引用本文:
Jing Lin CHEN, Li Yi ZHANG, Zhong Ning CHEN. A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units[J]. Chinese Chemical Letters,
2005, 16(3): 372-374.
Citation: Jing Lin CHEN, Li Yi ZHANG, Zhong Ning CHEN. A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units[J]. Chinese Chemical Letters, 2005, 16(3): 372-374.

Citation: Jing Lin CHEN, Li Yi ZHANG, Zhong Ning CHEN. A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units[J]. Chinese Chemical Letters, 2005, 16(3): 372-374.

A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units
摘要:
A novel dimeric complex[Ru3Ⅲ,Ⅲ,Ⅱ(μ3-O)(μ-CH3COO) (CO)]2 (μ-dppf)(μ-odppf) (dppf=1, l'-bis(diphenylphosphio) ferrocene, odppf=1, 1'-bis(oxodiphenylphosphoranyl)ferrocene) (1) of oxo-centered triruthenium-aectate cluster units was synthesized and characterized by X-ray crystallography. Compound 1 exhibits a cyclic structure formed by linkages of two triruthenium cluster units Ru3Ⅲ,Ⅲ, Ⅱ (μ3-O)(μ-CH3COO)6(CO) through dppf and odppf ligands, respectively. The diameter of the molecular loop is ca. 1.0 nm.
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关键词:
- Carboxylate
- / crystal structure
- / diphosphine
- / ruthenium
- / cluster complex.
English
A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units
Abstract:
A novel dimeric complex[Ru3Ⅲ,Ⅲ,Ⅱ(μ3-O)(μ-CH3COO) (CO)]2 (μ-dppf)(μ-odppf) (dppf=1, l'-bis(diphenylphosphio) ferrocene, odppf=1, 1'-bis(oxodiphenylphosphoranyl)ferrocene) (1) of oxo-centered triruthenium-aectate cluster units was synthesized and characterized by X-ray crystallography. Compound 1 exhibits a cyclic structure formed by linkages of two triruthenium cluster units Ru3Ⅲ,Ⅲ, Ⅱ (μ3-O)(μ-CH3COO)6(CO) through dppf and odppf ligands, respectively. The diameter of the molecular loop is ca. 1.0 nm.
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Key words:
- Carboxylate
- / crystal structure
- / diphosphine
- / ruthenium
- / cluster complex.

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