Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over An Ultrafine Co-B Amorphous Catalyst

Xing Fan CHEN He Xing LI Ye Ping XU Ming Hui WANG

引用本文: Xing Fan CHEN,  He Xing LI,  Ye Ping XU,  Ming Hui WANG. Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over An Ultrafine Co-B Amorphous Catalyst[J]. Chinese Chemical Letters, 2002, 13(2): 107-110. shu
Citation:  Xing Fan CHEN,  He Xing LI,  Ye Ping XU,  Ming Hui WANG. Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over An Ultrafine Co-B Amorphous Catalyst[J]. Chinese Chemical Letters, 2002, 13(2): 107-110. shu

Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over An Ultrafine Co-B Amorphous Catalyst

  • 基金项目:

    This work was supported by the National Natural Science Foundation of China (29973025) and the Natural Science Foundation of Shanghai Science and Technology Committee (98QMA11402).

摘要: A novel Co-B amorphous alloy catalyst in the form of ultrafine particles was prepared by chemical reduction of CoCl2 with aqueous NaBH4, which exhibited excellent activity and selectivity during the hydrogenation of cinnamaldehyde to cinnamyl alcohol in liquid phase.The optimum yield of cinnamyl alcohol was 87.6%, much better than the yield of using Raney Ni, Raney Co and other Co-based catalysts.

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  • 收稿日期:  2001-06-04
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