SYNCHROTRON INVESTIGATION ON MESOMORPHIC STRUCTURE OF sPP AND POLY(ETHYLENE-CO-OCTENE) IN THEIR INITIAL CRYSTALLIZATION STAGE

Rong Cheng Hui-ying Wen Hong-fei Li Shi-chun Jiang Li-jia An Zhong-hua Wu

Citation:  Rong Cheng, Hui-ying Wen, Hong-fei Li, Shi-chun Jiang, Li-jia An, Zhong-hua Wu. SYNCHROTRON INVESTIGATION ON MESOMORPHIC STRUCTURE OF sPP AND POLY(ETHYLENE-CO-OCTENE) IN THEIR INITIAL CRYSTALLIZATION STAGE[J]. Chinese Journal of Polymer Science, 2010, 28(5): 745-751. doi: 10.1007/s10118-010-9130-x shu

SYNCHROTRON INVESTIGATION ON MESOMORPHIC STRUCTURE OF sPP AND POLY(ETHYLENE-CO-OCTENE) IN THEIR INITIAL CRYSTALLIZATION STAGE

摘要: Using synchrotron SAXS and WAXS, we investigated crystalline structures including crystallite size, lamellar thickness, long spacing of syndiotactic polypropylene (sPP) and poly(ethylene-co-octene) (PEcO) that crystallized from the sheared melt. The independence of the shear effects on the crystalline structures and the shear related lamellar orientation indicate the stable mesophase. Experiments on the different shear effects on polymer various crystalline structures confirm the multi-step polymer crystallization process.

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  • 发布日期:  2010-09-20
  • 收稿日期:  2009-09-02
  • 修回日期:  2009-12-02
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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