Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate

Yun Xing YAN Qi FANG Wen Tao YU Yu Peng TIAN Duo Rong YUAN Xin Qiang WANG Fan Qing MENG Zhi Gang CAI Ling Zhi ZHANG

引用本文: Yun Xing YAN,  Qi FANG,  Wen Tao YU,  Yu Peng TIAN,  Duo Rong YUAN,  Xin Qiang WANG,  Fan Qing MENG,  Zhi Gang CAI,  Ling Zhi ZHANG. Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate[J]. Chinese Chemical Letters, 1998, 9(12): 1125-1128. shu
Citation:  Yun Xing YAN,  Qi FANG,  Wen Tao YU,  Yu Peng TIAN,  Duo Rong YUAN,  Xin Qiang WANG,  Fan Qing MENG,  Zhi Gang CAI,  Ling Zhi ZHANG. Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate[J]. Chinese Chemical Letters, 1998, 9(12): 1125-1128. shu

Synthesis, Structure and Non-linear Optical Properties of Iron Mercury Tetrathiocyanate

  • 基金项目:

    This work was supported by the National Natural Science Foundation of China and by the Scientific Research Foundation for Outstanding Young Scientist of Shangdong Province of China.

摘要: Iron Mercury Tetrathiocyanate (FeHg(SCN)4) has been synthesized and its structure has been determined. It belongs to the tetragonal system, 14 space group. The Hg-S-C≡N-Fe bridge leads to the formation of an infinite three dimensional network. Irradiated by a 1.064 nm Nd:YAG laser beam, FeHg (SCN)4 showed a 0.532 nm second harmonic intensity which is 0.6 times as that of organic nonlinear optical crystal urea.

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  • 收稿日期:  1998-04-20
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