lett. 244(2019) 159, https://doi.org/10.1016/j.matlet.2019.02.052I. Mohammad, R. Witter, Mater. Lett. 244(2019) 159, https://doi.org/10.1016/j.matlet.2019.02.052
25. [25]
  M. A. Nowroozi, I. Mohammad, P. Molaiyan, K. Wissel, A. R. Munnangi, O. Clemens, J. Mater. Chem. A 9(2021) 5980, https://doi.org/10.1039/d0ta11656dM. A. Nowroozi, I. Mohammad, P. Molaiyan, K. Wissel, A. R. Munnangi, O. Clemens, J. Mater. Chem. A 9(2021) 5980, https://doi.org/10.1039/d0ta11656d
26. [26]
  M. A. Nowroozi, K. Wissel, M. Donzelli, N. Hosseinpourkahvaz, S. Plana-Ruiz, U. Kolb, R. Schoch, M. Bauer, A. M. Malik, J. Rohrer, S. Ivlev, F. Kraus, O. Clemens, Commun. Mater. 1(2020) 27, https://doi.org/10.1038/s43246-020-0030-5M. A. Nowroozi, K. Wissel, M. Donzelli, N. Hosseinpourkahvaz, S. Plana-Ruiz, U. Kolb, R. Schoch, M. Bauer, A. M. Malik, J. Rohrer, S. Ivlev, F. Kraus, O. Clemens, Commun. Mater. 1(2020) 27, https://doi.org/10.1038/s43246-020-0030-5
27. [27]
  K. Wissel, A. M. Malik, S. Vasala, S. Plana-Ruiz, U. Kolb, P. R. Slater, I. da Silva, L. Alff, J. Rohrer, O. Clemens, Chem. Mater. 32(2020) 3160, https://doi.org/10.1021/acs.chemmater.0c00193K. Wissel, A. M. Malik, S. Vasala, S. Plana-Ruiz, U. Kolb, P. R. Slater, I. da Silva, L. Alff, J. Rohrer, O. Clemens, Chem. Mater. 32(2020) 3160, https://doi.org/10.1021/acs.chemmater.0c00193
28. [28]
  K. Wissel, R. Schoch, T. Vogel, M. Donzelli, G. Matveeva, U. Kolb, M. Bauer, P. R. Slater, O. Clemens, Chem. Mater. 33(2021) 499, https://doi.org/10.1021/acs.chemmater.0c01762K. Wissel, R. Schoch, T. Vogel, M. Donzelli, G. Matveeva, U. Kolb, M. Bauer, P. R. Slater, O. Clemens, Chem. Mater. 33(2021) 499, https://doi.org/10.1021/acs.chemmater.0c01762
29. [29]
  M. A. Nowroozi, S. Ivlev, J. Rohrer, O. Clemens, J. Mater. Chem. A 6(2018) 4658, https://doi.org/10.1039/c7ta09427bM. A. Nowroozi, S. Ivlev, J. Rohrer, O. Clemens, J. Mater. Chem. A 6(2018) 4658, https://doi.org/10.1039/c7ta09427b
30. [30]
  M. A. Nowroozi, K. Wissel, J. Rohrer, A. R. Munnangi, O. Clemens, Chem. Mater. 29(2017) 3441, https://doi.org/10.1021/acs.chemmater.6b05075M. A. Nowroozi, K. Wissel, J. Rohrer, A. R. Munnangi, O. Clemens, Chem. Mater. 29(2017) 3441, https://doi.org/10.1021/acs.chemmater.6b05075
31. [31]
  Y. Wang, K. Yamamoto, Y. Tsujimoto, T. Matsunaga, D. Zhang, Z. Cao, K. Nakanishi, T. Uchiyama, T. Watanabe, T. Takami, H. Miki, H. Iba, K. Maeda, H. Kageyama, Y. Uchimoto, Chem. Mater. 34(2022) 609, https://doi.org/10.1021/acs.chemmater.1c03189Y. Wang, K. Yamamoto, Y. Tsujimoto, T. Matsunaga, D. Zhang, Z. Cao, K. Nakanishi, T. Uchiyama, T. Watanabe, T. Takami, H. Miki, H. Iba, K. Maeda, H. Kageyama, Y. Uchimoto, Chem. Mater. 34(2022) 609, https://doi.org/10.1021/acs.chemmater.1c03189
32. [32]
  V. Vanita, G. Mezzadra., C. Tealdi, O. Clemens, ACS Appl. Energy Mater. 8(2025) 7562, https://doi.org/10.1021/acsaem.5c00875V. Vanita, G. Mezzadra., C. Tealdi, O. Clemens, ACS Appl. Energy Mater. 8(2025) 7562, https://doi.org/10.1021/acsaem.5c00875
