Citation:
CHEN Chunwei, HUANG Meiyu, JIANG Yingyan. CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL[J]. Chinese Journal of Polymer Science,
1996, 14(1): 26-33.
CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL
摘要:
A new kind of inorganic polymer, viz. silica-supported polytitazane (Ti-N), and itsplatinum complex (Ti-N-Pt) were prepared. Cyclohexanone can be obtained in a maximumyield of about 62.2% in the hydrogenation of phenol over Ti-N-Pt at room temperatureunder atmospheric pressure. The effects of mole ratio of N/Pt in the complex, concentrationof the catalyst and reaction temperature on the catalytic activity and selectivity have beenstudied. The complex can be reused several times without loss in its catalytic activity.
English
CATALYTIC BEHAVIOR OF A SILICA-SUPPORTED POLYTITAZANE-PLATINUM COMPLEX FOR THE HYDROGENATION OF PHENOL
Abstract:
A new kind of inorganic polymer, viz. silica-supported polytitazane (Ti-N), and itsplatinum complex (Ti-N-Pt) were prepared. Cyclohexanone can be obtained in a maximumyield of about 62.2% in the hydrogenation of phenol over Ti-N-Pt at room temperatureunder atmospheric pressure. The effects of mole ratio of N/Pt in the complex, concentrationof the catalyst and reaction temperature on the catalytic activity and selectivity have beenstudied. The complex can be reused several times without loss in its catalytic activity.
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