SYNTHESIS AND CHARACTERIZATION OF A NOVEL MACROMOLECULAR SURFACE MODIFIER FOR POLYETHYLENE

Min-min Zhang Si-wei Liu Yi Zhang Liang-hui Chen Zhen-guo Chi Jia-rui Xu

Citation:  Min-min Zhang, Si-wei Liu, Yi Zhang, Liang-hui Chen, Zhen-guo Chi, Jia-rui Xu. SYNTHESIS AND CHARACTERIZATION OF A NOVEL MACROMOLECULAR SURFACE MODIFIER FOR POLYETHYLENE[J]. Chinese Journal of Polymer Science, 2013, 31(6): 894-900. doi: 10.1007/s10118-013-1277-9 shu

SYNTHESIS AND CHARACTERIZATION OF A NOVEL MACROMOLECULAR SURFACE MODIFIER FOR POLYETHYLENE

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (Nos. 51173214, J1103305), Department of Education of Guangdong Province (2012KJCX0005), and Science and Technology Bureau of Guangzhou.

摘要: A new macromolecular surface modifier, a copolymer of lauryl methacrylate (LMA) and poly(ethylene glycol) methyl methacrylate (PEGMA), was synthesized through free radical polymerization. The copolymer was characterized by nuclear magnetic resonance spectrum (1H-NMR) and thermogravimetric analysis (TGA). The copolymer was used to blend with polyethylene. The binary blends have been characterized by attenuated total reflection/Fourier transform infrared (ATR-FTIR), contact-angle measurements (CDA) and scanning electron microscopy (SEM). The results indicated that poly(ethylene glycol) methyl methacrylate-co-lauryl methacrylate (PEGMA-co-LMA) could diffuse preferably onto the surface of the polyethylene (PE) film, and thus can be used as an efficient surface modifier for PE.

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    1. [1]

      Bergbreiter, D.E., Walchuk, B., Holtzman, B. and Gray, H.N., Macromolecules, 1998, 31: 3417[2]Fu, Z.S., Liu, M., Xu, J.T., Wang, Q. and Fan, Z.Q., J. Appl. Polym. Sci., 2011, 119: 1111[3]Zhao, G.W., Chen, Y[J].S. and Wang, X.L., Appl. Surf. Sci.2007, 253:4709-[4]Hardman, S.J., Hutchings, L.R., Clarke, N., Kimani, S.M., Mears, L.L.E., Smith, E.F., Webster J.R.P. and Thompson, R.L., Langmuir, 2012, 28: 5125[5]Severini, F., Landro, L.D, Galfetti, L., Meda, L., Ricca, G. and Zenere, G., Macromol. Symp., 2002, 181: 225[6]Song, J., Gunst, U[J]., Arlinghaus, H.F. and Vancso, G.J., Appl. Surf. Sci.2007, 253:9489-[7]Bandopadhay, D., Tarafdar,A[J]., Panda, A.B. and Pramanik, P., J. Appl. Polym. Sci.2004, 92:3046-[8]Kavc, T. and Kern, W[J]., Chem. Mater.2000, 12:1053-[9]iseth, S.K., Krozer, A[J]., Kasemo, B. and Lausmaa, J., Appl. Surf. Sci.2002, 202:92-[10]Deshmukh, R.R. and Shetty, A[J].R., J. Appl. Polym. Sci.2007, 106:4075-[11]Král, M., Ogino, A[J].and Nagatsu, M., J. Phys. D: Appl. Phys.2008,41:105213-[12]Wang, T., Wang, C[J].and Qiu, Y., J. Appl. Polym. Sci.2008, 108:25-[13]Wang, K., Li, J., Ren, C.S., Wang, D.Z. and Wang, Y.N., Plasma Sci. Technol., 2008, 10: 433[14]Píchal, J., Hladík, J[J].and ?patenka, P., Plasma Process. Polym.2009, 6:148-[15]Uyama,Y., Kato, K[J].and Ikada, Y., Adv. Polym. Sci.1998, 137:1-[16]Zhao, J.Q. and Geuskens, G[J]., Eur. Polym. J.1999, 35:2115-[17]Chen, Y.S. and Liu, P[J]., J. Appl. Polym. Sci.2004, 93:2014-[18]Ranby, B., Polym. Eng. Sci., 1998, 38: 1229[19]Bergbreiter, D.E., Prog. Polym. Sci., 1994, 19: 529[20]Ma, D.L., Hugener, T.A., Siegel, R.W., Christerson, A., M?rtensson, E., ?nneby, C. and Schadler, L.S., Nanotechnology, 2005, 16: 724[21]Puukilainen, E. and Pakkanen, T[J].A., J. Polym. Sci. Part B: Polym. Phys.2005, 43:2252-[22]Chen, H.J., Zhu, Y[J].F., Zhang, Y. and Xu, J.R., J. Appl. Polym. Sci.2006, 102:3413-[23]Datta, V.M., Shim, E[J].and Pourdeyhimi, B., J. Appl. Polym. Sci.2011, 121:1335-[24]Bergberiter, D.E. and Stinivas, B[J]., Macromolecules.1992, 25:636-[25]Lee. H. and Archer, L.A., Polymer, 2002, 43: 272[26]Bergbreiter, D.E., Hu, H.P. and Hein, M.D., Macromolecules, 1989, 22:54[27]Hallden, A. and Wessle, B[J]., J. Appl. Polym. Sci.2000, 75:316-3.0.CO;2-M' target='_blank'>[28]Zhou, X., Zhu, Y.F. and Xu, J.R., J. Funct. Polym., 2003, 16: 347[29]Qian, H., Zhou, X. and Xu, J.R., J. Funct. Polym., 2003, 16: 184[30]Chen, G.F., Zhang, Y[J]., Zhou, X. and Xu, J.R., J. Appl. Surf. Sci.2006, 253:1107-[31]Chen, H.J., Shi, X.H., Zhu, Y.F., Zhang, Y. and Xu, J.R., J. Appl. Polym. Sci., 2008, 107: 3049[32]Chen, H.J., Zhu, Y.F., Zhang, Y. and Xu, J.R., J. Polym. Res., 2007, 14: 489[33]Chen, H.J., Shi, X.H., Zhu, Y.F., Zhang, Y. and Xu, J.R., J. Vinyl. Addit. Techn., 2008, 14: 28[34]Chen, H.J., Shi, X.H., Zhu, Y.F., Zhang, Y. and Xu, J.R., J. Appl. Polym. Sci., 2009, 114: 2461[35]Schmidt, J.J., Gardella, J.A. Jr. and Salvati, L. Jr., Macromolecules, 1989, 22: 4489

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  • 发布日期:  2013-06-05
  • 收稿日期:  2013-01-04
  • 修回日期:  2013-01-30
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