The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core

Rui Fang GUAN Chuan Jian ZHOU Sheng Yu FENG David J. BERG Stephen R. STOBART

引用本文: Rui Fang GUAN,  Chuan Jian ZHOU,  Sheng Yu FENG,  David J. BERG,  Stephen R. STOBART. The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core[J]. Chinese Chemical Letters, 2006, 17(3): 293-295. shu
Citation:  Rui Fang GUAN,  Chuan Jian ZHOU,  Sheng Yu FENG,  David J. BERG,  Stephen R. STOBART. The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core[J]. Chinese Chemical Letters, 2006, 17(3): 293-295. shu

The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core

  • 基金项目:

    The Project Sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (2005-55).

摘要: Carbosilane dendrimers with p-bromophenyl core were synthesized by alternating Grignard and hydrosilylation reaction. And the α-naphthalenyl was connected to the core by the Suzuki coupling reaction. A new carbosilane dendrimer with big π-conjugated structure[4-(naphthalen-1-yl)phenyl core] was given. It shows Suzuki coupling reaction is an effective and powerful core-functionalization method and the satisfactory result can be obtained through prolonging the reaction time with the increase of the generation of dendrimer.

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  • 收稿日期:  2005-06-24
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