高分散钴氮共掺杂碳纳米纤维氧还原催化剂

引用本文: 周扬, 程庆庆, 黄庆红, 邹志青, 严六明, 杨辉. 高分散钴氮共掺杂碳纳米纤维氧还原催化剂[J]. 物理化学学报, 2017, 33(7): 1429-1435. doi: 10.3866/PKU.WHXB201704131 shu

Citation: ZHOU Yang, CHENG Qing-Qing, HUANG Qing-Hong, ZOU Zhi-Qing, YAN Liu-Ming, YANG Hui. Highly Dispersed Cobalt-Nitrogen Co-doped Carbon Nanofiber as Oxygen Reduction Reaction Catalyst[J]. Acta Physico-Chimica Sinica, 2017, 33(7): 1429-1435. doi: 10.3866/PKU.WHXB201704131 shu

高分散钴氮共掺杂碳纳米纤维氧还原催化剂

周扬 ^1,2, ,
程庆庆 ^2, ,
黄庆红 ^2, ,
邹志青 ^2, ,
严六明 ^1, ,
杨辉 ^2,

1.
上海大学理学院, 上海 200444;
2.
中国科学院上海高等研究院, 上海 201210
基金项目:
国家高技术研究发展计划（“863”计划，2015AA043503）和国家自然科学基金（21533005，216673275）资助项目

摘要: 过渡金属氮掺杂碳基催化剂已成为替代铂基氧还原反应（ORR）电催化剂的理想选择。本文通过静电纺丝技术制备了高比表面、高度分散的钴原子配位氮掺杂的碳纳米纤维催化剂（Co-N/C）。X射线衍射（XRD）和高分辨率透射电镜（HRTEM）结果证实Co元素高度分散于制备的Co-N/C催化剂中。X射线光电子能谱结果表明N元素主要以吡啶N和石墨N形式存在。该Co-N/C催化剂对ORR反应呈现出较高的电催化活性，其氧还原起始和半波电位分别为0.92 V和0.80 V （相对于标准氢电极），接近于商业化Pt/C催化剂的性能。以制备的Co-N/C催化剂作为阴极，25℃下锌空气燃料电池的开路电位1.54 V、最大功率密度达到了190 mV·cm^-2表明该催化剂具有良好的应用前景。

关键词:

English

Highly Dispersed Cobalt-Nitrogen Co-doped Carbon Nanofiber as Oxygen Reduction Reaction Catalyst

1.
College of Sciences, Shanghai University, Shanghai 200444, P. R. China;
2.
Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, P. R. China
Received Date: 20 February 2017
Revised Date: 05 April 2017
Available Online: 07 April 2017
Fund Project:
The project was supported by the National High-tech R&D Program (863 Program, 2015AA043503) and the Nature Science Foundation of China (21533005, 21673275).

Abstract: Transition metal-nitrogen doped carbon-based catalysts have become promising alternatives to precious metal catalysts for the oxygen reduction reaction (ORR). Here, we report a nitrogen-doped carbon nanofiber electrocatalyst coordinated with highly dispersed cobalt atoms (Co-N/C) with a high specific surface area prepared by an electrospinning method. X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HR-TEM) results confirmed that Co was highly dispersed within the prepared Co-N/C catalyst. X-ray photoelectron spectroscopy for N 1s spectra showed that the N species mainly existed in the forms of pyridinic N and graphitic N. This Co-N/C catalyst exhibited considerable ORR performance with onset and half-wave potentials at 0.92 and 0.80 V (relative to the reversible hydrogen electrode (RHE)), which are comparable to those of commercial Pt/C. With the prepared Co-N/C catalyst as the cathode, a Zn-air battery displayed an open-circuit potential of 1.54 V and a peak power density of 190 mW·cm^-2 at 25℃, which suggest a promising application.

Key words:

Oxygen reduction reaction
/ Transition metal-nitrogen doped catalyst
/ Carbon nanofibers
/ Highly dispersed
/ Electrospinning

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沈阳化工大学材料科学与工程学院沈阳 110142

高分散钴氮共掺杂碳纳米纤维氧还原催化剂

English

Highly Dispersed Cobalt-Nitrogen Co-doped Carbon Nanofiber as Oxygen Reduction Reaction Catalyst

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

高分散钴氮共掺杂碳纳米纤维氧还原催化剂

English

Highly Dispersed Cobalt-Nitrogen Co-doped Carbon Nanofiber as Oxygen Reduction Reaction Catalyst

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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