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MOF(Fe)的制备及其氧气还原催化性能

宋国强 ,  王志清 ,  王亮 ,  李国儒 ,  黄敏建 ,  银凤翔

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引用本文: 宋国强, 王志清, 王亮, 李国儒, 黄敏建, 银凤翔. MOF(Fe)的制备及其氧气还原催化性能[J]. 催化学报, 2014, 35(2): 185-195. doi: 10.1016/S1872-2067(12)60729-3 shu
Citation:  Guoqiang Song, Zhiqing Wang, Liang Wang, Guoru Li, Minjian Huang, Fengxiang Yin. Preparation of MOF(Fe) and its catalytic activity for oxygen reduction reaction in an alkaline electrolyte[J]. Chinese Journal of Catalysis, 2014, 35(2): 185-195. doi: 10.1016/S1872-2067(12)60729-3 shu

MOF(Fe)的制备及其氧气还原催化性能

    通讯作者: Fengxiang Yin
  • 基金项目:

    国家自然科学基金（21276018）；北京市优秀人才培养资助项目（2012D009016000003）；江苏省自然科学基金（BK2012596）；常州市科技计划（工业支撑）项目（CE20120034）. 

摘要: 以硝酸铁为金属离子前驱体、均苯三甲酸为有机配体，采用水热法合成了金属有机骨架MOF（Fe）催化剂，应用X射线衍射、N2吸附-脱附、透射电镜、红外光谱和热重等方法对催化剂的结构进行了表征，并采用循环伏安法测试了催化剂在碱性电解质中的氧气还原（ORR）催化性能，同时也采用旋转圆盘电极进一步研究了催化剂的ORR的动力学行为. 结果表明，所制MOF（Fe）具有很好的晶型结构、大比表面积、丰富的微孔以及较高的热稳定性. 且表现出很好的ORR催化活性. ORR的反应历程随电位的改变而改变：电位在-0.3到0.50 V范围内，ORR为2电子途径；随着电位从-0.50 V升至-0.95 V，ORR从2电子向4电子途径转变. 另外，该催化剂在碱性电解质中也表现出较好的氧气析出（OER）催化性能，这为制备用于ORR和OER的高效非贵金属催化剂提供了新的途径.

English

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  • 发布日期:  2014-02-20
  • 收稿日期:  2013-07-31
  • 网络出版日期:  2013-10-15
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