引用本文:
Tian Yu WANG, Jing Rong CHEN, Jin Shi MA. Synthesis and Photochemistry of Diphenylchlorin and Diphenylbacteriochlorin[J]. Chinese Chemical Letters,
2001, 12(8): 671-674.
Citation: Tian Yu WANG, Jing Rong CHEN, Jin Shi MA. Synthesis and Photochemistry of Diphenylchlorin and Diphenylbacteriochlorin[J]. Chinese Chemical Letters, 2001, 12(8): 671-674.
Citation: Tian Yu WANG, Jing Rong CHEN, Jin Shi MA. Synthesis and Photochemistry of Diphenylchlorin and Diphenylbacteriochlorin[J]. Chinese Chemical Letters, 2001, 12(8): 671-674.
Synthesis and Photochemistry of Diphenylchlorin and Diphenylbacteriochlorin
摘要:
Diphenylchlorin (DPC) and diphenylbacteriochlorin (DPBC) were synthesized for the first time from reduction of 5,10-diphenylporphyrin (DPP). As photosensitizers they have sizable absorption in the red region of the visible spectrum. The high yield of DPC-photosensitized generation of 1O2, and the EPR studies in homogenerous solution showed that the photodynamic action of DPP-based photosensitizers may proceed via type I and type Ⅱ machanisms.
English
Synthesis and Photochemistry of Diphenylchlorin and Diphenylbacteriochlorin
Abstract:
Diphenylchlorin (DPC) and diphenylbacteriochlorin (DPBC) were synthesized for the first time from reduction of 5,10-diphenylporphyrin (DPP). As photosensitizers they have sizable absorption in the red region of the visible spectrum. The high yield of DPC-photosensitized generation of 1O2, and the EPR studies in homogenerous solution showed that the photodynamic action of DPP-based photosensitizers may proceed via type I and type Ⅱ machanisms.
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Key words:
- Diphenylchlorin
- / diphenylbacteriochlorin
- / synthesis
- / photochemistry.
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