33. [33]
  S. Vasala, A. Jakob, K. Wissel, A. I. Waidha, L. Alff, O. Clemens, Adv. Electron Mater. 6(2020) 1900974, https://doi.org/10.1002/aelm.201900974S. Vasala, A. Jakob, K. Wissel, A. I. Waidha, L. Alff, O. Clemens, Adv. Electron Mater. 6(2020) 1900974, https://doi.org/10.1002/aelm.201900974
34. [34]
  H. Miki, K. Yamamoto, C. Shuo, T. Matsunaga, M. Kumar, N. Thakur, Y. Sakaguchi, T. Watanabe, H. Iba, H. Kageyama, Y. Uchimoto, Solid State Ionics 406(2024) 116480, https://doi.org/10.1016/j.ssi.2024.116480H. Miki, K. Yamamoto, C. Shuo, T. Matsunaga, M. Kumar, N. Thakur, Y. Sakaguchi, T. Watanabe, H. Iba, H. Kageyama, Y. Uchimoto, Solid State Ionics 406(2024) 116480, https://doi.org/10.1016/j.ssi.2024.116480
35. [35]
  H. Miki, K. Yamamoto, H. Nakaki, T. Yoshinari, K. Nakanishi, S. Nakanishi, H. Iba, J. Miyawaki, Y. Harada, A. Kuwabara, Y. Wang, T. Watanabe, T. Matsunaga, K. Maeda, H. Kageyama, Y. Uchimoto, J. Am. Chem. Soc. 146(2024) 3844, https://doi.org/10.1021/jacs.3c10871H. Miki, K. Yamamoto, H. Nakaki, T. Yoshinari, K. Nakanishi, S. Nakanishi, H. Iba, J. Miyawaki, Y. Harada, A. Kuwabara, Y. Wang, T. Watanabe, T. Matsunaga, K. Maeda, H. Kageyama, Y. Uchimoto, J. Am. Chem. Soc. 146(2024) 3844, https://doi.org/10.1021/jacs.3c10871
36. [36]
  G. Galatolo, O. Alshangiti, C. Di Mino, G. Matthews, A. W. Xiao, G. J. Rees, M. Schart, Y. A. Chart, L. F. Olbrich, M. Pasta, ACS Energy Lett. 9(2023) 85, https://doi.org/10.1021/acsenergylett.3c02228G. Galatolo, O. Alshangiti, C. Di Mino, G. Matthews, A. W. Xiao, G. J. Rees, M. Schart, Y. A. Chart, L. F. Olbrich, M. Pasta, ACS Energy Lett. 9(2023) 85, https://doi.org/10.1021/acsenergylett.3c02228
37. [37]
  H. Chen, T. Aalto, V. Vanita, O. Clemens, Small Struct. 5(2024) 2300570, https://doi.org/10.1002/sstr.202300570H. Chen, T. Aalto, V. Vanita, O. Clemens, Small Struct. 5(2024) 2300570, https://doi.org/10.1002/sstr.202300570
38. [38]
  M. H. Ehsani, M. E. Ghazi, P. Kameli, F. S. Razavi, J. Alloy Compd. 586(2014) 261, https://doi.org/10.1016/j.jallcom.2013.10.002M. H. Ehsani, M. E. Ghazi, P. Kameli, F. S. Razavi, J. Alloy Compd. 586(2014) 261, https://doi.org/10.1016/j.jallcom.2013.10.002
39. [39]
  V. Vanita, A. I. Waidha, S. Vasala, P. Puphal, R. Schoch, P. Glatzel, M. Bauer, O. Clemens, J. Mater. Chem. A 12(2024) 8769, https://doi.org/10.1039/d4ta00704bV. Vanita, A. I. Waidha, S. Vasala, P. Puphal, R. Schoch, P. Glatzel, M. Bauer, O. Clemens, J. Mater. Chem. A 12(2024) 8769, https://doi.org/10.1039/d4ta00704b
40. [40]
  L. Aikens, L. Gillie, R. Li, C. Greaves, J. Mater. Chem. A 12(2002) 264, https://doi.org/10.1039/B105550JL. Aikens, L. Gillie, R. Li, C. Greaves, J. Mater. Chem. A 12(2002) 264, https://doi.org/10.1039/B105550J
41. [41]
  C. Greaves, J. L. Kissick, M. G. Francesconi, L. D. Aikens, L. J. Gillie, J. Mater. Chem. A 9(1999) 111, https://doi.org/10.1039/A804447CC. Greaves, J. L. Kissick, M. G. Francesconi, L. D. Aikens, L. J. Gillie, J. Mater. Chem. A 9(1999) 111, https://doi.org/10.1039/A804447C
