The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne

引用本文: Jin Sheng CHENG, Jin Heng LI, Huan Feng JIANG, Xiao Yue OUYANGLCLC. The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne[J]. Chinese Chemical Letters, 2003, 14(9): 966-968. shu

Citation: Jin Sheng CHENG, Jin Heng LI, Huan Feng JIANG, Xiao Yue OUYANGLCLC. The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne[J]. Chinese Chemical Letters, 2003, 14(9): 966-968. shu

The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne

1.
LCLC Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650;
2.
State Key Laboratory of Organometallics Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

摘要: The chemoselectivities of PdCl₂ and CuCl₂-catalyzed oligomerization of 3, 3-dimethyl-butyne:1, 3, 5-tri-tert-butylbenzene, 2, 2, 7, 7-tetramethyl-3, 6-dichloro-3, 5-octadiene and 2, 2, 7,7- tetramethyl-3,5-octadiyne were obtained, respectively, by regulating the polarity of the solvent.

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English

The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne

1.
LCLC Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650;
2.
State Key Laboratory of Organometallics Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
Received Date: 27 September 2002

Abstract: The chemoselectivities of PdCl₂ and CuCl₂-catalyzed oligomerization of 3, 3-dimethyl-butyne:1, 3, 5-tri-tert-butylbenzene, 2, 2, 7, 7-tetramethyl-3, 6-dichloro-3, 5-octadiene and 2, 2, 7,7- tetramethyl-3,5-octadiyne were obtained, respectively, by regulating the polarity of the solvent.

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne

English

The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne

English

The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-1-butyne

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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