引用本文:
Xiang Jun YUE, Yu Lin LI. STUDIES ON THE SYNTHESIS OF SINULARIOL-D, SINULARIOL-A AND SINULARIC ACID-A.-SYNTHESIS OF (5R)-7,7-DIMETHOXY-5-[1-(2-TERT-BUTYLDIPHENYLSILOXYMETHYL)VINYL]-2-HEPTANONE[J]. Chinese Chemical Letters,
1994, 5(7): 563-564.
Citation: Xiang Jun YUE, Yu Lin LI. STUDIES ON THE SYNTHESIS OF SINULARIOL-D, SINULARIOL-A AND SINULARIC ACID-A.-SYNTHESIS OF (5R)-7,7-DIMETHOXY-5-[1-(2-TERT-BUTYLDIPHENYLSILOXYMETHYL)VINYL]-2-HEPTANONE[J]. Chinese Chemical Letters, 1994, 5(7): 563-564.
Citation: Xiang Jun YUE, Yu Lin LI. STUDIES ON THE SYNTHESIS OF SINULARIOL-D, SINULARIOL-A AND SINULARIC ACID-A.-SYNTHESIS OF (5R)-7,7-DIMETHOXY-5-[1-(2-TERT-BUTYLDIPHENYLSILOXYMETHYL)VINYL]-2-HEPTANONE[J]. Chinese Chemical Letters, 1994, 5(7): 563-564.
STUDIES ON THE SYNTHESIS OF SINULARIOL-D, SINULARIOL-A AND SINULARIC ACID-A.-SYNTHESIS OF (5R)-7,7-DIMETHOXY-5-[1-(2-TERT-BUTYLDIPHENYLSILOXYMETHYL)VINYL]-2-HEPTANONE
摘要:
An efficient synthesis of (5R)-7,7-dimethoxy-5-[1-(2-tert-butyldiphenylsiloxymethyl)vinyl]-2-heptanone,a key intermediate in the synthesis of antitumor cembrane type sinuiariol-D,sinularial-A and sinuiaric acid-A isolated from the soft coral Sinularin moyi was first described from (R)-limonene.
English
STUDIES ON THE SYNTHESIS OF SINULARIOL-D, SINULARIOL-A AND SINULARIC ACID-A.-SYNTHESIS OF (5R)-7,7-DIMETHOXY-5-[1-(2-TERT-BUTYLDIPHENYLSILOXYMETHYL)VINYL]-2-HEPTANONE
Abstract:
An efficient synthesis of (5R)-7,7-dimethoxy-5-[1-(2-tert-butyldiphenylsiloxymethyl)vinyl]-2-heptanone,a key intermediate in the synthesis of antitumor cembrane type sinuiariol-D,sinularial-A and sinuiaric acid-A isolated from the soft coral Sinularin moyi was first described from (R)-limonene.
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