Citation:
A DSC STUDY OF PHOTOPOLYMERIZATION OF POLYESTERS CONTAINING CONJUGATED DIACETYLENES[J]. Chinese Journal of Polymer Science,
2000, 18(4): 351-356.
A DSC STUDY OF PHOTOPOLYMERIZATION OF POLYESTERS CONTAINING CONJUGATED DIACETYLENES
摘要:
The photopolymerization of two kinds of prepolyesters containing conjugated diacetylene (PDA-6 and PDA-12)was investigated using DSC. By measuring the endothermic enthalpy of the prepolymers after different UV-irradiation times,the polymerizations were found to follow the first-order rate law which agreed with the results of other investigators using adifferent method. The endothermic enthalpy measurements of PDA-6 and PDA-12 before UV-irradiation precluded the possibility that the decrease of endothermic enthalpy was caused by thermal polymerization.
English
A DSC STUDY OF PHOTOPOLYMERIZATION OF POLYESTERS CONTAINING CONJUGATED DIACETYLENES
Abstract:
The photopolymerization of two kinds of prepolyesters containing conjugated diacetylene (PDA-6 and PDA-12)was investigated using DSC. By measuring the endothermic enthalpy of the prepolymers after different UV-irradiation times,the polymerizations were found to follow the first-order rate law which agreed with the results of other investigators using adifferent method. The endothermic enthalpy measurements of PDA-6 and PDA-12 before UV-irradiation precluded the possibility that the decrease of endothermic enthalpy was caused by thermal polymerization.
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