引用本文:
Zhi Liang SHANG, Zhi Cai SHANG, Cheng Yun WANG, Qing Sen YU. Synthesis of a New Chiral Ligand Containing 1, 5-Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde[J]. Chinese Chemical Letters,
2002, 13(2): 115-116.
Citation: Zhi Liang SHANG, Zhi Cai SHANG, Cheng Yun WANG, Qing Sen YU. Synthesis of a New Chiral Ligand Containing 1, 5-Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde[J]. Chinese Chemical Letters, 2002, 13(2): 115-116.
Citation: Zhi Liang SHANG, Zhi Cai SHANG, Cheng Yun WANG, Qing Sen YU. Synthesis of a New Chiral Ligand Containing 1, 5-Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde[J]. Chinese Chemical Letters, 2002, 13(2): 115-116.
Synthesis of a New Chiral Ligand Containing 1, 5-Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde
摘要:
A new chiral tetradentate ligand (S, S)-1, 5-bis (4-benzyloxazolin-2-yl-methyl)-1, 5-diazacyclo-octane 1 has been synthesized and the application of 1 as catalyst in the enantioselective addition of diethyl zinc to benzaldehyde is also described.
English
Synthesis of a New Chiral Ligand Containing 1, 5-Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde
Abstract:
A new chiral tetradentate ligand (S, S)-1, 5-bis (4-benzyloxazolin-2-yl-methyl)-1, 5-diazacyclo-octane 1 has been synthesized and the application of 1 as catalyst in the enantioselective addition of diethyl zinc to benzaldehyde is also described.
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Key words:
- Chiral oxazoline
- / 1,5-diazacyclooctane
- / enantioselective addition
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