稠油的可控氧化热采:MnO<sub>2</sub>催化剂上的重油低温氧化分解行为

引用本文: 樊铖, 张强, 魏飞. 稠油的可控氧化热采:MnO₂催化剂上的重油低温氧化分解行为[J]. 催化学报, 2015, 36(2): 153-159. doi: 10.1016/S1872-2067(14)60236-9 shu

Citation: Cheng Fan, Qiang Zhang, Fei Wei. Controllable oxidation for oil recovery: Low temperature oxidative decomposition of heavy oil on a MnO₂ catalyst[J]. Chinese Journal of Catalysis, 2015, 36(2): 153-159. doi: 10.1016/S1872-2067(14)60236-9 shu

稠油的可控氧化热采:MnO₂催化剂上的重油低温氧化分解行为

通讯作者: 张强

基金项目:
国家自然科学基金(21422604) (21422604)

中石油油气田开发专项(2011A-1006). (2011A-1006)

摘要: 采用MnO₂纳米催化剂促进稠油重组分的低温氧化裂解及高温氧化生热, 进而促进火烧油层技术在超稠油油藏开发中的应用, 提高火烧油层技术的采收率. 结果表明, MnO₂促进了稠油的低温裂解, 高温生热量并不随燃料沉积量的减少而降低. MnO₂的加入促进了低温下小分子的生成, 并使高温氧化反应更加温和, 提高了高温产物的氧化度. 相比无催化剂的氧化反应, MnO₂使稠油的低温氧化和高温氧化的表观活化能分别降低了10-30 kJ/mol和20-40 kJ/mol.

关键词:

English

Controllable oxidation for oil recovery: Low temperature oxidative decomposition of heavy oil on a MnO₂ catalyst

1.
Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: 张强

Received Date: 16 August 2014
Available Online: 20 February 2015
Fund Project:
国家自然科学基金(21422604)

中石油油气田开发专项(2011A-1006).

Abstract: Heavy oil is a readily available alternative energy resource with a reserve that is more than twice that of conventional light oil. In situ combustion is one of the most promising strategies for heavy oil exploitation, and the modulating of the oxidation behavior of heavy oil is an efficient way to expand the applicability of the in situ combustion method. MnO₂ nanoparticles were employed to facilitate the cracking of heavy compounds, promote heat production, and improve recovery efficiency. The oxidative decomposition rate of heavy oil was doubled in the low temperature interval, and the heat release rate was accelerated in the high temperature interval. The increased weight loss at low temperature was attributed to the decomposition of heavy components. The detection of incomplete oxidation products by mass spectroscopy under excessive oxygen flow at high temperature indicated a diffusion controlled process of oil combustion. The same amount of CO₂ from the combustion of less fuel demonstrated an increased oxidation degree of the products. The apparent activation energies of the oxidation reactions were decreased by 10-30 kJ/mol at low temperature and 20-40 kJ/mol at high temperature by the addition of MnO₂. MnO₂ can render in situ combustion more feasible for various oil reservoirs, and is also promising for other thermal recovery processes for improved oil recovery.

Key words:

