The Effect of Particle Shape on the Structure and Rheological Properties of Carbon-based Particle Suspensions

Citation: Ran Niu, Jiang Gong, Dong-hua Xu, Tao Tang, Zhao-yan Sun. The Effect of Particle Shape on the Structure and Rheological Properties of Carbon-based Particle Suspensions[J]. Chinese Journal of Polymer Science, 2015, 33(11): 1550-1561. doi: 10.1007/s10118-015-1704-1 shu

The Effect of Particle Shape on the Structure and Rheological Properties of Carbon-based Particle Suspensions

1.
1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
2.
2. University of Chinese Academy of Sciences, Beijing 100049, China
3.
4.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21474111, 21222407 and 21274152) and subsidized by the National Basic Research Program of China (973 Program, 2012CB821500).

摘要: The structure and rheological properties of carbon-based particle suspensions, i.e., carbon black (CB), multi-wall carbon nanotube (MWNT), graphene and hollow carbon sphere (HCS) suspended in polydimethylsiloxane (PDMS), are investigated. In order to study the effect of particle shape on the structure and rheological properties of suspensions, the content of surface oxygen-containing functional groups of carbon-based particles is controlled to be similar. Original spherical-like CB (fractal filler), rod-like MWNT and sheet-like graphene form large agglomerates in PDMS, while spherical HCS particles disperse relatively well in PDMS. The dispersion state of carbon-based particles affects the critical concentration of forming a rheological percolation network. Under weak shear, negative normal stress differences (N) are observed in CB, MWNT and graphene suspensions, while N is nearly zero for HCS suspensions. It is concluded that the vorticity alignment of CB, MWNT and graphene agglomerates under shear results in the negative N. However, no obvious structural change is observed in HCS suspension under weak shear, and accordingly, the N is almost zero.

关键词:

English

The Effect of Particle Shape on the Structure and Rheological Properties of Carbon-based Particle Suspensions

1.
1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
2.
2. University of Chinese Academy of Sciences, Beijing 100049, China
3.
4.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Received Date: 09 April 2015
Revised Date: 22 May 2015
Available Online: 05 November 2015
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21474111, 21222407 and 21274152) and subsidized by the National Basic Research Program of China (973 Program, 2012CB821500).

Abstract: The structure and rheological properties of carbon-based particle suspensions, i.e., carbon black (CB), multi-wall carbon nanotube (MWNT), graphene and hollow carbon sphere (HCS) suspended in polydimethylsiloxane (PDMS), are investigated. In order to study the effect of particle shape on the structure and rheological properties of suspensions, the content of surface oxygen-containing functional groups of carbon-based particles is controlled to be similar. Original spherical-like CB (fractal filler), rod-like MWNT and sheet-like graphene form large agglomerates in PDMS, while spherical HCS particles disperse relatively well in PDMS. The dispersion state of carbon-based particles affects the critical concentration of forming a rheological percolation network. Under weak shear, negative normal stress differences (N) are observed in CB, MWNT and graphene suspensions, while N is nearly zero for HCS suspensions. It is concluded that the vorticity alignment of CB, MWNT and graphene agglomerates under shear results in the negative N. However, no obvious structural change is observed in HCS suspension under weak shear, and accordingly, the N is almost zero.

Key words:

