The Stereocomplex Formation and Phase Separation of PLLA/PDLA Blends with Different Optical Purities and Molecular Weights

Citation: Jun Shao, Yan-long Liu, Sheng Xiang, Xin-chao Bian, Jing-ru Sun, Gao Li, Xue-si Chen, Hao-qing Hou. The Stereocomplex Formation and Phase Separation of PLLA/PDLA Blends with Different Optical Purities and Molecular Weights[J]. Chinese Journal of Polymer Science, 2015, 33(12): 1713-1720. doi: 10.1007/s10118-015-1715-y shu

The Stereocomplex Formation and Phase Separation of PLLA/PDLA Blends with Different Optical Purities and Molecular Weights

1.
1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
2.
2. Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
3.
4.
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
5.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China(Nos.51273198, 51373169, 51033003, 51303176, 51321062 and 51403089), and 863 Program(No.2011AA02A202) from the Ministry of Science and Technology of China, and Innovative Research Group(No.51321062).

摘要: In this study, the poly(L-lactide)/poly(D-lactide)(PLLA/PDLA) blends with different optical purities of PLLA and various molecular weights of PDLA are prepared by solution mixing, and the stereocomplex formation and phase separation behaviors of these blends are investigated. Results reveal that optical purity and molecular weight do not vary the crystal structure of PLA stereocomplex(sc) and homochiral crystallites(hc). As the optical purity increasing in the blends, the melting temperature of sc(Tsc) and the content of sc(Hsc) increased, while the melting temperature of hc(Thm) hardly changes, although the content of hc(Hhm) decreased gradually. The Tsc and Hsc are also enhanced as the molecular weight of PDLA reduces, and the Hhm reduces rapidly even though the Thm does not vary apparently. With lower optical purities of PLLA and higher molecular weights of PDLA, three types of crystals form in the blends, i.e., PLA sc, PLLA hc and PDLA hc. As molecular weight decreases and optical purity enhances, the crystal phase decreases to two(sc and PDLA hc), and one(sc) finally. This investigation indicates that the phase separation behavior between PLLA and PDLA in the PLLA/PDLA blends not only depends on molecular weights, but also relies on the optical purities of polymers.

关键词:

English

The Stereocomplex Formation and Phase Separation of PLLA/PDLA Blends with Different Optical Purities and Molecular Weights

1.
1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
2.
2. Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
3.
4.
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
5.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
Received Date: 18 May 2015
Revised Date: 05 July 2015
Available Online: 05 December 2015
Fund Project:
This work was financially supported by the National Natural Science Foundation of China(Nos.51273198, 51373169, 51033003, 51303176, 51321062 and 51403089), and 863 Program(No.2011AA02A202) from the Ministry of Science and Technology of China, and Innovative Research Group(No.51321062).

Abstract: In this study, the poly(L-lactide)/poly(D-lactide)(PLLA/PDLA) blends with different optical purities of PLLA and various molecular weights of PDLA are prepared by solution mixing, and the stereocomplex formation and phase separation behaviors of these blends are investigated. Results reveal that optical purity and molecular weight do not vary the crystal structure of PLA stereocomplex(sc) and homochiral crystallites(hc). As the optical purity increasing in the blends, the melting temperature of sc(Tsc) and the content of sc(Hsc) increased, while the melting temperature of hc(Thm) hardly changes, although the content of hc(Hhm) decreased gradually. The Tsc and Hsc are also enhanced as the molecular weight of PDLA reduces, and the Hhm reduces rapidly even though the Thm does not vary apparently. With lower optical purities of PLLA and higher molecular weights of PDLA, three types of crystals form in the blends, i.e., PLA sc, PLLA hc and PDLA hc. As molecular weight decreases and optical purity enhances, the crystal phase decreases to two(sc and PDLA hc), and one(sc) finally. This investigation indicates that the phase separation behavior between PLLA and PDLA in the PLLA/PDLA blends not only depends on molecular weights, but also relies on the optical purities of polymers.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

The Stereocomplex Formation and Phase Separation of PLLA/PDLA Blends with Different Optical Purities and Molecular Weights

English

The Stereocomplex Formation and Phase Separation of PLLA/PDLA Blends with Different Optical Purities and Molecular Weights

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通讯作者: 陈斌, bchen63@163.com

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The Stereocomplex Formation and Phase Separation of PLLA/PDLA Blends with Different Optical Purities and Molecular Weights

English

The Stereocomplex Formation and Phase Separation of PLLA/PDLA Blends with Different Optical Purities and Molecular Weights

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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