EFFECT OF HYDROGEN BONDING ON DIRECTION OF PHOTOISOMERIZATION OF RETINOIDS:THE ORIGIN OF THE SOLVENT POLARITY EFFECT.

Bao Wen ZHANG Robert S. H. LIU

引用本文: Bao Wen ZHANG,  Robert S. H. LIU. EFFECT OF HYDROGEN BONDING ON DIRECTION OF PHOTOISOMERIZATION OF RETINOIDS:THE ORIGIN OF THE SOLVENT POLARITY EFFECT.[J]. Chinese Chemical Letters, 1991, 2(1): 9-12. shu
Citation:  Bao Wen ZHANG,  Robert S. H. LIU. EFFECT OF HYDROGEN BONDING ON DIRECTION OF PHOTOISOMERIZATION OF RETINOIDS:THE ORIGIN OF THE SOLVENT POLARITY EFFECT.[J]. Chinese Chemical Letters, 1991, 2(1): 9-12. shu

EFFECT OF HYDROGEN BONDING ON DIRECTION OF PHOTOISOMERIZATION OF RETINOIDS:THE ORIGIN OF THE SOLVENT POLARITY EFFECT.

  • 基金项目:

    The work was supported by grants from U.S.Public Health Services (DK-17806) and the Natural Science Foundation (CHE-16500).

摘要: Studies of direction of photoisomerization of retinal, retinonitrile, α-retinonitrile and a trienenitrile analog in different solvents with varying wave-lengths of excitation and reaction temperature led to the conclusion that the well known solvent dependent photochemistry of retinoids is due to selective excitation of the hydrogen bonded species.

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  • 收稿日期:  1990-12-14
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