Copolymerization and Properties of Multicomponent Crosslinked Hydrogels

Zheng-bai Zhao Shuang-shuang An Hai-jiao Xie Yong Jiang

Citation:  Zheng-bai Zhao, Shuang-shuang An, Hai-jiao Xie, Yong Jiang. Copolymerization and Properties of Multicomponent Crosslinked Hydrogels[J]. Chinese Journal of Polymer Science, 2015, 33(1): 173-183. doi: 10.1007/s10118-015-1565-7 shu

Copolymerization and Properties of Multicomponent Crosslinked Hydrogels

    通讯作者: Yong Jiang,
  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No. 21174029) and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry.

摘要: A series of multicomponent hydrogels were prepared by the copolymerization of hydrophobic silicon-containing monomer 3-bis(trimethylsilyloxy) methylsilylpropyl glycerol methacrylate (SiMA) with the solvent-responsive monomers 2-hydroxyethyl methacrylate (HEMA) and N-vinyl pyrrolidone (NVP) and thermosensitive monomer N,N-dimethyl acrylamide (DMA). 2-Hydroxy-2-methyl phenyl acetone (D-1173) was chosen as UV initiator and five different dienes/triene monomers were selected as crosslinking agent in order to select the best crosslinker. The ethanol extraction experiments as well as the FTIR, DSC and TG results showed that the copolymerization was effective. The optical, permeability, and mechanical analysis results demonstrated that the obtained hydrogels were highly transparent with good oxygen permeability and mechanical properties. And the impact of crosslinker on the mechanical properties of the hydrogels was also discussed in detail. The basic results demonstrated that the obtained hydrogels had good stimuli-responsive effects to both pH value and solvent.

English

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  • 发布日期:  2015-01-05
  • 收稿日期:  2014-06-17
  • 修回日期:  2014-07-13
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