1. [1] Chu S, Majumdar A. Nature, 2012, 488: 294[1] Chu S, Majumdar A. Nature, 2012, 488: 294
2. [2] Al-Bahlani A M, Babadagli T. Chem Eng J, 2012, 181: 557[2] Al-Bahlani A M, Babadagli T. Chem Eng J, 2012, 181: 557
3. [3] Vogel G H. Chem Eng Technol, 2008, 31: 730[3] Vogel G H. Chem Eng Technol, 2008, 31: 730
4. [4] Keim W. Petrol Chem, 2010, 50: 298[4] Keim W. Petrol Chem, 2010, 50: 298
5. [5] Li Y F, Wang H F, Wang G, Gao J S. Chem Eng J, 2012, 211: 255[5] Li Y F, Wang H F, Wang G, Gao J S. Chem Eng J, 2012, 211: 255
6. [6] Shah A, Fishwick R, Wood J, Leeke G, Rigby S, Greaves M. Energy Environ Sci, 2010, 3: 700[6] Shah A, Fishwick R, Wood J, Leeke G, Rigby S, Greaves M. Energy Environ Sci, 2010, 3: 700
7. [7] Brüggemann P, Baitalow F, Seifert P, Meyer B, Schlichting H. Fuel Process Technol, 2010, 91: 211[7] Brüggemann P, Baitalow F, Seifert P, Meyer B, Schlichting H. Fuel Process Technol, 2010, 91: 211
8. [8] Zhao D W, Wang J, Gates I D. Fuel, 2014, 117: 431[8] Zhao D W, Wang J, Gates I D. Fuel, 2014, 117: 431
9. [9] Chu Y, Fan C, Zhang Q, Zan C, Ma D S, Jiang H, Wang Y, Wei F. Chem Eng J, 2014, 248: 422[9] Chu Y, Fan C, Zhang Q, Zan C, Ma D S, Jiang H, Wang Y, Wei F. Chem Eng J, 2014, 248: 422
10. [10] Moore R G, Laureshen C J, Ursenbach M G, Mehta S A, Belgrave J D M. J Can Petrol Technol, 1999, 38(13): 96[10] Moore R G, Laureshen C J, Ursenbach M G, Mehta S A, Belgrave J D M. J Can Petrol Technol, 1999, 38(13): 96
11. [11] Weissman J G, Kessler R V, Sawicki R A, Belgrave J D M, Laureshen C J, Mehta S A, Moore R G, Ursenbach M G. Energy Fuels, 1996, 10: 883[11] Weissman J G, Kessler R V, Sawicki R A, Belgrave J D M, Laureshen C J, Mehta S A, Moore R G, Ursenbach M G. Energy Fuels, 1996, 10: 883
12. [12] Shah A, Fishwick R P, Leeke G A, Wood J, Rigby S P, Greaves M. J Can Petrol Technol, 2011, 50(11-12): 33[12] Shah A, Fishwick R P, Leeke G A, Wood J, Rigby S P, Greaves M. J Can Petrol Technol, 2011, 50(11-12): 33
13. [13] Xia T X, Greaves M. J Can Petrol Technol, 2002, 41(8): 58[13] Xia T X, Greaves M. J Can Petrol Technol, 2002, 41(8): 58
14. [14] Xia T X, Greaves M. In: SPE International Thermal Operations and Heavy Oil Symposium. Margarita Island: The Society of Petroleum Engineers, 2001. 69693[14] Xia T X, Greaves M. In: SPE International Thermal Operations and Heavy Oil Symposium. Margarita Island: The Society of Petroleum Engineers, 2001. 69693
15. [15] Greaves M, Xia T X. J Can Petrol Technol, 2004, 43(9): 25[15] Greaves M, Xia T X. J Can Petrol Technol, 2004, 43(9): 25
16. [16] Hart A. Int J Petrol Sci Technol, 2012, 6(2): 79[16] Hart A. Int J Petrol Sci Technol, 2012, 6(2): 79
17. [17] Hashemi R, Nassar N N, Almao P P. Energy Fuels, 2013, 27: 2194[17] Hashemi R, Nassar N N, Almao P P. Energy Fuels, 2013, 27: 2194
18. [18] Reservoir Engineering Section on in situ Combustion. Department of Energy of the United States. California, 1998[18] Reservoir Engineering Section on in situ Combustion. Department of Energy of the United States. California, 1998
19. [19] The Effect of Metallic Additives on the Kinetics of Oil Oxidation Reactions in in situ Combustion. Department of Energy of the United States. California, 1988[19] The Effect of Metallic Additives on the Kinetics of Oil Oxidation Reactions in in situ Combustion. Department of Energy of the United States. California, 1988
20. [20] Zhao M Q, Zhang Q, Huang J Q, Wei F. Adv Funct Mater, 2012, 22: 675[20] Zhao M Q, Zhang Q, Huang J Q, Wei F. Adv Funct Mater, 2012, 22: 675
21. [21] Zaera F. ChemSusChem, 2013, 6: 1797[21] Zaera F. ChemSusChem, 2013, 6: 1797
22. [22] Sun X Y, Wang R, Su D S. Chin J Catal (孙晓岩, 王锐, 苏党生. 催化学报), 2013, 34: 508[22] Sun X Y, Wang R, Su D S. Chin J Catal (孙晓岩, 王锐, 苏党生. 催化学报), 2013, 34: 508
23. [23] Montes A R, Gutierrez D, Moore R G, Mehta S A, Ursenbach M G. J Can Petrol Technol, 2010, 49(2): 56[23] Montes A R, Gutierrez D, Moore R G, Mehta S A, Ursenbach M G. J Can Petrol Technol, 2010, 49(2): 56
24. [24] Chao K, Chen Y L, Liu H C, Zhang X M, Li J. Energy Fuels, 2012, 26: 1152[24] Chao K, Chen Y L, Liu H C, Zhang X M, Li J. Energy Fuels, 2012, 26: 1152
25. [25] Castanier L M, Brigham W E. In Situ, 1997, 21: 27[25] Castanier L M, Brigham W E. In Situ, 1997, 21: 27
