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Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction

Zhi Quan ZHAO ,  Li Zeng PENG ,  Yu Lin LI

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引用本文: Zhi Quan ZHAO,  Li Zeng PENG,  Yu Lin LI. Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction[J]. Chinese Chemical Letters, 2005, 16(3): 290-292. shu
Citation:  Zhi Quan ZHAO,  Li Zeng PENG,  Yu Lin LI. Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction[J]. Chinese Chemical Letters, 2005, 16(3): 290-292. shu

Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction

  • 1.

    Lunan Pharmaceutical Co., Ltd., Linyi, Shandong 276003;

  • 2.

    National Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (Grant No. 20072012).

摘要: The phenomenon of migration of the silyl groups from α-oxygen to β-oxygen in sodium aldol reaction was observed for the first time in this paper.

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  • 收稿日期:  2004-01-16
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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