Citation:
SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*[J]. Chinese Journal of Polymer Science,
2002, 20(2): 177-180.
SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*
摘要:
A route was proposed to synthesize 3-benryl-glyceric acid (3-BGA) as an important intermediate for the synthesis ofa novel six-membered cyclic ester monomer - 3-benzyloxymethyl-1,4-dioxane-2,5-dione (3-BMG). According to this route,3-BGA was obtained from ring-opening reaction of benzyl alcohol with methyl glycidate, which was prepared from theepoxidation of methyl acrylate using sodium hypochlorite as the oxidant.
English
SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*
Abstract:
A route was proposed to synthesize 3-benryl-glyceric acid (3-BGA) as an important intermediate for the synthesis ofa novel six-membered cyclic ester monomer - 3-benzyloxymethyl-1,4-dioxane-2,5-dione (3-BMG). According to this route,3-BGA was obtained from ring-opening reaction of benzyl alcohol with methyl glycidate, which was prepared from theepoxidation of methyl acrylate using sodium hypochlorite as the oxidant.
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