引用本文:
Michael Yu ZHU, Susan Si Xun SUN, Yu Buang ZHANG, Xi Kui JIANG. CAN TRICHLOROMETHANE SULFONYL BROMIDE BE USED AS AN ADDENDUM AS WELL AS A TELOGEN IN ITS ADDITION REACTION TO VINYLIDENE FLUORIDE?[J]. Chinese Chemical Letters,
1993, 4(7): 583-586.
Citation: Michael Yu ZHU, Susan Si Xun SUN, Yu Buang ZHANG, Xi Kui JIANG. CAN TRICHLOROMETHANE SULFONYL BROMIDE BE USED AS AN ADDENDUM AS WELL AS A TELOGEN IN ITS ADDITION REACTION TO VINYLIDENE FLUORIDE?[J]. Chinese Chemical Letters, 1993, 4(7): 583-586.
Citation: Michael Yu ZHU, Susan Si Xun SUN, Yu Buang ZHANG, Xi Kui JIANG. CAN TRICHLOROMETHANE SULFONYL BROMIDE BE USED AS AN ADDENDUM AS WELL AS A TELOGEN IN ITS ADDITION REACTION TO VINYLIDENE FLUORIDE?[J]. Chinese Chemical Letters, 1993, 4(7): 583-586.
CAN TRICHLOROMETHANE SULFONYL BROMIDE BE USED AS AN ADDENDUM AS WELL AS A TELOGEN IN ITS ADDITION REACTION TO VINYLIDENE FLUORIDE?
摘要:
CCl3SO2Br used as a "telogen" reacts with CH2=CF2 to give mainly the "mono-adduct" CCl3CH2CF2Br, together with very small amouats of CCl3CF2CH2Br, CCl2BrCH2CF2Br and the "di-adduct" CCl3 (CH2CF2)2Br.The result indicates that CCl3SO2Br can be used as an addendum in trichloromethyl-bromo-addition reactions to olefins.
English
CAN TRICHLOROMETHANE SULFONYL BROMIDE BE USED AS AN ADDENDUM AS WELL AS A TELOGEN IN ITS ADDITION REACTION TO VINYLIDENE FLUORIDE?
Abstract:
CCl3SO2Br used as a "telogen" reacts with CH2=CF2 to give mainly the "mono-adduct" CCl3CH2CF2Br, together with very small amouats of CCl3CF2CH2Br, CCl2BrCH2CF2Br and the "di-adduct" CCl3 (CH2CF2)2Br.The result indicates that CCl3SO2Br can be used as an addendum in trichloromethyl-bromo-addition reactions to olefins.
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