引用本文:
Quan Ling SUO, Xing Ming LIU, Yuan Qi YIN, Dao Sen JIN, Shu Ben LI. STRUCTURAL EVIDENCES OF Ru (H)2(H2) (PPh3)3 AT LOW TEMPERATURE[J]. Chinese Chemical Letters,
1993, 4(7): 653-656.
Citation: Quan Ling SUO, Xing Ming LIU, Yuan Qi YIN, Dao Sen JIN, Shu Ben LI. STRUCTURAL EVIDENCES OF Ru (H)2(H2) (PPh3)3 AT LOW TEMPERATURE[J]. Chinese Chemical Letters, 1993, 4(7): 653-656.
Citation: Quan Ling SUO, Xing Ming LIU, Yuan Qi YIN, Dao Sen JIN, Shu Ben LI. STRUCTURAL EVIDENCES OF Ru (H)2(H2) (PPh3)3 AT LOW TEMPERATURE[J]. Chinese Chemical Letters, 1993, 4(7): 653-656.
STRUCTURAL EVIDENCES OF Ru (H)2(H2) (PPh3)3 AT LOW TEMPERATURE
摘要:
FTIR spectrum at liquid nitrogen temperature and 1H NMR of air-sensitive polyhydride Ru(H)2(H2)(PPh3)3 have been measured for the first time.It is found that a fluxional process happens at room temperature, but the structure of Ru(H)2(H2)(PPh3)3 with non-equivalent hydrogens is discernible at low temperature.
English
STRUCTURAL EVIDENCES OF Ru (H)2(H2) (PPh3)3 AT LOW TEMPERATURE
Abstract:
FTIR spectrum at liquid nitrogen temperature and 1H NMR of air-sensitive polyhydride Ru(H)2(H2)(PPh3)3 have been measured for the first time.It is found that a fluxional process happens at room temperature, but the structure of Ru(H)2(H2)(PPh3)3 with non-equivalent hydrogens is discernible at low temperature.
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