1. [1]
  Baughman, R.H., Zakhidov, A.A. and de Heer, W.A., Science, 2002, 297: 787
2. [2]
  Harris, P.J.F., Int. Mater. Rev., 2004, 49: 31
3. [3]
  Kim, H., Miura, Y. and Macosko, C.W., Chem. Mater., 2010, 22: 3441
4. [4]
  Lee, S.H., Cho, E., Jeon, S.H. and Youn, J.R., Carbon, 2007, 45: 2810
5. [5]
  Niu, R., Gong, J., Xu, D.H., Tang, T. and Sun, Z.Y., RSC Adv., 2014, 4: 62759
6. [6]
  Wu, D., Wu, L., Zhou, W.D., Sun, Y.R. and Zhang, M., J. Polym. Sci., Part B: Polym. Phys., 2010, 48: 479
7. [7]
  Ye, L., Xie, Y., Qiu, D., Kan, Y. and Zhang, Z.D., Chinese J. Polym. Sci., 2014, 32(11): 1515
8. [8]
  Kasaliwal, G.R., Gldel, A., Ptschke, P. and Heinrich, G., Polymer, 2011, 52: 1027
9. [9]
  Niu, R., Gong, J., Xu, D.H., Tang, T. and Sun, Z.Y., Polymer, 2014, 55: 5445
10. [10]
  Hobbie, E.K. and Fry, D.J., Phys. Rev. Lett., 2006, 97: 036101
11. [11]
  Tan, H.Y., Xu, D.H., Wan, D., Wang, Y., Wang, L., Zheng, J., Liu, F., Ma, L. and Tang, T., Soft Matter, 2013, 9: 6282
12. [12]
  Tan, Y.Q., Song, Y.H. and Zheng, Q., Nanoscale, 2012, 4: 6997
13. [13]
  Sha, X.F., Yu, K.J., Cao, H.J. and Qian, K., J. Nanopart. Res., 2013, 15: 1816
14. [14]
  Jun, S.I. and Lee, H.S., Appl. Phys. Lett., 2012, 100: 164108
15. [15]
  Lin-Gibson, S., Pathak, J.A., Grulke, E.A., Wang, H. and Hobbie, E.K., Phys. Rev. Lett., 2004, 92: 048302
16. [16]
  Niu, R., Gong, J., Xu, D.H., Tang, T. and Sun, Z.Y., Colloid Surface A, 2014, 444: 120
17. [17]
  Osujia, C.O. and Weitz, D.A., Soft Matter, 2008, 4: 1388
18. [18]
  Gong, J., Liu, J., Chen, X.C., Wen, X., Jiang, Z.W., Mijowska, E., Wang, Y.H. and Tang, T., Micropor. Mesopor. Mater., 2013, 176: 31
19. [19]
  Kharchenko, S.B., Douglas, J.F., Obrzut, J., Grulke, E.A. and Migler, K.B., Nat. Mater., 2004, 3: 564
20. [20]
  Rieker, T.P., Hindermann-Bischoff, M. and Ehrburger-Dolle, F., Langmuir, 2000, 16: 5588
21. [21]
  Keefer, K.D. and Schaefer, D.W., Phys. Rev. Lett., 1986, 56: 2376
22. [22]
  Koga, T., Takenaka, M., Aizawa, K., Nakamura, M. and Hashimoto, T., Langmuir, 2005, 21: 11409
23. [23]
  Koga, T., Hashimoto, T., Takenaka, M., Aizawa, K., Amino, N., Nakamura, M., Yamaguchi, D. and Koizumi, S., Macromolecules, 2008, 41: 453
24. [24]
  Briggs, D. and Beamson, G., High resolution XPS of organic polymers: The Scienta ESCA300 Database John Wiley Sons Inc, New York, 1992
25. [25]
  Szab, T., Berkesi, O., Forg, P., Josepovits, K., Sanakis, Y., Petridis, D. and Dkny, I., Chem. Mater., 2006, 18: 2740
26. [26]
  Hernandez, R., Weksler, J., Padsalgikar, A. and Runt, J., Macromolecules, 2007, 40: 5441
27. [27]
  Faiella, G., Piscitelli, F., Lavorgna, M., Antonucci, V. and Giordano, M., Appl. Phys. Lett., 2009, 95: 153106
28. [28]
  Schaefer, D.W. and Keefer, K.D., Phys. Rev. Lett., 1986, 19: 2199
29. [29]
  Jawhari, T., Roid, A. and Casado, J., Carbon, 1995, 33: 1561
30. [30]
  Sun, C.H., Li, F., Ying, Z., Liu, C. and Cheng, H.M., Phys. Rev. B, 2004, 69: 033404
31. [31]
  Saunders, J.M., Goodwin, J.W., Richardson, R.M. and Vincent, B., J. Phys. Chem. B, 1999, 103: 9211
32. [32]
  Baskaran, D., Mays, J.W. and Bratcher, M.S., Chem. Mater., 2005, 17: 3389
33. [33]
