反式钙钛矿光伏电池制备及性能表征——推荐一个综合化学设计性实验

引用本文: 许利刚, 李明光, 陈润锋. 反式钙钛矿光伏电池制备及性能表征——推荐一个综合化学设计性实验[J]. 大学化学, 2023, 38(11): 180-186. doi: 10.3866/PKU.DXHX202304020 shu

Citation: Ligang Xu, Mingguang Li, Runfeng Chen. Fabrication and Performance Characteristics of Inverted Perovskite Solar Cells: Recommending a Comprehensive Chemistry Design Experiment[J]. University Chemistry, 2023, 38(11): 180-186. doi: 10.3866/PKU.DXHX202304020 shu

反式钙钛矿光伏电池制备及性能表征——推荐一个综合化学设计性实验

南京邮电大学有机电子与信息显示国家重点实验室, 南京 210023

通讯作者: 许利刚,Email:iamlgxu@njupt.edu.cn

基金项目:
国家自然科学基金面上项目（62274094），南京邮电大学教学改革研究项目（JG03020JX17）；南京邮电大学材料科学与工程学院教学改革研究项目（CLJG2005）

摘要: 面向中国“双碳”目标的战略需求，发展新型的低成本高性能的光伏电池至关重要。本文介绍了新型反式结构钙钛矿光伏电池的制备过程及其相关的性能表征，推荐其作为一个综合化学设计性实验，提高本科生的科技创新及综合实践能力。该实验包括反式钙钛矿光伏电池的制备流程，包括电极传输层、钙钛矿薄膜和电极层的制备。用扫描电子显微镜及X射线衍射仪研究钙钛矿薄膜的形貌及结晶质量表征，随后通过太阳光模拟器对电池的电流密度与电压（J–V）特性曲线及标准太阳光照稳定性测试。本实验集薄膜制备、材料表征及电池性能测试为一体，满足不同的教学需求，同时对实验涉及的化学原理进行讲授，方便学生对实验进行拓展，为今后的课外科技研究提供重要的基础。

关键词:

English

Fabrication and Performance Characteristics of Inverted Perovskite Solar Cells: Recommending a Comprehensive Chemistry Design Experiment

Key Laboratory for Organic Electronics and Information Displays (KLOEID), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: Ligang Xu, iamlgxu@njupt.edu.cn

Received Date: 06 April 2023

Abstract: The development of low-cost and high-performance solar cells has become an important direction for the "dual carbon strategy". In this manuscript, we mainly describe the fabrication and characterization of novel inverted perovskite solar cells as well as a comprehensive chemistry experiment for undergraduates conceived to promote their scientific innovation and comprehensive practical abilities. This experiment encompasses the fabrication process of inverted perovskite solar cells, including transport layer fabrication, perovskite film, and electrode. The morphology and crystal quality of perovskite films were characterized by scanning electron microscope and X-ray diffractometer, and the current density and voltage (J-V) curves and photostability of the devices were tested using a solar simulator. The proposed experiment also integrates film preparation, material characterization, and device performance testing to meet different teaching needs. Simultaneously, the basic chemical principles in the experiment are taught to encourage students to further expand the experiment and provide a solid foundation for their future research and exploration.

Key words:

1. [1]
  Manser, J. S.; Christians, J. A.; Kamat, P. V. Chem. Rev. 2016, 116 (21), 12956.Manser, J. S.; Christians, J. A.; Kamat, P. V. Chem. Rev. 2016, 116 (21), 12956.
2. [2]
  Zhang, C.; Kuang, D.-B.; Wu, W.-Q. Small Methods 2020, 4 (2), 1900662.Zhang, C.; Kuang, D.-B.; Wu, W.-Q. Small Methods 2020, 4 (2), 1900662.
3. [3]
  Min, H.; Lee, D. Y.; Kim, J.; Kim, G.; Lee, K. S.; Kim, J.; Paik, M. J.; Kim, Y. K.; Kim, K. S.; Kim, M. G.; et al. Nature 2021, 598 (7881), 444.Min, H.; Lee, D. Y.; Kim, J.; Kim, G.; Lee, K. S.; Kim, J.; Paik, M. J.; Kim, Y. K.; Kim, K. S.; Kim, M. G.; et al. Nature 2021, 598 (7881), 444.
4. [4]
  Peng, J.; Kremer, F.; Walter, D.; Wu, Y. L.; Ji, Y.; Xiang, J.; Liu, W. Z.; Duong, T.; Shen, H. P.; Lu, T.; et al. Nature 2022, 601 (7894), 573.Peng, J.; Kremer, F.; Walter, D.; Wu, Y. L.; Ji, Y.; Xiang, J.; Liu, W. Z.; Duong, T.; Shen, H. P.; Lu, T.; et al. Nature 2022, 601 (7894), 573.
5. [5]
  Kim, M.; Jeong, J.; Lu, H.; Lee, T. K.; Eickemeyer, F. T.; Liu, Y.; Choi, I. W.; Choi, S. J.; Jo, Y.; Kim, H.-B.; et al. Science 2022, 375 (6578), 302.Kim, M.; Jeong, J.; Lu, H.; Lee, T. K.; Eickemeyer, F. T.; Liu, Y.; Choi, I. W.; Choi, S. J.; Jo, Y.; Kim, H.-B.; et al. Science 2022, 375 (6578), 302.
6. [6]
  周禹含, 冯湘云, 朱佳, 许利刚, 陈润锋. 无机化学学报, 2022, 38 (10), 188.
7. [7]
  Li, X.; Zhang, W.; Guo, X.; Lu, C.; Wei, J.; Fang, J. Science 2022, 375 (6579), 434.Li, X.; Zhang, W.; Guo, X.; Lu, C.; Wei, J.; Fang, J. Science 2022, 375 (6579), 434.
8. [8]
  Peng, W.; Mao, K.; Cai, F.; Meng, H.; Zhu, Z.; Li, T.; Yuan, S.; Xu, Z.; Feng, X.; Xu, J.; et al. Science 2023, 379 (6633), 683.Peng, W.; Mao, K.; Cai, F.; Meng, H.; Zhu, Z.; Li, T.; Yuan, S.; Xu, Z.; Feng, X.; Xu, J.; et al. Science 2023, 379 (6633), 683.
9. [9]
  范旭良, 许丽梅, 马琳. 大学化学, 2021, 36 (12), 2102027.
10. [10]
  吴兴隆, 吕红艳, 杜苗, 王嗣泽, 王晓彤, 张凯洋, 李炜晨. 大学化学, 2023, 38 (9), 234.
11. [11]
  张金澍, 王以春, 倪江锋. 大学化学, 2023, 38 (2), 221.
12. [12]
  车平, 杨涵, 范慧俐, 王明文, 李文军. 大学化学, 2020, 35 (1), 59.
13. [13]
  Park, N.-G. Mater. Today 2015, 18 (2), 65.Park, N.-G. Mater. Today 2015, 18 (2), 65.
14. [14]
  Jeng, J.-Y.; Chiang, Y.-F.; Lee, M.-H.; Peng, S.-R.; Guo, T.-F.; Chen, P. Adv. Mater. 2013, 25 (27), 3727.Jeng, J.-Y.; Chiang, Y.-F.; Lee, M.-H.; Peng, S.-R.; Guo, T.-F.; Chen, P. Adv. Mater. 2013, 25 (27), 3727.

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沈阳化工大学材料科学与工程学院沈阳 110142

反式钙钛矿光伏电池制备及性能表征——推荐一个综合化学设计性实验

通讯作者: 许利刚,Email:iamlgxu@njupt.edu.cn

English

Fabrication and Performance Characteristics of Inverted Perovskite Solar Cells: Recommending a Comprehensive Chemistry Design Experiment

Corresponding author: Ligang Xu, iamlgxu@njupt.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

反式钙钛矿光伏电池制备及性能表征——推荐一个综合化学设计性实验

通讯作者: 许利刚,Email:iamlgxu@njupt.edu.cn

English

Fabrication and Performance Characteristics of Inverted Perovskite Solar Cells: Recommending a Comprehensive Chemistry Design Experiment

Corresponding author: Ligang Xu, iamlgxu@njupt.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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