42. [42]
  R. S. Liu, L. Y. Jang, J. M. Chen, J. B. Wu, R. G. Liu, J. G. Lin, C. Y. Huang, Solid State Commun. 105(1998) 605, https://doi.org/10.1016/S0038-1098(98)80003-3R. S. Liu, L. Y. Jang, J. M. Chen, J. B. Wu, R. G. Liu, J. G. Lin, C. Y. Huang, Solid State Commun. 105(1998) 605, https://doi.org/10.1016/S0038-1098(98)80003-3
43. [43]
  M. Abu-Samak, U. Kumar, A. M. Quraishi, R. Kumar, S. Kumar, S. Dalela, M. A. Ahmad, B. L. Choudhary, P. A. Alvi, Phys. B 628(2022) 413562, https://doi.org/41356210.1016/j.physb.2021.413562M. Abu-Samak, U. Kumar, A. M. Quraishi, R. Kumar, S. Kumar, S. Dalela, M. A. Ahmad, B. L. Choudhary, P. A. Alvi, Phys. B 628(2022) 413562, https://doi.org/41356210.1016/j.physb.2021.413562
44. [44]
  T. Yamamoto, Int. Tables Crystallogr. 1(2024) 80, https://doi.org/10.1107/S157487072000751XT. Yamamoto, Int. Tables Crystallogr. 1(2024) 80, https://doi.org/10.1107/S157487072000751X
45. [45]
  M. Kubota, H. Yoshizawa, H. Fujioka, K. Hirota, K. Ohoyama, Y. Endoh, Y. Moritomo, J. Phys. Soc. Jpn. 69(2000) 1606, https://doi.org/10.1143/JPSJ.69.1606M. Kubota, H. Yoshizawa, H. Fujioka, K. Hirota, K. Ohoyama, Y. Endoh, Y. Moritomo, J. Phys. Soc. Jpn. 69(2000) 1606, https://doi.org/10.1143/JPSJ.69.1606
46. [46]
  I. B. Sharma, D. Singh, Proc. Indian Acad. Sci. Chem. Sci. 107(1995) 189, https://doi.org/10.1007/BF02884435I. B. Sharma, D. Singh, Proc. Indian Acad. Sci. Chem. Sci. 107(1995) 189, https://doi.org/10.1007/BF02884435
47. [47]
  A. S. Erchidi Elyacoubi, R. Masrour, A. Jabar, E. K. Hlil, J. Low Temp. Phys. 203(2021) 419, https://doi.org/10.1007/s10909-021-02592-wA. S. Erchidi Elyacoubi, R. Masrour, A. Jabar, E. K. Hlil, J. Low Temp. Phys. 203(2021) 419, https://doi.org/10.1007/s10909-021-02592-w
48. [48]
  Tommi Hendrik Aalto, T. Widder, Eberhard Goering, Peter Nagel, Kerstin Wissel, Oliver Clemens Preprint, https://doi.org/10.26434/chemrxiv-2025-qlbkpTommi Hendrik Aalto, T. Widder, Eberhard Goering, Peter Nagel, Kerstin Wissel, Oliver Clemens Preprint, https://doi.org/10.26434/chemrxiv-2025-qlbkp
49. [49]
  T. H. Aalto, R. Talei, K. Küster, G. Schmitz, O. Clemens, Batteries Supercaps (2025) 2500195, https://doi.org/10.1002/batt.202500195T. H. Aalto, R. Talei, K. Küster, G. Schmitz, O. Clemens, Batteries Supercaps (2025) 2500195, https://doi.org/10.1002/batt.202500195
50. [50]
  H. Chen, R. Schoch, J. N. Chotard, Y. M. Thiebes, K. Wissel, R. Niewa, M. Bauer, O. Clemens, Small Methods (2025) e2500374, https://doi.org/10.1002/smtd.202500374H. Chen, R. Schoch, J. N. Chotard, Y. M. Thiebes, K. Wissel, R. Niewa, M. Bauer, O. Clemens, Small Methods (2025) e2500374, https://doi.org/10.1002/smtd.202500374

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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: Oliver Clemens,Email:oliver.clemens@imw.uni-stuttgart.de

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