Citation:
LI Bogeng, YU Zaizhang, CAI Qizen, LI Baofang. STUDIES ON POLYMERIZATION KINETICS OF METHYL METHACRYLATE AT HIGH CONVERSION*[J]. Chinese Journal of Polymer Science,
1984, 2(1): 82-91.
STUDIES ON POLYMERIZATION KINETICS OF METHYL METHACRYLATE AT HIGH CONVERSION*
摘要:
The bulk polymerization of methyl methacrylate which was carried out in a metallic dilatometer and in a differential scanning calorimeter has been studied over the complete course of the reaction. An attempt was made to quantitatively express the relation on the onset of gel effect and the final conversion with polymerization conditions such as temperature, kinds and concentration of initiators. It was demonstrated further that the final conversion of polymerization in homogeneous ideal systems is only dependent upon the reaction temperature.
English
STUDIES ON POLYMERIZATION KINETICS OF METHYL METHACRYLATE AT HIGH CONVERSION*
Abstract:
The bulk polymerization of methyl methacrylate which was carried out in a metallic dilatometer and in a differential scanning calorimeter has been studied over the complete course of the reaction. An attempt was made to quantitatively express the relation on the onset of gel effect and the final conversion with polymerization conditions such as temperature, kinds and concentration of initiators. It was demonstrated further that the final conversion of polymerization in homogeneous ideal systems is only dependent upon the reaction temperature.
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