Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

Citation: Jing Wang, Hong-ming Li, Jiang-ping Guo, Qi-gu Huang, Jian-jun Yi, Yun-fang Liu, Ke-jing Gao, Wan-tai Yang. Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization[J]. Chinese Journal of Polymer Science, 2015, 33(12): 1650-1660. doi: 10.1007/s10118-015-1719-7 shu

Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

1.
State Key Laboratory of Chemical Resource Engineering, Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
2.
Lab for Synthetic Resin Research Institution of Petrochemical Technology, China National Petroleum Corporation, Beijing 100083, China

通讯作者: Qi-gu Huang,

基金项目:
This work was financially supported by the National Natural Science Foundation of China(Nos.21174011 and U1462102).

摘要: The example of the preparation of nano- and micro-scaled, coral-shaped and core-shell topological morphology of copolyethylene particles promoted by the novel heterogeneous non-metallocene catalyst(m-CH3PhO)TiCl3/carbon nanotubes(CNTs) was reported. Mass fraction of titanium component of the catalyst was 4.0 wt% determined by ICP analysis. The catalyst system can effectively catalyze polymerization of ethylene and copolymerization of ethylene with 1-hexene. Morphological examination of the obtained polymer particles was carried out by scanning electron microscope(SEM) and high resolution transmission electron microscope(HR-TEM) technique. The results revealed that the morphology of the nascent copolyethylene particles looked like coral shape with size in micro-scaled and featured the core-shell structure consisting of CNTs as the core and copolyethylene as the shell.

关键词:

Catalysts
/ Composites
/ Copolymers

English

Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

1.
State Key Laboratory of Chemical Resource Engineering, Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
2.
Lab for Synthetic Resin Research Institution of Petrochemical Technology, China National Petroleum Corporation, Beijing 100083, China

Corresponding author: Qi-gu Huang,

Received Date: 05 May 2015
Revised Date: 05 August 2015
Available Online: 05 December 2015
Fund Project:
This work was financially supported by the National Natural Science Foundation of China(Nos.21174011 and U1462102).

Abstract: The example of the preparation of nano- and micro-scaled, coral-shaped and core-shell topological morphology of copolyethylene particles promoted by the novel heterogeneous non-metallocene catalyst(m-CH3PhO)TiCl3/carbon nanotubes(CNTs) was reported. Mass fraction of titanium component of the catalyst was 4.0 wt% determined by ICP analysis. The catalyst system can effectively catalyze polymerization of ethylene and copolymerization of ethylene with 1-hexene. Morphological examination of the obtained polymer particles was carried out by scanning electron microscope(SEM) and high resolution transmission electron microscope(HR-TEM) technique. The results revealed that the morphology of the nascent copolyethylene particles looked like coral shape with size in micro-scaled and featured the core-shell structure consisting of CNTs as the core and copolyethylene as the shell.

Key words:

Catalysts
/ Composites
/ Copolymers

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

通讯作者: Qi-gu Huang,

English

Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

Corresponding author: Qi-gu Huang,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

通讯作者: Qi-gu Huang,

English

Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

Corresponding author: Qi-gu Huang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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