Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine

Hua YANG Yong Qiang WANG Wei Dong Z. LI

引用本文: Hua YANG,  Yong Qiang WANG,  Wei Dong Z. LI. Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine[J]. Chinese Chemical Letters, 2005, 16(3): 311-314. shu
Citation:  Hua YANG,  Yong Qiang WANG,  Wei Dong Z. LI. Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine[J]. Chinese Chemical Letters, 2005, 16(3): 311-314. shu

Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation (Distinguished Youth Fund 29925204), Fok Ying Tung Education Foundaiton (Fund 71012). The Cheung Kong Scholars Program is gratefully acknowledged.

摘要: Methylenedioxyphenyl unit displays a significant stereoelectronic effect in some key transformations in the total synthesis of cephalotaxine. The ring-strain of methylenedioxy ring may account for some important facile ring-skeleton rearrangements.

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  • 收稿日期:  2004-02-09
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