引用本文:
Fan Zhi KONG, Xiao Lai ZHENG, Zi Lin JIN. Aqueous Biphasic Hydroformylation of Oleyl Alcohol Catalyzed by Thermoregulated Rhodium Complex[J]. Chinese Chemical Letters,
2003, 14(9): 917-919.
Citation: Fan Zhi KONG, Xiao Lai ZHENG, Zi Lin JIN. Aqueous Biphasic Hydroformylation of Oleyl Alcohol Catalyzed by Thermoregulated Rhodium Complex[J]. Chinese Chemical Letters, 2003, 14(9): 917-919.
Citation: Fan Zhi KONG, Xiao Lai ZHENG, Zi Lin JIN. Aqueous Biphasic Hydroformylation of Oleyl Alcohol Catalyzed by Thermoregulated Rhodium Complex[J]. Chinese Chemical Letters, 2003, 14(9): 917-919.
Aqueous Biphasic Hydroformylation of Oleyl Alcohol Catalyzed by Thermoregulated Rhodium Complex
摘要:
The aqueous biphasic hydroformylation of oleyl alcohol was achieved under thermo-regulated phase transfer catalysis (TRPTC) conditions with Rh(acac)(CO)2 Ph2P[p-C6H4(OCH2CH2)25OH] (PETPP) complex catalyst formed in situ.The aldehyde yield reached 81.2% within 6 hrs under 140℃ and 5.0 MPa (CO/H2,1/1) and the separated catalysts dissolved in the aqueous phase could be reused for 3 times without evident changes in activity.
-
关键词:
- Rhodium
- / hydroformylation
- / oleyl alcohol
- / TRPTC
English
Aqueous Biphasic Hydroformylation of Oleyl Alcohol Catalyzed by Thermoregulated Rhodium Complex
Abstract:
The aqueous biphasic hydroformylation of oleyl alcohol was achieved under thermo-regulated phase transfer catalysis (TRPTC) conditions with Rh(acac)(CO)2 Ph2P[p-C6H4(OCH2CH2)25OH] (PETPP) complex catalyst formed in situ.The aldehyde yield reached 81.2% within 6 hrs under 140℃ and 5.0 MPa (CO/H2,1/1) and the separated catalysts dissolved in the aqueous phase could be reused for 3 times without evident changes in activity.
-
Key words:
- Rhodium
- / hydroformylation
- / oleyl alcohol
- / TRPTC
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 0
- HTML全文浏览量: 0
下载:
