Poly(N,N-dimethylaminoethyl methacrylate) Grafted Poly(vinyl chloride)s Synthesized via ATRP Process and Their Membranes for Dye Separation

Citation: Li-feng Fang, Na-chuan Wang, Ming-yong Zhou, Bao-ku Zhu, Li-ping Zhu, Angelin Ebanezar John. Poly(N,N-dimethylaminoethyl methacrylate) Grafted Poly(vinyl chloride)s Synthesized via ATRP Process and Their Membranes for Dye Separation[J]. Chinese Journal of Polymer Science, 2015, 33(11): 1491-1502. doi: 10.1007/s10118-015-1701-4 shu

Poly(N,N-dimethylaminoethyl methacrylate) Grafted Poly(vinyl chloride)s Synthesized via ATRP Process and Their Membranes for Dye Separation

1.
Key Laboratory of Macromolecular Synthesis and Functionalization (Ministry of Education), Engineering Research Center of Membrane and Water Treatment (Ministry of Education), Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

通讯作者: Bao-ku Zhu, ms630@zju.edu.cn

基金项目:
This work was financially supported by the National 863 Program (No. 2012AA03A602), National 973 Program (No. 2009CB623402) and the National Natural Science Foundation of China (No. U1134002).

摘要: To functionalize poly(vinyl chloride) (PVC) for various applications, monomers containing tertiary amine group are incorporated into PVC via atom transfer radical polymerization (ATRP) initiated by the labile chlorines in their backbones. The kinetics of synthesis was carefully investigated, and it is proven that the grafting polymerization process can be effectively controlled by regulating the reaction time. The membranes are fabricated using PVC and copolymers by non-solvent induced phase separation (NIPS) process. The hydrophilicity and pore structure of copolymer membranes were enhanced as well, these membranes are endowed with positive charge. When PDMA% (i.e., the PDMA weight percentage in copolymer) is 31.1%, the flux and Victoria blue B rejection are 26.0 Lm-2h-1 (0.5 MPa) and 91.2%, respectively. Thus, the newly synthesized polymer is proven to be a promising material for dye separation with positive charges.

关键词:

Poly(vinyl chloride)
/ Poly(N,N-dimethylaminoethyl methacrylate)
/ Non-solvent induced phase separation
/ Dye separatio

English

Poly(N,N-dimethylaminoethyl methacrylate) Grafted Poly(vinyl chloride)s Synthesized via ATRP Process and Their Membranes for Dye Separation

1.
Key Laboratory of Macromolecular Synthesis and Functionalization (Ministry of Education), Engineering Research Center of Membrane and Water Treatment (Ministry of Education), Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Bao-ku Zhu, ms630@zju.edu.cn

Received Date: 24 March 2015
Revised Date: 17 April 2015
Available Online: 05 November 2015
Fund Project:
This work was financially supported by the National 863 Program (No. 2012AA03A602), National 973 Program (No. 2009CB623402) and the National Natural Science Foundation of China (No. U1134002).

Abstract: To functionalize poly(vinyl chloride) (PVC) for various applications, monomers containing tertiary amine group are incorporated into PVC via atom transfer radical polymerization (ATRP) initiated by the labile chlorines in their backbones. The kinetics of synthesis was carefully investigated, and it is proven that the grafting polymerization process can be effectively controlled by regulating the reaction time. The membranes are fabricated using PVC and copolymers by non-solvent induced phase separation (NIPS) process. The hydrophilicity and pore structure of copolymer membranes were enhanced as well, these membranes are endowed with positive charge. When PDMA% (i.e., the PDMA weight percentage in copolymer) is 31.1%, the flux and Victoria blue B rejection are 26.0 Lm-2h-1 (0.5 MPa) and 91.2%, respectively. Thus, the newly synthesized polymer is proven to be a promising material for dye separation with positive charges.

Key words:

Poly(vinyl chloride)
/ Poly(N,N-dimethylaminoethyl methacrylate)
/ Non-solvent induced phase separation
/ Dye separatio

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Poly(N,N-dimethylaminoethyl methacrylate) Grafted Poly(vinyl chloride)s Synthesized via ATRP Process and Their Membranes for Dye Separation

通讯作者: Bao-ku Zhu, ms630@zju.edu.cn

English

Poly(N,N-dimethylaminoethyl methacrylate) Grafted Poly(vinyl chloride)s Synthesized via ATRP Process and Their Membranes for Dye Separation

Corresponding author: Bao-ku Zhu, ms630@zju.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Poly(N,N-dimethylaminoethyl methacrylate) Grafted Poly(vinyl chloride)s Synthesized via ATRP Process and Their Membranes for Dye Separation

通讯作者: Bao-ku Zhu, ms630@zju.edu.cn

English

Poly(N,N-dimethylaminoethyl methacrylate) Grafted Poly(vinyl chloride)s Synthesized via ATRP Process and Their Membranes for Dye Separation

Corresponding author: Bao-ku Zhu, ms630@zju.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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