引用本文:
Xiu Zhong ZHOU, Bai Quan WANG, Shan Sheng XU. SYNTHESIS,STRUCTURE AND THERMOREANGEMENT OF TRTRA METHYLDISILANDIYL BIS(1-INDENYL) TETRACARBONYL DI-IRON[J]. Chinese Chemical Letters,
1995, 6(10): 897-898.
Citation: Xiu Zhong ZHOU, Bai Quan WANG, Shan Sheng XU. SYNTHESIS,STRUCTURE AND THERMOREANGEMENT OF TRTRA METHYLDISILANDIYL BIS(1-INDENYL) TETRACARBONYL DI-IRON[J]. Chinese Chemical Letters, 1995, 6(10): 897-898.
Citation: Xiu Zhong ZHOU, Bai Quan WANG, Shan Sheng XU. SYNTHESIS,STRUCTURE AND THERMOREANGEMENT OF TRTRA METHYLDISILANDIYL BIS(1-INDENYL) TETRACARBONYL DI-IRON[J]. Chinese Chemical Letters, 1995, 6(10): 897-898.
SYNTHESIS,STRUCTURE AND THERMOREANGEMENT OF TRTRA METHYLDISILANDIYL BIS(1-INDENYL) TETRACARBONYL DI-IRON
摘要:
The title compound (Me2SiSiMe2)[η5-1-indenyl)Fe(CO)]2(μ-CO)2(1) was prepared by the reaction of 1.2-bis(1-indenyl)tetramethyldisilane and Fe(CO)5 in relluxing heptane.1 in refluxing xylene can be converted into [Me2Si(η5-1-indenyl) Fe(CO)2]2(2).The pure trans isomer 2t was obtained and its crystal and molecular structure was determined by X-ray diffraction.
English
SYNTHESIS,STRUCTURE AND THERMOREANGEMENT OF TRTRA METHYLDISILANDIYL BIS(1-INDENYL) TETRACARBONYL DI-IRON
Abstract:
The title compound (Me2SiSiMe2)[η5-1-indenyl)Fe(CO)]2(μ-CO)2(1) was prepared by the reaction of 1.2-bis(1-indenyl)tetramethyldisilane and Fe(CO)5 in relluxing heptane.1 in refluxing xylene can be converted into [Me2Si(η5-1-indenyl) Fe(CO)2]2(2).The pure trans isomer 2t was obtained and its crystal and molecular structure was determined by X-ray diffraction.
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