引用本文:
师同顺, 柳巍, 徐春放, 王杏乔, 刘国发. 四萘基四苯并卟啉钴的合成、表征和电化学行为[J]. 应用化学,
1998, 15(2): 23-26.
Citation: Shi Tongshun, Liu Wei, Xu Chunfang, Wang Xingqiao, Liu Guofa. Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex[J]. Chinese Journal of Applied Chemistry, 1998, 15(2): 23-26.
Citation: Shi Tongshun, Liu Wei, Xu Chunfang, Wang Xingqiao, Liu Guofa. Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex[J]. Chinese Journal of Applied Chemistry, 1998, 15(2): 23-26.
四萘基四苯并卟啉钴的合成、表征和电化学行为
English
Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex
Abstract:
The title complex TNTBPCo(Ⅱ) was synthesized and characterized by elemental analysis, UV-vis, spectrum, IR photoacoustic spectrum, H NMR and molar conductance measurements. Its electrochemical behavior has been investigated by cyclic voltammetry in DMSO. The half wave potential of [TNTBPCo(Ⅲ)]+ /TNTBPCo(Ⅱ) was -0.255 V and that of TNTBPCo(Ⅱ)/[TNTBPCo(Ⅰ)]-1 was -1.175 V. The half wave potential of redox of porphyrin ring [TNTBPCo(Ⅰ)]-1 /[TNTBPCo(Ⅰ)]-2 was -1.850 V.
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