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Studies on Diastereoselective Intramolecular meta-Cycloaddition ofArene to Olefin (Part I)

Xiu Min SHEN ,  Xiao Chuan GUO ,  Liang Dong SUN ,  Cong ZHANG

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引用本文: Xiu Min SHEN,  Xiao Chuan GUO,  Liang Dong SUN,  Cong ZHANG. Studies on Diastereoselective Intramolecular meta-Cycloaddition ofArene to Olefin (Part I)[J]. Chinese Chemical Letters, 1998, 9(2): 131-134. shu
Citation:  Xiu Min SHEN,  Xiao Chuan GUO,  Liang Dong SUN,  Cong ZHANG. Studies on Diastereoselective Intramolecular meta-Cycloaddition ofArene to Olefin (Part I)[J]. Chinese Chemical Letters, 1998, 9(2): 131-134. shu

Studies on Diastereoselective Intramolecular meta-Cycloaddition ofArene to Olefin (Part I)

  • Department of Chemistry, Bejing Normal University, Beijing 100875

  • 基金项目:

    This project was supported by the NNSFC. The authors wish to thank the National Laboratory of Applied Organic Chemistry and the Research Center for Analysis and Measurement of Lanzhou University for the measurement of all spectra.

摘要: The photoinduced intramolecular meta-cycloaddition of bichromophores la-Id gave diastereoselectively two types of adducts, 2a-2d and 3a-3d. respectively. The observed stereo-chemistry of cycloaddition was rationalized in terms of hydrogen bond effect induced by the 3-hydroxy group in the 5-phenylpent-1-ene skeleton.

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  • 收稿日期:  1997-09-23
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