引用本文:
Hua YANG, Yong Qiang WANG, Wei Dong Z. LI. Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine[J]. Chinese Chemical Letters,
2005, 16(3): 311-314.
Citation: Hua YANG, Yong Qiang WANG, Wei Dong Z. LI. Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine[J]. Chinese Chemical Letters, 2005, 16(3): 311-314.

Citation: Hua YANG, Yong Qiang WANG, Wei Dong Z. LI. Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine[J]. Chinese Chemical Letters, 2005, 16(3): 311-314.

Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine
摘要:
Methylenedioxyphenyl unit displays a significant stereoelectronic effect in some key transformations in the total synthesis of cephalotaxine. The ring-strain of methylenedioxy ring may account for some important facile ring-skeleton rearrangements.
English
Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine
Abstract:
Methylenedioxyphenyl unit displays a significant stereoelectronic effect in some key transformations in the total synthesis of cephalotaxine. The ring-strain of methylenedioxy ring may account for some important facile ring-skeleton rearrangements.
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Key words:
- Stereoelectronic effect
- / reductive rearrangement
- / cephalotaxine
- / total synthesis.

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