  Rahatekar, S.S., Koziol, K.K., Kline, S.R., Hobbie, E.K., Gilman, J.W. and Windle, A.H., Adv. Mater., 2009, 21: 874
34. [34]
  Szab?, T., Berkesi, O., Forg?, P., Josepovits, K., Sanakis, Y., Petridis, D. and Dkny, I., Chem. Mater., 2006, 18: 2740
35. [35]
  Donnet, J.B. and Vidal, A., Adv. Polym. Sci., 1986, 76: 103
36. [36]
  Li, Y., Krger, M. and Liu, K.W., Macromolecules, 2012, 45: 2099
37. [37]
  Hobbie, E.K., Ihle, T., Harris, J.M. and Semler, M.R., Phys. Rev. B, 2012, 85: 245439
38. [38]
  Smith, E.R., Mitchell, D.J. and Ninham, B.W., J. Colloid Interf. Sci., 1973, 45: 55
39. [39]
  Hough, L.A., Islam, M.F., Janmey, P.A. and Yodh, A.G., Phys. Rev. Lett., 2004, 93: 168102
40. [40]
  Beigbeder, A., Linares, M., Devalckenaere, M., Dege, P., Claes, M., Beljonne, D., Lazzaroni, R. and Dubois, P., Adv. Mater., 2008, 20: 1003
41. [41]
  Suezawa, H., Yoshida, T., Ishihara, S., Umezawa, Y. and Nishio, M., Cryst. Eng. Comm., 2003, 5: 514
42. [42]
  Nishinari, K., Prog. Colloid Polym. Sci., 2009, 136: 87
43. [43]
  Paleo, A.J., Silva, J., van Hattum, F.W.J.; Lanceros-Mndez, S. and Ares, A.I., J. Polym. Sci., Part B: Polym. Phys., 2013, 51: 207
44. [44]
  de Gennes, P.G., Scaling concepts in polymer physics Cornell University Press, New York, 1979, p. 105
45. [45]
  Sahimi, M. and Arbabi, S., Phys. Rev. B, 1993, 47: 703
46. [46]
  Loiseau, A. and Tassin, J.F., Macromolecules, 2006, 39: 9185
47. [47]
  Guimont, A., Beyou, E., Martin, G., Sonntag, P. and Cassagnau, P., Macromolecules, 2011, 44: 3893
48. [48]
  Trappe, V., Prasad, V., Cipelletti, L., Segre, P.N. and Weitz, D.A., Nature, 2001, 411: 772
49. [49]
  Knauert, S.T., Douglas, J.F. and Starr, F.W., J. Polym. Sci., Part B: Polym. Phys., 2007, 45: 1882
50. [50]
  Wagner, N.J. and Brady, J.F., Phys. Today, 2009, 62: 27
51. [51]
  Brown, E., Forman, N.A., Orellana, C.S., Zhang, H.J., Maynor, B.W., Betts, D.E., DeSimone, J.M. and Jaeger, H.M., Nat. Mater., 2010, 9: 220
52. [52]
  Youssry, M., Madec, L., Soudan, P., Cerbelaud, M., Guyomard, D. and Lestriez, B., Phys. Chem. Chem. Phys., 2013, 15: 14476
53. [53]
  Yokozeki, T., Schulz, S.C., Buschhorn, S.T. and Schulte, K., Eur. Polym. J., 2012, 48: 1042
54. [54]
  Yang, J.J., Zhang, Y.Q., Wang, Z.G. and Chen, P., RSC Adv., 2014, 4: 1246
55. [55]
  Xu, D.H., Wang, Z.G. and Douglas, J.F., Macromolecules, 2008, 41: 815
56. [56]
  Li, Y., Nie, Y.J., Ma, Y. and Hu, W.B., Chinese J. Polym. Sci., 2013, 31(11): 1590

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The Effect of Particle Shape on the Structure and Rheological Properties of Carbon-based Particle Suspensions

English

The Effect of Particle Shape on the Structure and Rheological Properties of Carbon-based Particle Suspensions

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

The Effect of Particle Shape on the Structure and Rheological Properties of Carbon-based Particle Suspensions

English

The Effect of Particle Shape on the Structure and Rheological Properties of Carbon-based Particle Suspensions

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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