引用本文:
Jian Jun ZHAI, Wei YING, Fan Zhi ZHA, Yao Zu CHEN. Detection of Claisen Rearrangement Occurring in Allyl Phenyl Ether by in situ GC/MS[J]. Chinese Chemical Letters,
1998, 9(4): 381-384.
Citation: Jian Jun ZHAI, Wei YING, Fan Zhi ZHA, Yao Zu CHEN. Detection of Claisen Rearrangement Occurring in Allyl Phenyl Ether by in situ GC/MS[J]. Chinese Chemical Letters, 1998, 9(4): 381-384.
Citation: Jian Jun ZHAI, Wei YING, Fan Zhi ZHA, Yao Zu CHEN. Detection of Claisen Rearrangement Occurring in Allyl Phenyl Ether by in situ GC/MS[J]. Chinese Chemical Letters, 1998, 9(4): 381-384.
Detection of Claisen Rearrangement Occurring in Allyl Phenyl Ether by in situ GC/MS
摘要:
We report here a new strategy for revealing the Claisen rearrangement of allyl phenyl ether occurring in the gas phase by in situ GC/MS technique. The Ciaisen rearrangement has been observed when allyl phenyl ether passed through the capillary column at certain temperatures. The relative proportion of rearrangement products is dependent on the temperature of the capillary column and the substituents on the phenyl ring.
English
Detection of Claisen Rearrangement Occurring in Allyl Phenyl Ether by in situ GC/MS
Abstract:
We report here a new strategy for revealing the Claisen rearrangement of allyl phenyl ether occurring in the gas phase by in situ GC/MS technique. The Ciaisen rearrangement has been observed when allyl phenyl ether passed through the capillary column at certain temperatures. The relative proportion of rearrangement products is dependent on the temperature of the capillary column and the substituents on the phenyl ring.
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Key words:
- in situ GC/MS
- / allyl phenyl ether
- / Claisen rearrangement
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