Citation:
LI Zifa, CHEN Zhijun, ZHANG Shuyuan, CAO Shaokui, ZHOU Qifeng. SYNTHESIS AND CHARACTERIZATION OF LIQUID CRYSTAL POLYMERS WITH T-SHAPED TWO-DIMENSIONAL MESOGENIC UNITS*[J]. Chinese Journal of Polymer Science,
1996, 14(1): 71-79.

SYNTHESIS AND CHARACTERIZATION OF LIQUID CRYSTAL POLYMERS WITH T-SHAPED TWO-DIMENSIONAL MESOGENIC UNITS*
摘要:
Two series of new liquid crystailine polymers with T-shaped two-dimensional mesogenicunits were synthesized by low temperature solution polycondensations of 4-substituted N-2, 5- dihydroxybenzylidene aniline monomers with different diacyl dichlorides. The polymerswere found to be nematic and shown liquid crystailine behavior. The melting temperatureT_m and the clearing temperature Ti of the polymers change regularly with varying of themonomer structures.
English
SYNTHESIS AND CHARACTERIZATION OF LIQUID CRYSTAL POLYMERS WITH T-SHAPED TWO-DIMENSIONAL MESOGENIC UNITS*
Abstract:
Two series of new liquid crystailine polymers with T-shaped two-dimensional mesogenicunits were synthesized by low temperature solution polycondensations of 4-substituted N-2, 5- dihydroxybenzylidene aniline monomers with different diacyl dichlorides. The polymerswere found to be nematic and shown liquid crystailine behavior. The melting temperatureT_m and the clearing temperature Ti of the polymers change regularly with varying of themonomer structures.

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