仪器分析课程中绿色度概念的引入

引用本文: 张红医, 何珺瑶, 石志红. 仪器分析课程中绿色度概念的引入[J]. 大学化学, 2023, 38(11): 293-300. doi: 10.3866/PKU.DXHX202304048 shu

Citation: Hongyi Zhang, Junyao He, Zhihong Shi. Introduction of the Concept of Greenness into Instrumental Analysis Course[J]. University Chemistry, 2023, 38(11): 293-300. doi: 10.3866/PKU.DXHX202304048 shu

仪器分析课程中绿色度概念的引入

1.
河北大学化学与环境科学学院, 河北保定 071002;
2.
河北大学化学教学研究所, 河北保定 071002

通讯作者: 张红医,Email:hyzhang@hbu.edu.cn

基金项目:
河北省首届课程思政示范课；2023年度河北省研究生教育教学改革研究项目（YJG2023005，YJG2023003）；河北省教育厅科学研究计划项目（ZD2019089）

摘要: 将绿色度引入仪器分析课程中，在简述绿色化学、绿色分析化学以及绿色液相色谱的基础上，重点讲述HPLC-EAT和CHEMS-1两种表征绿色度的方法，包括它们的使用、应用范围、局限性，并对它们绿色度结果进行了相关性分析。HPLC-EAT和CHEMS-1均可以用于表征液相色谱的绿色度，计算过程易于学生掌握。

关键词:

English

Introduction of the Concept of Greenness into Instrumental Analysis Course

1.
College of Chemistry and Environmental Science, Hebei University, Baoding 071002, Hebei Province, China;
2.
Teaching Institute for Chemistry, Hebei University, Baoding 071002, Hebei Province, China

Corresponding author: Hongyi Zhang, hyzhang@hbu.edu.cn

Received Date: 13 April 2023

Abstract: In order to fulfill organic combination of professional goal and moral goal from the course of instrumental analysis and student education, and unification of green analytical chemistry from discipline concept and the social responsibility of green development, greenness the evaluation index for describing the greening of analytical methods was introduced into our instrumental analysis course. Firstly, the development of green chemistry, green analytical chemistry and green liquid chromatography was briefly covered. Secondly, various methods for quantitative expression of greenness were presented, and the two methods of HPLC-EAT and CHEMS-1 were emphasized, involving their usages, scope of application and limitations. Finally, the two methods were employed for calculating the greenness values of the liquid chromatography methods selected from literatures, and the correlation analysis between the calculation results from the two methods were done. It was shown that the data from the two methods were not the same, but their correlation was good. Both HPLC-EAT and CHEMS-1were capable of measuring greenness of liquid chromatography, and the two methods were easy for students to grasp. We would like to recommend that the concept of greenness and together with the two methods for calculating greenness should be adopted in instrumental analysis textbooks in the future.

Key words:

1. [1]
  李克安. 分析化学教程. 北京:北京大学出版社, 2013:46-47.
2. [2]
  武汉大学. 分析化学(下册). 第5版. 北京:高等教育出版社, 2015:11-13.
3. [3]
  叶宪曾, 张新祥. 仪器分析教程. 第2版. 北京:北京大学出版社, 2008:144-145.
4. [4]
  高向阳. 新编仪器分析. 第3版. 北京:科学出版社, 2009:3-5.
5. [5]
  吴性良, 孔继烈. 分析化学原理. 第2版. 北京:化学工业出版社, 2010:25-26.
6. [6]
  Chang, C. C.; Zhang, D.; Wang, Z.; Chen, B.-H. J. Chromatogr. A 2019, 1585, 82.Chang, C. C.; Zhang, D.; Wang, Z.; Chen, B.-H. J. Chromatogr. A 2019, 1585, 82.
7. [7]
  Betz, J. M.; Brown, P. N.; Roman, M. C. Fitoterapia 2011, 82 (1), 44.Betz, J. M.; Brown, P. N.; Roman, M. C. Fitoterapia 2011, 82 (1), 44.
8. [8]
  Anastas, P.; Eghbali, N. Chem. Soc. Rev. 2010, 39 (1), 301.Anastas, P.; Eghbali, N. Chem. Soc. Rev. 2010, 39 (1), 301.
9. [9]
  Tobiszewski, M.; Mechlińska, A.; Namieśnik, J. Chem. Soc. Rev. 2010, 39,2869.Tobiszewski, M.; Mechlińska, A.; Namieśnik, J. Chem. Soc. Rev. 2010, 39,2869.
10. [10]
  Salvador, A.; Chisvert, A. Anal. Chim. Acta 2005, 537 (1-2), 15.Salvador, A.; Chisvert, A. Anal. Chim. Acta 2005, 537 (1-2), 15.
11. [11]
  Hemdan, A.; Magdy, R.; Farouk, M. J. Sep. Sci. 2018, 41 (16), 3213.Hemdan, A.; Magdy, R.; Farouk, M. J. Sep. Sci. 2018, 41 (16), 3213.
12. [12]
  Lawrence, H. K.; Gron, L. U.; Young, J. L. Chem. Rev. 2007, 107, 2695.Lawrence, H. K.; Gron, L. U.; Young, J. L. Chem. Rev. 2007, 107, 2695.
13. [13]
  Gaber, Y.; Tornvall, U.; Kumar, M. A.; Amin, M. A.; Hatti-Kaul, R. Green Chem. 2011, 13, 2021.Gaber, Y.; Tornvall, U.; Kumar, M. A.; Amin, M. A.; Hatti-Kaul, R. Green Chem. 2011, 13, 2021.
14. [14]
  Tobiszewski, M.; Namiesnik, J. Ecotox. Environ. Safe. 2015, 120, 169.Tobiszewski, M.; Namiesnik, J. Ecotox. Environ. Safe. 2015, 120, 169.
15. [15]
  叶宪曾, 张新祥. 仪器分析教程. 第2版. 北京:北京大学出版社, 2008:348.
16. [16]
  Welch, C. J.; Wu, N.; Biba, M.; Hartman, R.; Brkovic, T.; Gong, X.; Helmy, R.; Schafer, W.; Cuff, J.; Pirzada, Z.; et al. TrAC Trends Anal. Chem. 2010, 29, 667.Welch, C. J.; Wu, N.; Biba, M.; Hartman, R.; Brkovic, T.; Gong, X.; Helmy, R.; Schafer, W.; Cuff, J.; Pirzada, Z.; et al. TrAC Trends Anal. Chem. 2010, 29, 667.
17. [17]
  Poliakoff, M.; Fotzpatrick, J. M.; Farren, T. R.; Anastas P. T. Science 2002, 297, 807.Poliakoff, M.; Fotzpatrick, J. M.; Farren, T. R.; Anastas P. T. Science 2002, 297, 807.
18. [18]
  蔡卫权, 程蓓蕾, 张光旭, 刘小平. 化学进展, 2009, 21 (10), 2001.
19. [19]
  Keith, L. H.; Gron, L. U.; Young, J. L. Chem. Rev. 2007, 107, 2695.Keith, L. H.; Gron, L. U.; Young, J. L. Chem. Rev. 2007, 107, 2695.
20. [20]
  [2023-05-20]. http://www.metzger.chemie.uni-oldenburg.de/eatos/english.htm[2023-05-20]. http://www.metzger.chemie.uni-oldenburg.de/eatos/english.htm
21. [21]
  [2023-05-20]. https://pubs.rsc.org/en/Content/ArticleLanding/2011/GC/c0gc00667j#!divAbstract[2023-05-20]. https://pubs.rsc.org/en/Content/ArticleLanding/2011/GC/c0gc00667j#!divAbstract
22. [22]
  Koller, G.; Fischer, U.; Hungerbühler, K. Ind. Eng. Chem. Res. 2000, 39, 960.Koller, G.; Fischer, U.; Hungerbühler, K. Ind. Eng. Chem. Res. 2000, 39, 960.
23. [23]
  Swanson, M. B.; Davis, G. A.; Kincaid, L. E.; Schultz, T. W.; Bartmess, J. E.; Jones, S. L.; George, E. L. Environ. Toxicol. Chem. 1997, 16, 372.Swanson, M. B.; Davis, G. A.; Kincaid, L. E.; Schultz, T. W.; Bartmess, J. E.; Jones, S. L.; George, E. L. Environ. Toxicol. Chem. 1997, 16, 372.
24. [24]
  Im, S. H.; Ryoo, J. J. J. Chromatogr. A 2009, 1216, 2339.Im, S. H.; Ryoo, J. J. J. Chromatogr. A 2009, 1216, 2339.
25. [25]
  Heinig, K.; Vogt, C.; Werner, G. Anal. Chem. 1998, 70, 1885.Heinig, K.; Vogt, C.; Werner, G. Anal. Chem. 1998, 70, 1885.
26. [26]
  Rombaut, R.; De Clercq, N.; Fouber, I.; Koen, D. J. Am. Oil Chem. Soc. 2009, 86 (1), 19.Rombaut, R.; De Clercq, N.; Fouber, I.; Koen, D. J. Am. Oil Chem. Soc. 2009, 86 (1), 19.
27. [27]
  Pei, M.; Zhu, X.; Huang, X. J. Chromatogr. A 2018, 1531, 13.Pei, M.; Zhu, X.; Huang, X. J. Chromatogr. A 2018, 1531, 13.
28. [28]
  Park, H. S.; Ryu, H. R.; Rhee, C. K. Talanta 2006, 70, 481.Park, H. S.; Ryu, H. R.; Rhee, C. K. Talanta 2006, 70, 481.
29. [29]
  Park, H. S.; Rhee, C. K. J. Chromatogr. A 2004, 1046, 289.Park, H. S.; Rhee, C. K. J. Chromatogr. A 2004, 1046, 289.
30. [30]
  李明杰, 张红医, 刘晓哲, 崔春艳, 石志红. 分析化学, 2015, 43 (8), 1231.

扫一扫看文章

计量

PDF下载量: 1
文章访问数: 1481
HTML全文浏览量: 139

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

仪器分析课程中绿色度概念的引入

通讯作者: 张红医,Email:hyzhang@hbu.edu.cn

English

Introduction of the Concept of Greenness into Instrumental Analysis Course

Corresponding author: Hongyi Zhang, hyzhang@hbu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

仪器分析课程中绿色度概念的引入

通讯作者: 张红医,Email:hyzhang@hbu.edu.cn

English

Introduction of the Concept of Greenness into Instrumental Analysis Course

Corresponding author: Hongyi Zhang, hyzhang@hbu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs