引用本文:
Meng ZHANG, Da Li YIN, Ji Yu GUO, Xiao Tian LIANG. Entry into Major Groups Retaining Taxol via Sinenxan A[J]. Chinese Chemical Letters,
2002, 13(2): 135-138.
Citation: Meng ZHANG, Da Li YIN, Ji Yu GUO, Xiao Tian LIANG. Entry into Major Groups Retaining Taxol via Sinenxan A[J]. Chinese Chemical Letters, 2002, 13(2): 135-138.
Citation: Meng ZHANG, Da Li YIN, Ji Yu GUO, Xiao Tian LIANG. Entry into Major Groups Retaining Taxol via Sinenxan A[J]. Chinese Chemical Letters, 2002, 13(2): 135-138.
Entry into Major Groups Retaining Taxol via Sinenxan A
摘要:
Compound 1 as a key intermediate of 1, 7, 9-trideoxytaxol was synthesized in ten steps from a biosynthetically available taxane, Sinenxan A.The key steps in the synthesis were deoxygenation at C-14, allylic oxidation at C-13 and construction of the oxetane ring.
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关键词:
- Taxol
- / Sinenxan A
- / deoxygenation
English
Entry into Major Groups Retaining Taxol via Sinenxan A
Abstract:
Compound 1 as a key intermediate of 1, 7, 9-trideoxytaxol was synthesized in ten steps from a biosynthetically available taxane, Sinenxan A.The key steps in the synthesis were deoxygenation at C-14, allylic oxidation at C-13 and construction of the oxetane ring.
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Key words:
- Taxol
- / Sinenxan A
- / deoxygenation
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