Na2S/Na2SO3溶液促进NiS2/Mn0.5Cd0.5S肖特基/S型孪晶同质结光催化转化H2S

引用本文: 肖子翼, 马心怡, 王林平, 胡浩斌, 刘恩周. Na₂S/Na₂SO₃溶液促进NiS₂/Mn_0.5Cd_0.5S肖特基/S型孪晶同质结光催化转化H₂S[J]. 物理化学学报, 2026, 42(4): 100171. doi: 10.1016/j.actphy.2025.100171 shu

Citation: Ziyi Xiao, Xinyi Ma, Linping Wang, Haobin Hu, Enzhou Liu. Efficient photocatalytic conversion H₂S over NiS₂/twinned-Mn_0.5Cd_0.5S Schottky/S-scheme homojunction in Na₂S/Na₂SO₃ solution[J]. Acta Physico-Chimica Sinica, 2026, 42(4): 100171. doi: 10.1016/j.actphy.2025.100171 shu

Na₂S/Na₂SO₃溶液促进NiS₂/Mn_0.5Cd_0.5S肖特基/S型孪晶同质结光催化转化H₂S

肖子翼 ^1, ,
马心怡 ^1, ,
王林平 ^2, ,
胡浩斌 ^{3,
,} ,
刘恩周 ^{1,
,}

1.
西北大学化工学院/西安市特种能源材料重点实验室, 陕西西安 710069
2.
中石油长庆油田分公司油气工艺研究院, 陕西西安 710021
3.
甘肃省陇东油气资源高效利用重点实验室, 陇东学院, 甘肃庆阳 745000

通讯作者: Email: hhb-88@126.com (胡浩斌); liuenzhou@nwu.edu.cn (刘恩周)

摘要: 将硫化氢(H₂S)有毒废气转化为氢气(H₂)和高附加值含硫化学品一直是光催化分解H₂S领域的重要研究目标。本文借助孪晶Mn_0.5Cd_0.5S (T-MCS)固溶体的结构优势促进光催化剂体相电荷分离，并将导电性能优异的二硫化镍(NiS₂)负载于T-MCS表面，构建了NiS₂/T-MCS界面肖特基结与体相S型孪晶同质结复合光催化剂。研究表明，NiS₂不仅引入了大量活性位点，而且显著改善了表面电荷分离效率。以0.1 mol L⁻¹ (M)硫化钠(Na₂S)与0.6 M无水亚硫酸钠(Na₂SO₃)吸收H₂S后的饱和溶液作为反应液，8 wt% NiS₂/T-MCS复合材料产氢速率可达59.95 mmol h⁻¹ g⁻¹。傅里叶变换红外光谱(FTIR)与紫外-可见吸收光谱(UV-Vis)证实反应液中硫化合物几乎完全转化为硫代硫酸钠(Na₂S₂O₃)，并通过滴定法对S₂O₃²⁻含量进行了定量测定。本文制备的肖特基结与固溶体孪晶同质结复合材料为开发高效H₂S光催化转化体系，以及同时获得H₂和Na₂S₂O₃提供了重要实验参考。

关键词:

English

Efficient photocatalytic conversion H₂S over NiS₂/twinned-Mn_0.5Cd_0.5S Schottky/S-scheme homojunction in Na₂S/Na₂SO₃ solution

Ziyi Xiao ^1, ,
Xinyi Ma ^1, ,
Linping Wang ^2, ,
Haobin Hu ^{3,
,} ,
Enzhou Liu ^{1,
,}

1.
School of Chemical Engineering/Xi'an Key Laboratory of Special Energy Materials, Northwest University, Xi'an 710069, Shaanxi Province, China
2.
PetroChina Changqing Oilfield Company Oil and Gas Technology Research Institute, Xi'an 710021, Shaanxi Province, China
3.
Gansu Key Laboratory of Efficient Utilization of Oil and Gas Resources in Longdong, Longdong University, Qingyang 745000, Gansu Province, China

Corresponding author: Email: hhb-88@126.com (Hu Haobin); liuenzhou@nwu.edu.cn (Liu Enzhou)

Received Date: 26 July 2025
Accepted Date: 20 August 2025
Revised Date: 19 August 2025
Available Online: 15 April 2026

Abstract: The concurrent production of hydrogen (H₂) and high-value products from waste and toxic hydrogen sulfide (H₂S) has long been a goal in the field of photocatalytic decomposition of H₂S. In this study, the twinned Mn_0.5Cd_0.5S (T-MCS) was selected for its combination of solid solution and twin structure advantages, significantly promoting the bulk phase separation of CdS-based photocatalysts. Furthermore, the highly conductive nickel disulfide (NiS₂) was loaded onto T-MCS to create a NiS₂/T-MCS composite photocatalyst that features both a bulk phase S-scheme homojunction and an interface Schottky junction. NiS₂ not only introduces a large number of active sites, but also improves the separation of surface charges obviously. Utilizing a 0.1 mol L⁻¹ (M) sodium sulfide (Na₂S) and 0.6 M anhydrous sodium sulfite (Na₂SO₃) solution saturated with H₂S as the reaction solution, the 8 wt% NiS₂/T-MCS composite achieves a remarkable hydrogen production rate of up to 59.95 mmol h⁻¹ g⁻¹. Fourier Transform Infrared (FTIR) spectroscopy and Ultraviolet-Visible (UV-Vis) spectroscopy confirm that the sulfur compounds in the reaction solution are nearly completely converted into high-value sodium thiosulfate (Na₂S₂O₃). The S₂O₃²⁻ was also quantitatively determined by titration. This work presents a novel solid solution twin crystal-based homojunction and Schottky junction for both the photocatalytic treatment of H₂S and the production of Na₂S₂O₃.

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沈阳化工大学材料科学与工程学院沈阳 110142

Na₂S/Na₂SO₃溶液促进NiS₂/Mn_0.5Cd_0.5S肖特基/S型孪晶同质结光催化转化H₂S

通讯作者: Email: hhb-88@126.com (胡浩斌); liuenzhou@nwu.edu.cn (刘恩周)

English

Efficient photocatalytic conversion H₂S over NiS₂/twinned-Mn_0.5Cd_0.5S Schottky/S-scheme homojunction in Na₂S/Na₂SO₃ solution

Corresponding author: Email: hhb-88@126.com (Hu Haobin); liuenzhou@nwu.edu.cn (Liu Enzhou)

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