Synthesis and Characterization of Bio-based Epoxy Blends from Renewable Resource Based Epoxidized Soybean Oil as Reactive Diluent

Sushanta K Sahoo Smita Mohanty Sanjay K Nayak

Citation:  Sushanta K Sahoo, Smita Mohanty, Sanjay K Nayak. Synthesis and Characterization of Bio-based Epoxy Blends from Renewable Resource Based Epoxidized Soybean Oil as Reactive Diluent[J]. Chinese Journal of Polymer Science, 2015, 33(1): 137-152. doi: 10.1007/s10118-015-1568-4 shu

Synthesis and Characterization of Bio-based Epoxy Blends from Renewable Resource Based Epoxidized Soybean Oil as Reactive Diluent

    通讯作者: Smita Mohanty, papers.journal@gmail.com
  • 基金项目:

    This work was financially supported by the Department of Chemicals and Petrochemicals, Govt. of India

摘要: A novel bioresin, epoxidized soybean oil was synthesized by in situ method and was characterized employing FTIR and NMR. The bioresin was blended with epoxy (DGEBA) at different ratios as reactive diluents for improved processibility and toughened nature. The composition with 20 wt% bioresin exhibited improved impact strength to the tune of 60% as compared to virgin epoxy. Fracture toughness parameters critical stress intensity factor (KIC) and critical strain energy release rate (GIC) were evaluated using single edge notch bending test and demonstrated superior enhancement in toughness. Dynamic mechanical, thermal, thermo mechanical and fracture morphological analyses have been studied for bio-based epoxy blends. Curing kinetics has been evaluated through DSC analysis to investigate the effect of bioresin on cross-linking reaction of neat epoxy with triethylenetetramine as curing agent.

English

  • 
    1. [1]

      Meier, M.A.R., Metzger, J.O. and Schubert, U.S., Chem. Soc. Rev., 2007, 36: 1788

    2. [2]

      Mallick, P.K. Fiber reinforced composites; Materials, Manufacturing and Design Taylor Francis, New York, 2007, p. 2

    3. [3]

      Tan, S.G. and Chow, W.S., Polymer-Plastics Tech and Eng., 2010, 49: 900

    4. [4]

      Delglise, J.M.M., Lacrampe, M.F. and Krawczak, P., Prog. Polym. Sci., 2010, 35: 487

    5. [5]

      Espinosa, L.M. de and Meier, M.A.R., Eur. Polym. J., 2011, 47: 837

    6. [6]

      Guner, F.S., Yagci, Y. and Erciyes, A.T., Prog. Polym. Sci., 2006, 31: 633

    7. [7]

      Gerbase, A.E., Petzhold, C.L. and Costa, A.P.O., J. Am. Oil Chem. Soc., 2002, 79 :797

    8. [8]

      Jin, F.L. and Park, S.J., J. Ind. Eng. Chem., 2007, 13: 808

    9. [9]

      Park, S.J., Jin, F.L. and Lee, J.R., Macromol. Rapid Commun., 2004, 25: 109

    10. [10]

      Liu, Z. and Erhan, S.Z., J. Am. Oil Chem. Soc., 2010, 87: 437

    11. [11]

      Kim, J.R. and Sharma, S., Ind. Crop. Prod., 2012, 36: 485

    12. [12]

      Parzuchowski, P.G., Kowalska, M.J., Ryszkowska, J. and Rokicki, G., J. Appl. Polym. Sci., 2006, 102: 2904

    13. [13]

      Ratna, D. and Banthia, A.K., Macromol. Research, 2004, 12: 11

    14. [14]

      Unnikrishnan, K.P. and Thachi, E.T., Des. Monomers Polym., 2006, 9: 129

    15. [15]

      Chen, W.Y., Wang, Y.Z. and Chang, F.C., J. Appl. Polym. Sci., 2004, 92: 892

    16. [16]

      Ahmad, Z., Ansell, M. and Smedley, D., Int. J. Adhesion Adhesives, 2010, 30: 539

    17. [17]

      Raghavachar, R., Letasi, R.J., Kola, P.V., Chen, Z. and Massingill, J.L., J. Am. Oil Chem. Soc., 1999, 76: 511

    18. [18]

      Ratna, D., Polym. Int., 2001, 50: 179

    19. [19]

      Zhu, J., Chandrashekhara, K., Flanigan, V. and Kapila, S., J. Appl. Polym. Sci., 2004, 91: 3513

    20. [20]

      Miyagawa, H., Misra, M. and Drzal, L.T., Polym. Eng. Sci., 2005, 45: 487

    21. [21]

      Park, S.J., Jin, F.L. and Lee, J.R., Mater. Sci. Eng. A., 2004, 374: 724

    22. [22]

      Shabeer, A., Garg, A., Sundararaman, S., Chandrashekhara, K., Flanigan, V. and Kapila, S., J. Appl. Polym. Sci., 2005, 98: 1772

    23. [23]

      Jin, F.L. and Park, S.J., Mater. Sci. Eng. A., 2008, 478: 402

    24. [24]

      Jin, F.L. and Park, S.J., Polym. Int., 2008, 57: 577

    25. [25]

      Lu, J. and Wool, R.P., Compos. Sci. Tech., 2008, 68: 1025

    26. [26]

      Mustata, F., Tudorachi, N. and Rosu, D., Composite Part B, 2011, 42: 1803

    27. [27]

      Altuna, F.I., Esposito, L.H., Ruseckaite, R.A. and Stefani, P.M., J. Appl. Polym. Sci., 2011, 120: 789

    28. [28]

      Gupta, A.P., Ahmad, S. and Dev, A., Polym. Eng. Sci., 2011, 51: 1087

    29. [29]

      Tan, S.G., Chow, W.S., J. Therm. Anal. Calorim., 2010, 101: 1051

    30. [30]

      Miyagawa, H., Misra, M., Drzal, L.T. and Mohanty, A.K., Polymer, 2005, 46: 445

    31. [31]

      Grishchuk, S. and Kargor-Kocsis, J.J., Mater. Sci., 2012, 47: 3391

    32. [32]

      Gedde, U.W., Polymer Physics Kluwer Academic Publishers, The Netherlands, 2001, p. 62

    33. [33]

      Barcia, F.L., Amaral, T.P. and Soares, B.G., Polymer, 2003, 44: 811

    34. [34]

      Thomas, R., Yumei, D., Yuelong, H., Le, Y., Moldenaers, P., Weimin, Y., Czigany, T. and Thomas, S., Polymer, 2008, 49: 278

    35. [35]

      Rico, M., Lpez, J., Montero, B. and Bellas, R., Eur. Polym. J., 2012, 48: 1660

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  • 发布日期:  2015-01-05
  • 收稿日期:  2014-05-13
  • 修回日期:  2014-08-15
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