引用本文:
刘宇, 林祥钦. 非水溶剂中铁酞菁的“in-situ”可见紫外光谱电化学[J]. 应用化学,
1998, 15(2): 47-50.
Citation: Liu Yu, Lin Xiangqin. in-situ UV-visible Spectroelectrochemical Studies of Ironphthalocyanine in Non Aqueous Solvents[J]. Chinese Journal of Applied Chemistry, 1998, 15(2): 47-50.
Citation: Liu Yu, Lin Xiangqin. in-situ UV-visible Spectroelectrochemical Studies of Ironphthalocyanine in Non Aqueous Solvents[J]. Chinese Journal of Applied Chemistry, 1998, 15(2): 47-50.
非水溶剂中铁酞菁的“in-situ”可见紫外光谱电化学
English
in-situ UV-visible Spectroelectrochemical Studies of Ironphthalocyanine in Non Aqueous Solvents
Abstract:
Cyclic voltammetry and in-situ UV-Visible spectroelectrochemical behavior of (TbPc)Fe(Ⅲ)Cl, (TbPc)Fe(Ⅲ)ClO4 and (TbPc)Zn(Ⅱ) are reported. Five redox steps of Fe(Ⅳ)/radical cation, Fe(Ⅳ)/Fe(Ⅲ), Fe(Ⅲ)/Fe(Ⅱ), Fe(Ⅱ)/Fe(Ⅰ) and Fe(Ⅰ)/radical anion in THF were observed. The existence of un usual oxidation state of Fe(Ⅳ) is attributed to the axial coordination of Cl- anion. A mechanism for the redox reactions has been proposed.
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Key words:
- iron phthalocyanine
- / in-situ spectroelectrochemistry
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