引用本文:
Yan LÜ, Lin Hong WENG, Zhi Li LAN, Jing LI, Qing Lan XIE. Synthesis and Structure of Mixed Distannoxane Dimers [ClR2SnOSnR'2Cl]2[J]. Chinese Chemical Letters,
2002, 13(2): 185-188.
Citation: Yan LÜ, Lin Hong WENG, Zhi Li LAN, Jing LI, Qing Lan XIE. Synthesis and Structure of Mixed Distannoxane Dimers [ClR2SnOSnR'2Cl]2[J]. Chinese Chemical Letters, 2002, 13(2): 185-188.
Citation: Yan LÜ, Lin Hong WENG, Zhi Li LAN, Jing LI, Qing Lan XIE. Synthesis and Structure of Mixed Distannoxane Dimers [ClR2SnOSnR'2Cl]2[J]. Chinese Chemical Letters, 2002, 13(2): 185-188.
Synthesis and Structure of Mixed Distannoxane Dimers [ClR2SnOSnR'2Cl]2
摘要:
Mixed distannoxane dimers [ClR2SnOSnR'2Cl]2 were synthesized by the reaction of R2SnO (R=Bu, Pr) and R2SnCl2 (R=Me, Ph, Cy, Oct).The crystal structures of compound 1 and 5 show they are ladder-type dimers that contain a central planar Sn2O2 four-membered ring.Both endo-and exo-Sn atoms are five-coordinate.
English
Synthesis and Structure of Mixed Distannoxane Dimers [ClR2SnOSnR'2Cl]2
Abstract:
Mixed distannoxane dimers [ClR2SnOSnR'2Cl]2 were synthesized by the reaction of R2SnO (R=Bu, Pr) and R2SnCl2 (R=Me, Ph, Cy, Oct).The crystal structures of compound 1 and 5 show they are ladder-type dimers that contain a central planar Sn2O2 four-membered ring.Both endo-and exo-Sn atoms are five-coordinate.
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Key words:
- Asymmetric tetraorganodistannoxane
- / synthesis
- / crystal structure
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