引用本文:
杨立群, 谢志明, 李卓美. 金属离子络合交联丙烯酸酯共聚物无皂水溶胶涂料Ⅰ.丙烯酸酯共聚物的合成和表征[J]. 应用化学,
1998, 15(2): 85-87.
Citation: Yang Liqun, Xie Zhiming, Li Zhuomei. Studies on Metal Ion Coordination-Crosslinking of Soap-free Acrylate Copolymer Hydrosol Coating Ⅰ. Synthesis and Characterization of Acrylate Copolymer[J]. Chinese Journal of Applied Chemistry, 1998, 15(2): 85-87.
Citation: Yang Liqun, Xie Zhiming, Li Zhuomei. Studies on Metal Ion Coordination-Crosslinking of Soap-free Acrylate Copolymer Hydrosol Coating Ⅰ. Synthesis and Characterization of Acrylate Copolymer[J]. Chinese Journal of Applied Chemistry, 1998, 15(2): 85-87.
金属离子络合交联丙烯酸酯共聚物无皂水溶胶涂料Ⅰ.丙烯酸酯共聚物的合成和表征
English
Studies on Metal Ion Coordination-Crosslinking of Soap-free Acrylate Copolymer Hydrosol Coating Ⅰ. Synthesis and Characterization of Acrylate Copolymer
Abstract:
The soap-free hydrosol, which was crosslinked by Zn(NH3)42+ to form coating film, has been prepared from acrylate copolymer from (methyl metacrylate/butyl acrylate/acrylic acid/styrene (or divinylbenzene). The coating films have better water resistance due to the presence of benzene ring in the copolymer, which has been characterized by 13C NMR, IR and GPC for molecular weight determination.
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Key words:
- crosslinked acrylate copolymer
- / soap-free hydrosol
- / water-borne coating
- / synthesis
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