26. [26] Shallcross D C, De los Rios C F, Castanier L M, Brigham W E. SPE Reservoir Engineering, 1991, 6: 287[26] Shallcross D C, De los Rios C F, Castanier L M, Brigham W E. SPE Reservoir Engineering, 1991, 6: 287
27. [27] Castanier L M, Baena C J, Holt R J, Brigham W E, Tavares C. In: Proceedings of the 2nd Latin American Petroleum Conference. Caracas: The Society of Petroleum Engineers, 1992. 23708[27] Castanier L M, Baena C J, Holt R J, Brigham W E, Tavares C. In: Proceedings of the 2nd Latin American Petroleum Conference. Caracas: The Society of Petroleum Engineers, 1992. 23708
28. [28] Nares H R, Schachat-Hernandez P, Ramirez-Garnica M A, Cabrera-Reyes M C, Noe-Valencia L, La Salle U. In: Latin American and Caribbean Petroleum Engineering Conference. Buenos Aires: The Society of Petroleum Engineers, 2007. 107837[28] Nares H R, Schachat-Hernandez P, Ramirez-Garnica M A, Cabrera-Reyes M C, Noe-Valencia L, La Salle U. In: Latin American and Caribbean Petroleum Engineering Conference. Buenos Aires: The Society of Petroleum Engineers, 2007. 107837
29. [29] Castanier L M, Brigham W E. J Petrol Sci Eng, 2003, 39: 125[29] Castanier L M, Brigham W E. J Petrol Sci Eng, 2003, 39: 125
30. [30] Racz D. In: Proceedings of European Meeting on Improved Oil Recovery. Rome, 1985[30] Racz D. In: Proceedings of European Meeting on Improved Oil Recovery. Rome, 1985
31. [31] In situ Combustion Handbook Principles and Practices. Department of Energy of the United States. California, 1999[31] In situ Combustion Handbook Principles and Practices. Department of Energy of the United States. California, 1999
32. [32] Shokrlu Y H, Maham Y, Tan X, Babadagli T, Gray M. Fuel, 2013, 105: 397[32] Shokrlu Y H, Maham Y, Tan X, Babadagli T, Gray M. Fuel, 2013, 105: 397
33. [33] Ramesh K, Chen L W, Chen F X, Liu Y, Wang Z, Han Y F. Catal Today, 2008, 131: 477[33] Ramesh K, Chen L W, Chen F X, Liu Y, Wang Z, Han Y F. Catal Today, 2008, 131: 477
34. [34] Shi F J, Wang F, Dai H X, Dai J X, Deng J G, Liu Y X, Bai G M, Ji K M, Au C T. Appl Catal A, 2012, 433: 206[34] Shi F J, Wang F, Dai H X, Dai J X, Deng J G, Liu Y X, Bai G M, Ji K M, Au C T. Appl Catal A, 2012, 433: 206
35. [35] Jiang F, Zhu X W, Fu B S, Huang J J, Xiao G M. Chin J Catal (姜枫, 朱晓文, 符宝嵩, 黄金金, 肖国民. 催化学报), 2013, 34: 1683[35] Jiang F, Zhu X W, Fu B S, Huang J J, Xiao G M. Chin J Catal (姜枫, 朱晓文, 符宝嵩, 黄金金, 肖国民. 催化学报), 2013, 34: 1683
36. [36] Wang M X, Zhang P Y, Li J G, Jiang C J. Chin J Catal (王鸣晓, 张彭义, 李金格, 姜传佳. 催化学报), 2014, 35: 335[36] Wang M X, Zhang P Y, Li J G, Jiang C J. Chin J Catal (王鸣晓, 张彭义, 李金格, 姜传佳. 催化学报), 2014, 35: 335
37. [37] Liang S H, Teng F, Bulgan G, Zong R L, Zhu Y F. J Phys Chem C, 2008, 112: 5307[37] Liang S H, Teng F, Bulgan G, Zong R L, Zhu Y F. J Phys Chem C, 2008, 112: 5307
38. [38] Chen C M, Zhang Q, Yang M G, Huang C H, Yang Y G, Wang M Z. Carbon, 2012, 50: 3572[38] Chen C M, Zhang Q, Yang M G, Huang C H, Yang Y G, Wang M Z. Carbon, 2012, 50: 3572
39. [39] Miura K. Energy Fuels, 1995, 9: 302[39] Miura K. Energy Fuels, 1995, 9: 302
40. [40] Miura K, Maki T. Energy Fuels, 1998, 12: 864[40] Miura K, Maki T. Energy Fuels, 1998, 12: 864
41. [41] Fan C, Zan C, Zhang Q, Ma D S, Chu Y, Jiang H, Shi L, Wei F. Fuel Process Technol, 2014, 119: 146[41] Fan C, Zan C, Zhang Q, Ma D S, Chu Y, Jiang H, Shi L, Wei F. Fuel Process Technol, 2014, 119: 146
42. [42] Liu X G, Li B Q, Miura K. Fuel Process Technol, 2001, 69: 1[42] Liu X G, Li B Q, Miura K. Fuel Process Technol, 2001, 69: 1

扫一扫看文章

计量

PDF下载量: 235
文章访问数: 776
HTML全文浏览量: 84

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

稠油的可控氧化热采:MnO₂催化剂上的重油低温氧化分解行为

通讯作者: 张强

English

Controllable oxidation for oil recovery: Low temperature oxidative decomposition of heavy oil on a MnO₂ catalyst

Corresponding author: 张强

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

稠油的可控氧化热采:MnO2催化剂上的重油低温氧化分解行为

通讯作者: 张强

English

Controllable oxidation for oil recovery: Low temperature oxidative decomposition of heavy oil on a MnO2 catalyst

Corresponding author: 张强

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

稠油的可控氧化热采:MnO₂催化剂上的重油低温氧化分解行为

Controllable oxidation for oil recovery: Low temperature oxidative decomposition of heavy oil on a MnO₂ catalyst

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs